山东龙宝山岩体稀土元素特征及矿源研究

龙宝山岩体是燕山期多阶段岩浆活动形成的中偏碱性杂岩体,其稀土元素特征为:wΣREE为地壳丰度的2.5倍,wLREE/wHREE为地壳的近9倍,轻稀土强烈富集,δEu、δCe均呈弱负异常,各期侵入岩及含金石英脉的稀土元素分布型式基本相似,呈向右陡倾斜线,但石英脉中稀土总量更高、轻稀土更为富集。研究结果表明:岩浆和成矿物质最初可能均来源于上地幔的同一岩浆房,并在岩浆上侵过程中不同程度地同化混染了地壳物质。     

白云鄂博碳酸岩墙的稀土和微量元素地球化学及对其成因的启示

根据矿物组成白云鄂博矿区的碳酸岩岩可墙可分为白云石型、白云石－方解石共存型和方解石型三种类型。REE和微量元素地球化学表明，这三类碳酸岩岩墙为碳酸岩浆演化不同阶段的产物，白云石型和白云石－方解石共存型对应于早期岩浆阶段，其（La/Nd)n、(La/Yb)n比值随稀土总量的增加而增大，方解石型则对应于碳酸岩浆演化的晚期热液阶段，其稀土总量明显富集，但其（La/Nd)n、(La/Y)n和（La/Yb)n比值随稀土总量的增加却有减小的趋势，热液阶段也是白云鄂博稀土矿化的主要阶段。     

粤北大沟谷热水沉积钠长石岩岩石化学及稀土元素

大沟谷含金钠长石岩带上为层状下为脉状产于震旦系乐昌峡群片岩中,主要由钠长石岩及碳酸盐岩组成。钠长石岩多为块状及条带状构造。钠长石岩和片岩化学成分不同,钠长石岩相对富集Al₂ O₃ 、TiO₂ 、MnO、Na₂O、P₂O₅,而贫Fe₂O₃ 、FeO、MgO、CaO、K₂ O。在主要氧化物组成的直角坐标图上,钠长石岩和片岩位于不同的区域及具不同的变化趋势。钠长石岩稀土元素含量较低,在 12.5 6× 10 -6～ 5 5.6 6× 10 -6之间,具较低的La/Yb(1.82～ 6.42 )、La/Sm(0.96～ 2.99)、Gd/Yb(0.99～ 2.71)比值,较大的δEu异常范围 (0.41～ 0.8),弱的δCe异常。钠长石岩地质产状特征及稀土元素特征表明其主要是热水沉积形成的。     

四川牦牛坪稀土矿床萤石REE配分模式的影响因素

四川牦牛坪稀土矿床萤石REE配分模式表现出明显变化的特征，本文从稀土离子半径和温度两个方面分析了影响矿区萤石配分模式的原因。结果表明：矿区萤石中LREE的配分模式主要受温度影响，而MREE、HREE主要受离子半径控制。     

南极菲尔德斯半岛湖泊沉积物的稀土地球化学

本文研究了燕鸥湖、西湖和基太湖湖泊沉积物的稀土地球化学。这些湖泊沉积物的稀土分布模式与菲尔德斯半岛第三纪火山岩非常相似，它们的物质来源是菲尔德斯半岛岛弧火山岩。湖泊沉积相与冰碛层稀土模式的差异，反映了它们经历的化学风化程度不同、粘土含量不同。Ｃｅ异常意味着每个湖泊沉积旋回结束的阶段气候是比较干燥的。湖泊沉积物的稀土含量和分布模式变化小，也意味着在中晚更新世时气候是比较干燥的。     

山东碳酸岩磷灰石的特征及其研究意义

鲁中隆起的北缘分布着100多个燕山期的碳酸岩体。本文详细研究了岩体中磷灰石的一些重要特征,包括晶体形态、物理性质、光学常数、晶胞参数、化学成分、包裹体及钕锶同位素组成等。并据所得资料对岩体的成因,成岩物质来源等问题进行探讨。     

