黔西北普宜地区下三叠统嘉陵江组沉凝灰岩锆石LA-ICP-MS U-Pb年龄、微量元素特征及其地质意义

早三叠世时期频繁的火山事件是导致全球性气候和海洋环境异常的主要原因,前人对早三叠世重要界线时期的火山事件地层开展了大量研究,但对典型界线时期以外的其他火山事件地层却鲜有报道.本文以上扬子西南普宜地区嘉陵江组两件沉凝灰岩为研究对象开展了岩石学、岩相学、锆石年代学及微量元素组合特征等方面的研究.沉凝灰岩样品具有典型岩浆锆石...     

大井矿冶遗址冶炼产物的输出方向

大井矿冶遗址是我国北方发现最早的一处古铜矿遗址。本文利用ICP方法,测试了该遗址的铜矿、炼渣和辽西地区出土的部分青铜器。结果显示,遗址的冶炼金属产品Ag、As、Sb、Bi、Co、Zn等元素含量偏高,Mo含量偏低。同时发现,这批辽西地区出土的青铜器样品微量元素特征明显不同于铜绿山和皖南的铜锭,而与大井铜矿很相似,其铜料来源很可能来自大井古铜矿或其周边铜矿。这一结论,对探讨大井古铜矿冶炼产品的使用范围和辽西地区的冶金历史有重要意义。     

椒江河口沉积物As、Hg黄铁矿矿化程度及其生物有效性

本文利用取自浙江椒江河口3个未扰动柱状沉积物样,进行了孔隙水化学测试、固相沉积物的活性分量与黄铁矿分量的分级提取和测试,结果表明：Hg主要以黄铁矿态形式存在于沉积物中。As在有机碳较高的河口区潮上带和沉积速率较慢的潮下带主要以黄铁矿形态存在[DTMP（degree of trace metal pyritization,痕量元素黄铁矿矿化程度）〉50%）],而在中潮带As的黄铁矿矿化程度略低（DTMP均值为40.99%）,研究区DOP（Fe的黄铁矿矿化程度）值普遍较低（〈35%）,Mn-DTMP低于3.32%。从而揭示了浙江椒江河口沉积物在数厘米以下,毒性痕量元素Hg和As被高度黄铁矿矿化的规律性,并指出在遇有海事活动或风暴潮事件对海底沉积物进行扰动时,河口沉积物与充氧的海水反应,高度黄铁矿矿化的痕量元素会转变成活性态,从而导致近海生态系统的毒性事件。     

地磁匹配特征量的选择

论文旨在选择合适的地磁特征量用于匹配制导.从地磁匹配的实际要求出发,提出了选择匹配特征量时应重点考虑的几个因素,通过理论分析初步拟定了选取准则,并针对特定区域,依据IGRF(International Geomagnetic Reference Field)和WMM(World Magnetic Model)计算出的地磁数据,结合选取准则进行了综合分析,给出了初选结果,对地磁匹配基准图的制备、实时图的获取、匹配算法的研究,以及地磁场资源应用于其他领域的相关研究有一定的借鉴意义.     

Trace‐element signatures of apatites in granitoids from the Mt Isa Inlier,northwestern Queensland

The concentrations of trace elements in apatite from granitoid rocks of the Mt Isa Inlier have been investigated using the laser‐ablation inductively coupled plasma‐mass spectrometry (ICP‐MS) microprobe. The results indicate that the distribution of trace elements (especially rare‐earth elements (REE), Sr, Y, Mn and Th) in apatite strongly reflects the chemical characteristics of the parental rock. The variations in the trace‐element concentrations of apatite are correlated with parameters such as the SiO₂ content, oxidation state of iron, total alkalis and the aluminium saturation index (ASI). The relative enrichment of Y, HREE and Mn and the relative depletion of Sr in the apatites studied reflect the degree of fractionation of the host granite. Apatites from strongly oxidised plutons tend to have higher concentrations of LREE relative to MREE. Manganese concentrations are higher in apatite from reduced granitoids because Mn²⁺substitutes directly for Ca²⁺. The La/Ce ratio of apatite is well‐correlated with the whole‐rock K²O and Na²O contents, as well as with the oxidation state and ASI. Because apatite trace‐element composition reflects the chemistry of the whole rock, it can be a useful indicator mineral for the recognition of mineralised granite suites, where particular mineralisation styles are associated with granitoids that have specific geochemical fingerprints.     

