西秦岭寨上金矿床中石英和绢云母40Ar/39Ar定年

寨上金矿是西秦岭地区近年新发现的大型金矿床。为确定该金矿床的成矿时代,对其含金石英、蚀变绢云母进行了40Ar/39Ar快中子活化法测定。2件样品的40Ar/39Ar坪年龄及等时线年龄分别为(130.62±1.38)Ma、(129.24±1.23)Ma和(125.28±1.26)Ma、(125.56±1.20)Ma,测试结果可信。40Ar/39Ar法年龄测定结果表明,寨上金矿床形成于燕山晚期,并可能历经了约5Ma时间最终形成。对西秦岭地区已有的金矿床测年数据进行分析后认为,该区可能存在3个金矿成矿高峰期,即220~170Ma、130Ma前后和50Ma左右。     

“中央造山带”早古生代缝合带及构造分区概述

“中央造山带”是夹持于中国塔里木、华北和扬子克拉通之间的近东西向延展的（局部为北东向和北西向）显生宙造山系统。该造山带中包括了库地-喀拉塔什、红柳沟-肃北-北祁连、南阿尔金-滩间山、昆中、朱阳关-夏馆和商州-丹凤6条早古生代缝合带。被缝合带所围限的前寒武纪地质构造单元包括中阿尔金-祁连-金吉地块、柴达木地块、北秦岭地块和东、西昆仑2个变质地体。南秦岭原为扬子克拉通的北部边缘，但卷入了显生宙造山带，成为中央造山带的一部分。对上述6条早古生代缝合带和6个前寒武纪地质构造单元的特点进行了概略总结，并阐述了各地质构造单元中的构造地层系统和热-构造事件的年代格架。     

What Happened in the Trans-North China Orogen in the Period 2560-1850 Ma？

The Trans-North China Orogen （TNCO） was a Paleoproterozic continent-continent collisional belt along which the Eastern and Western Blocks amalgamated to form a coherent North China Craton （NCC）. Recent geological, structural, geochemical and isotopic data show that the orogen was a continental margin or Japan-type arc along the western margin of the Eastern Block, which was separated from the Western Block by an old ocean, with eastward-directed subduction of the oceanic lithosphere beneath the western margin of the Eastern Block. At 2550-2520 Ma, the deep subduction caused partial melting of the medium-lower crust, producing copious granitoid magma that was intruded into the upper levels of the crust to form granitoid plutons in the low- to medium-grade granite-greeustone terranes. At 2530-2520 Ma, subduction of the oceanic lithosphere caused partial melting of the mantle wedge, which led to underplating of mafic magma in the lower crust and widespread mafic and minor felsic volcanism in the arc, forming part of the greenstone assemblages. Extension driven by widespread mafic to felsic volcanism led to the development of back-arc and/or intra-arc basins in the orogen. At 2520-2475 Ma, the subduction caused further partial melting of the lower crust to form large amounts of tonalitic-trondhjemitic-granodioritic （TTG） magmatism. At this time following further extension of back-arc basins, episodic granitoid magmatism occurred, resulting in the emplacement of 2360 Ma, -2250 Ma 2110-21760 Ma and -2050 Ma granites in the orogen. Contemporary volcano-sedimentary rocks developed in the back-arc or intra-are basins. At 2150-1920 Ma, the orogen underwent several extensional events, possibly due to subduction of an oceanic ridge, leading to emplacement of mafic dykes that were subsequently metamorphosed to amphibolites and medium- to high-pressure mafic granulites. At 1880-1820 Ma, the ocean between the Eastern and Western Blocks was completely consumed by subduction, and the dosing of the ocean led to the continent-arc-continent collision, which caused large-scale thrusting and isoclinal folds and transported some of the rocks into the lower crustal levels or upper mantle to form granulites or eclogites. Peak metamorphism was followed by exhumation/uplift, resulting in widespread development of asymmetric folds and symplectic textures in the rocks.     

DPIS（矿床定位预测系统）在西秦岭地区金矿综合评价应用效果

在大量收集西秦岭地质资料基础上，以信息量计算法为数学依据，以DPIS软件为工具，建立了西秦岭地区较为详实的地质空间信息数据库，圈定出成矿预测区8处，并对其中的岷县一礼县成矿预测区进行了解释和推断，认为寨上西南、北东部地区仍有较大的找矿潜力。应用DPIS进行区域成矿预测，具有降低信息统计的劳动强度、分析处理海量数据、快速进行多种方案对比、筛选有利找矿靶区的优点；建议推广DPIS系统应用研究工作。     