姑婆山主体花岗岩中富钇钍石的发现

本文论述一种据X射线粉晶分析属钍石类矿物结构,但成分上富含高量重稀土(HRE_2O_3达11.51%),且以钇(Y_2O_3达8.69%)为主的钍石矿物。文中在阐述其产状、共生组合及物性的基础上,对其生成条件进行了初步探讨,认为该矿物的生成是两次替代作用的结果。铀在其中起了媒介作用;重稀土(特别是钇)在姑婆山主体花岗岩边部相岩石中的明显富集是其生成的物质条件。     

云南双沟变质橄榄岩中蛇纹石的稀土元素空间分布

本文探讨变质橄榄岩的ＬＲＥＥ富集型及Ｕ型分布的ＲＥＥ球粒陨石模型，是橄榄石固有的还是后期蚀变形成的。并寻求复原蚀变前橄榄石的ＲＥＥ丰度及型式。我们用蛇纹石颗粒代表蚀变后的橄榄石，用分选法和化学分层剥离法对样品进行予处理。用中子活化分析（ＮＡＡ）手段进行了测试。结果表明：分选法确定了ＬＲＥＥ的主要赋存载体是蛇纹石。分层剥离最后内核的ＲＥＥ丰度及模型，可近似地作为原来（未蚀变前）橄榄石的ＲＥＥ丰度及模型。     

Rare-earth element mobility during ore-forming hydrothermal alteration: A case study of Dongping gold deposit Hebei Province,China

REE mobility during hydrothermal ore-forming processes has been extensively investigated in recent years and the potential of REE to provide information about ore forming processes has commonly been recognized.The Dongping gold deposit,which is located in northwestern Hebei Province,China,occurring in the inner contact zone of the Shuiquangou syenite complex,is spatially,and probably genetically,related to the syenite,the deposit was formed under the moderate to high temperature(220℃ to 320℃),weakly acidic to weakly alkaline,rather high fo2(lgfo2=-30～-34)environment.The REE study of the host rocks,altered wall rocks,ores and gangue minerals from the deposit suggests that the REEs have been mobilized and differentiated during K-feldspathization and silicification.The extremely altered syenite enveloping auriferous quartz vein shows positive Ce anomaly and larger LREE/HREE ratio than that of the unaltered syenite.The REE concentrations and patterns of the ores are determined by the ore types and mineral assemblages,LREE/HREE ratios in the gangue quartz and hydrothermal Kfeldspars are relatively low.The most significant observation is that the gangue quartz shows significant positive Eu anomaly,whereas the hydrothermal K-feldspars show less significant or no positive Eu anomaly at all relative to the primary feldspar in the unaltered syenite. It is evident that the REEs are mobile during K-feldspathization and silicification in the ore forming process.Weak to moderate K-feldspathization caused REE mobility without apparent differentiation with the exception of extreme K-feldspathization and silicification which resulted in significant depletion of HREE and Eu and relative enrichment of Ce.The REE,Y,U,Th and Au contents of the syenite decrease as the degrees of K-feldspathization and silicification of the rocks increase towards the auriferous quartz veins.As the ores were deposited under a rather oxidized environment,Ce^4 predominated over Ce^3 .The precipitation of the former in the form of CeO2 or absorpted onto the secondary mineral assemblage resulted in the inconsistent removal of the REE and the relative Ce enrichment in the strongly altered rocks.in contrast,Eu was present mainly in a low valence state (Eu^2 ).The geochemical differences from the other REE^3 and much less sites in the secondary minerals to accommodate the Eu released form the original minerals resulted in the enrichment of Eu in the fluids.The mobility and differentiation of REE and the coherent mobilities of Y,U,Th and Au also support the argument that the syenite is one of the source rocks for gold mineralization.The REE contents and patterns of the altered rocks enveloping the auriferous quartz vein could be used as a guide for locating ore veins in mineral exploration.