Towards developing sediment quality assessment guidelines for aquatic systems: An Australian perspective

Sediment at the sediment‐water interface of natural and man‐made waterways forms an integral part of the ecosystem because it is affected by a continuous flux of physical, chemical and biological components between the sediment, interstitial water and the overlying water column. Aquatic sediments contain records of past and present urban and rural runoff, chemical discharges and spills. In recent years sediment quality has received increasing attention following identification of the role of sediment as both a sink for pollutants and as a contaminant source with potential impacts on the quality of receiving waters. Research has indicated that the processes leading to remobilization of contaminated sediments in upstream reaches of a waterway may, through time, exert a significant influence on water quality in the downstream reaches. This, together with the cumulative effects due to contaminant input from point and non‐point source discharges, have dramatic effects on water quality and thus on ecosystem structure and functioning.

The problems associated with elevated concentrations of many hazardous organic and inorganic compounds have resulted in the establishment of aquatic sediment quality criteria and management guidelines in many overseas countries, with the objectives being the reduction and elimination of adverse environmental effects and human health risks associated with contaminated sediments. Whereas more than 70% of the Australian population is clustered around the coastal waterways, little is known about the role of sediments as a repository of environmental pollutants and/or as a source of adverse impacts on water quality and the health of our rivers. The paucity of knowledge on the quality of aquatic sediment highlights the need for the development of coherent guidelines for sediment quality assessment and management of contaminated sites, which are consistent with Australian environmental conditions and land use features.

A comparative evaluation of sediment quality information from eight coastal rivers along the east coast of Australia, presented in this paper, indicates the possibility for establishing a framework for regional sediment quality assessment. This may be achievable by using textural and compositional attributes of bottom sediments in depositional areas to develop databases on the loading and concentration trends of nutrients and contaminants. Regional variability in sediment quality determinants are shown to reflect the influence of catchment hydrology, lithology and land use on nutrient and contaminant concentration trends. Locally, the loading and partitioning behaviour of sediment‐bound contaminants is largely controlled by the nature and the extent of interactions occurring at the sediment‐water interface within individual depositional units.

The concept of ‘Sediment Effect Zone’ is introduced to provide a compartmental approach to the characterization of aquatic sediments and depositional environments in different hydrologic zones. This approach offers a rational basis for follow‐up chemical and biological assessments to establish sediment quality standards and management guidelines. Because of the complex influences of environmental, methodological and statistical factors on defining the sediment variability, the need for implementing proper quality control measures from early stages of design of a sediment quality assessment program is highlighted.     

河北省峪耳崖金矿床地质地球化学特征

本文从地质地球化学角度对峪耳崖金矿床进行了详细研究,认为该金矿是典型的岩浆热浪型脉状金矿床,金矿与峪耳崖花岗岩(即矿床的主要围岩)为同源岩浆作用的产物,而其源岩物质可能来自深部地壳。黄铁矿中Co/Ni比为1.58,石英中La/Yb比为2.95,δ~(34)S_∑为+2.6‰,δ~(13)O水为+7.03‰,δD为-88.4‰,δ~(13)C为-4.18‰,成矿温度为305～343℃,pH为6.2～6.8,石英包裹体成分中Cl~->F~-、Na~+>K~+,金可能是以Na[AuCl_2],Na[Aucl_4]或Na[AuS]等络合物形式迁移。     

漳州地热普查区地球化学异常的讨论

本文以漳州热田为例,通过对该区的地质及构造特征、地下热水分布、水化学特征及土壤地球化学异常的分析对照,论证了化探工作在地热勘查中的应用效果。同时,对热田的化探异常成因进行了初浅的探讨。