河南冷水北沟铅锌银矿床流体包裹体研究及矿床成因

河南栾川冷水北沟铅锌银矿床位于华北克拉通南界栾川断裂北侧。矿床赋存于中-晚元古代浅变质碎屑岩建造中,受断裂控制,矿体呈脉状;矿石主要由金属硫化物,少量石英和碳酸盐组成;围岩蚀变和成矿过程分为4个阶段,以石英- 黄铁矿组合(Ⅰ阶段)、黄铁矿-闪锌矿组合(Ⅱ阶段)、多金属硫化物(Ⅲ阶段)和碳酸盐(Ⅳ阶段)为标志。包裹体研究表明,成矿流体为含 CH_4的碳水体系,盐度为0.22～13.8 wt% NaCl eqv.。从早到晚,流体包裹体均一温度为420℃～340℃(Ⅰ)、370℃～280℃(Ⅱ)、320℃～260℃(Ⅲ)和<260℃(Ⅳ)。Ⅰ、Ⅱ阶段的流体盐度低于8 wt% NaCl eqv.,Ⅲ阶段增高至13.8 wt%NaCl eqv.,甚至偶见子晶。Ⅰ、Ⅱ阶段的流体包裹体均一压力分为两组,即180～200MPa 和70～80MPa,代表着深约8km 的静水与静岩压力系统的共存或交替;Ⅲ阶段只有70～80MPa 一组压力,指示开放环境注入的静水压力体系。Ⅰ、Ⅱ阶段静岩与静水压力系统的交替现象完全吻合于断层阀模式,含 CH_4的 CO_2-H_O 流体的脉动沸腾消耗了流体成矿系统热能,并使盐度不断增高、成矿。该认识可被Ⅱ阶段广泛存在的沸腾流体包裹体组合证明,也与流体包裹体成分类型、矿物共生组合特征、矿石组构的规律演化相一致。以上表明,冷水北沟是一个典型的形成于碰撞造山挤压向伸展转变期的造山型 Pb-Zn-Ag 矿床实例,成矿机理可由碰撞造山成岩成矿与流体作用模型(即 CMF 模式)所解释。     

Flat rare earth element patterns as an indicator of cumulate processes in the Lesser Qinling carbonatites, China

The Lesser Qinling carbonatite dykes are mainly composed of calcites. They are characterized by unusually high heavy rare earth element concentrations (HREE; e.g. Yb > 30 ppm) and flat to weakly light rare earth element (LREE) enriched chondrite-normalized patterns (La/Yb_n = 1.0–5.5), which is in marked contrast with all other published carbonatite data. The trace element contents of calcite crystals were measured in situ by laser ablation inductively coupled plasma mass spectrometry (LA-ICPMS). Some crystals show reduced LREE from core to rim, whereas their HREE compositions are relatively constant. The total REE contents and chondrite-normalized REE patterns from the cores of carbonate crystals are similar to those of the whole rock. The carbon and oxygen isotopic compositions of calcites fall within the range of primary, mantle-derived carbonatites. The initial Sr isotopic compositions (0.70480–0.70557) of calcites are consistent with an EM1 source or mixing between HIMU and EM1 mantle sources. However these sources cannot produce carbonatite parental magmas with a flat or slightly LREE enrichment pattern by low degrees of partial melting. Analyses of carbonates from other carbonatites show that carbonates have nearly flat REE pattern if they crystallize from a LREE enriched carbonatite melt. This implies that when carbonates crystallize from a carbonatite melt the calcite/melt partition coefficients (D) for HREE are much greater than the D for the LREE. The nearly flat REE patterns of the Lesser Qinling carbonatites can be explained if they are carbonate cumulates that contain little trapped carbonatite melt. Strong enrichment of HREE in the carbonatites may require their derivation by small degrees of melting from a garnet-poor source.     

青海同仁县隆务峡地区首次发现镁铁质——超镁铁质岩带

在青海省同仁县隆务峡南段的二叠纪地层中首次发现了北西—南东向分布的镁铁质—超镁铁质岩带,命名为隆务峡镁铁质—超镁铁质岩带。该岩带的岩石组合包括纯橄岩、辉石橄榄岩、辉长岩、辉绿岩、枕状玄武岩等。从超镁铁岩—下部堆晶岩—辉绿岩—上部堆晶岩,其稀土元素总量逐渐增加,稀土元素配分型式总体一致,从超镁铁岩的Eu正异常到上部辉长岩的Eu负异常,显示了各岩石间的同源性。根据对其两侧沉积岩中化石的研究,推测该镁铁质—超镁铁质岩带的形成时代为二叠纪。该岩带位于西秦岭造山带与祁连造山带的接舍部,对于揭示秦岭和祁连接合部的大地构造演化有重要意义。     

北秦岭二郎坪群重晶石岩热水沉积地球化学证据及其成矿意义

北秦岭二郎坪群中存在与地层整合产出的层状重晶石岩和铜多金属矿床。重晶石岩贫Al2O3、TiO2组分含量;富集热液组分As、Sb、Ba、Ag和Hg;微量元素U/Th>1;低ΣREE(平均值27.78×10-6)、富集轻稀土(LREE)、亏损重稀土(HREE)、具明显Eu正异常、Ce负异常及与大西洋TAG热液区热液沉积物相似的球粒陨石标准化的稀土元素配分模式特征。这些特征揭示研究区重晶石岩是热水沉积成因型。热水沉积重晶石岩与铜多金属矿床的紧密联系说明,研究区铜金属矿床是海底热液喷流沉积成岩成矿作用的产物。     

