排序方式: 共有32条查询结果,搜索用时 359 毫秒
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利用谱睿(Pre)在线样品前处理技术检测高碳酸盐基体中阴离子 总被引:2,自引:1,他引:1
利用戴安公司全新的谱睿(Pre)在线样品前处理技术,开发了一种柱前在线去除高碳酸盐基体中碳酸盐的方法,解决了以往高碳酸盐基体对其他阴离子测定的影响问题。利用该方法对钢铁洗涤液碳酸钠溶液、固体碳酸钠试剂、商品化碳酸钠淋洗液浓缩液等不同类型的样品分别进行了检测。选择的色谱条件为高容量氢氧化物选择性IonPac AS15阴离子交换色谱柱,淋洗液自动发生装置在线产生KOH进行梯度淋洗,抑制电导检测。该方法在常规离子色谱基础上增加一个输液泵、一个六通阀和一个在线二氧化碳去除器(CRD),提出了不使用浓缩柱作为前处理设备与离子色谱主机之间的接口,而采用大定量环,选取合适的时间窗口这一先进理念。该方法可实现5000 mg/L碳酸盐溶液的在线去除,同时检测出浓度低于50μg/L的氯离子、硝酸根离子、硫酸根离子等阴离子。采用外标法和外延法进行定量,标准曲线线性较好,标准加入回收率为92%~108%。方法具有操作简单、可重复性强、方法新颖等特点,并解决了碳酸根离子对其他阴离子的测定干扰这一离子色谱技术难题。 相似文献
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采用戴安公司谱睿(Pre)在线样品前处理技术,使用高容量在线Ag柱和Na柱,开发出了一种柱前去除高氯基体中氯离子的在线分析方法。操作简便,且适用样品范围广;不更换Ag柱可耐受10 g/L NaCl基体,25μL连续进样400针,氯离子去除效率可保持在99%以上。系统选用高容量IonPac AS11-HC氢氧根体系阴离子交换色谱柱,在线淋洗液自动发生装置进行梯度淋洗,用抑制型电导检测。对食盐、分析纯氯化钠等不同基体进行检测,可实现样品在线除氯,并可检测其中不高于10μg/L的溴酸根、氯酸根、亚硝酸根、硝酸根和硫酸根等离子。不同离子校准曲线相关系数均在99.8%以上,加标回收率为80%~110%。该技术具有操作简单、可重复性强、方法新颖等特点,解决了以往高氯基体检测成本过高、适用范围有限、前处理操作复杂等问题。 相似文献
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We revisit the equations governing the bending motions in thin rods and analyse the filtration of flexural waves in vertical drill strings pre‐stressed by gravity. The aim is to study transverse drill‐string vibrations at seismic frequencies for acoustic communication purposes and provide an algorithm for processing reflected and transmitted bending motions generated by downhole lateral vibrations. We obtain the dispersion equation, including attenuation due to a gravity pre‐stress gradient and frequency‐dependent reflection and transmission coefficients at the interface between subsequent tube intervals. We then develop a propagation‐matrix algorithm to simulate flexural waves in a drill string consisting in an assembly of multiple tube sections of different dimensions. The deflection vibrations are obtained at any arbitrary recording point in the drill string. The modelling is cross‐checked with a full‐wave grid algorithm. The analysis shows that the waves produced by a concentrated force are partitioned in standing and propagating modes, which are calculated by using the flexural impedance of the drill string. Moreover, the reflection coefficients weakly depend on the pre‐stress conditions and pre‐stress has important effects for far‐field signal transmission with variable weight on bit (WOB). We discuss the approximations and limits of the method with respect to realistic drilling conditions. 相似文献
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三维叠前深度偏移复杂构造成像 总被引:2,自引:0,他引:2
三维叠前深度偏移能对复杂构造准确成像,可以减小钻井风险。大规模并行处理机的并行高效率为短周期完成三维叠前深度偏移成像奠定了基础。笔者简要介绍三维叠前深度偏移的技术要点及其典型实例。 相似文献
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苏南地区前第四纪岩石地层主要特征及几点认识 总被引:1,自引:1,他引:0
依据“苏南及沿江地区1∶5万区调片区总结”的成果,概述了苏南地区前第四纪岩石地层的划分、岩性、分布、古地理沉积环境及其演化等主要特征,并就埤城岩群的原岩恢复,大王山组、黄尖组的时代归属,西区中—上新世地层划分等问题进行了讨论,提出了一些新认识。 相似文献
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In order to study a model‐dependence of the results achieved in the previous investigations of the Pleiades luminosity function using D'Antona and Mazzitelli (1994) evolutionary tracks, we repeated the computations with the new track system by D'Antona and Mazzitelli (1997). The following main conclusions can be drawn: the new models agree better with observations; the helium abundance needed to fit the Hipparcos distance modulus is reduced to a more reasonable value of Y = 0.31; the cluster age becomes slightly higher and the slope of the initial mass function somewhat lower. The conclusions on the fine structure of the luminosity function do not change significantly due to the application of the new models. 相似文献
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