Collision leading to multiple-stage large-scale extrusion in the Qinling orogen: Insights from the Mianlue suture

The geologic framework of the Phanerozoic Qinling–Dabie orogen was built up through two major suturing events of three blocks. From north to south these include the North China craton (including the north Qinling block), the Qinling–Dabie microblock, and the South China craton (including the Bikou block), separated by the Shangdan and Mianlue sutures. The Mianlue suture zone contains evidence for Mesozoic extrusion tectonics in the form of major strike–slip border faults surrounding basement blocks, a Late Paleozoic ophiolite and a ca. 240–200 Ma thrust belt that reformed by 200–150 Ma thrusts during A-type (intracontinental) subduction. The regional map pattern shows that the blocks are surrounded by complexly deformed Devonian to Early Triassic metasandstones and metapelites, forming a regional-scale block-in-matrix mélange fabric. Five distinct tectonic units have been recognized in the belt: (1) basement blocks including two types of Precambrian basement, crystalline and transitional; (2) continental margin slices including Early Paleozoic strata, and Late Paleozoic fluviodeltaic sedimentary rocks, proximal and distal fan clastics, reflecting the development of a north-facing rift margin on the edge of the South China plate; (3) out of sequence oceanic crustal slices including strongly deformed postrift, deep-water sedimentary rocks, sheeted dikes, basalts, and mafic–ultramafic cumulates of a Late Paleozoic ophiolite suite, developing independent of the rift margin in a separate basin; (4) out-of-sequence island-arc slices; (5) accretionary wedge slices. All the tectonic units were deformed during three geometrically distinct deformation episodes (D₁, D₂ and D₃ during 240–200 Ma). Units 2–4 involved southward thrusting and vertical then southward extrusion of about 20 km of horizontal displacement above the autochthonous basement during the D₁ episode. Thrust slices 20 km south of the Mianlue suture are related to this vertical extrusion due to the same rock assemblages, ages and kinematics. The D₂ and D₃ episodes folded all the units in a thick-skinned style about east–west (D₂) and west–northwest (D₃) axes in the Mianlue suture zone. An early foreland propagating sequence of accretion of Late Paleozoic rocks deposited above the Yangtze craton is not involved in D₁ deformation but is temporally equivalent to the D₂ and D₃ deformation in the Mianlue suture. Two stages of strike–slip faulting mainly occurred at the end of D₂ and D₃, respectively. During D₂ deformation, the Bikou block was obliquely indented to the ESE into the Mianlue suture, rather than being thrust over the Mianlue suture from the north as a part of the Qinling–Dabie microblock. During D₃ deformation, however, the Bikou block was bounded by the south boundary fault of the Mianlue suture, and the Yangpingguan fault on the south. These faults are coeval strike–slip faults, but of opposite senses, and accommodated minor southwestward extrusion of the Bikou block into Songpan–Ganze orogen. The other basement blocks north of the Mianlue suture were extruded eastward by about 20 km of lateral displacement, based on the offset of the Wudang dome, during the D₃ episode due to the northeastward indentation of the Hannan complex of the South China craton. Post-D₃ emplacement of granite, cutting across the strike–slip faults such as the Mianlue suture, provides a minimum age of 200 Ma for D₃ deformation. Therefore, based on insights from the evolution of the Mianlue suture, the D₂ and D₃ episodes in the Mianlue suture and its neighbors are not responsible for and associated with the two-stage extrusion of the Dabie UHP-HP terranes from the Foping dome to the present erosional surface (more than 350 km).     

西秦岭天水尹道寺中生代酸性火山岩锆石U-Pb定年和元素地球化学研究

对天水尹道寺酸性火山岩进行了LA-ICPMS锆石U-Pb定年、全岩主量和微量元素分析.结果表明,本区酸性火岩熔岩均为流纹岩,SiO2、Na2O K2O含量高,TiO2含量低,主体为亚碱性系列,轻稀土高度富集,Eu负异常明显.微量元素原始地幔标准化分配模式及洋中脊玄武岩标准化分配模式分别与大陆板内火山岩或大陆板内花岗岩的分配模式一致,Ba、Sr、P、Ti显著亏损.锆石U-Pb同位素定年揭示了流纹岩的岩浆结晶年龄为印支末期(211Ma).流纹岩具有富集放射性Pb同位素的特点,其源区可能为北秦岭基底岩石.依据稀土元素和微量元素分配模式对比研究,认为流纹岩浆为地壳下部部分熔融的产物.源区物质可能为下元古界秦岭岩群中的黑云角闪斜长片麻岩,源区的残留物主体可能为斜长石,含有角闪石,岩浆演化过程中存在少量的碱性长石和黑云母的分离结晶.印支末期秦岭地区处于由陆内碰撞造山阶段开始向深部地幔调整和岩石圈减薄阶段转变,特殊的构造背景使得陆内挤压、剪切走滑和推覆构造较为发育,西秦岭尹道寺地区特定的构造背景与断裂构造的结合,形成了该地区独特的流纹岩浆喷发.