Deciphering As and Cu cycling in sediment pore waters in a large marina (Port Camargue,southern France) using a multi-tracer (Fe,Mn, U,Mo) approach

The sediments of the Port Camargue marina (South of France) are highly polluted by Cu and As (Briant et al., 2013). The dynamics of these pollutants in pore waters was investigated using redox tracers (sulfides, Fe, Mn, U, Mo) to better constrain the redox conditions.In summer, pore water profiles showed a steep redox gradient in the top 24 cm with the reduction of Fe and Mn oxy-hydroxides at the sediment water interface (SWI) and of sulfate immediately below. Below a depth of 24 cm, the Fe, Mn, Mo and U profiles in pore waters reflected Fe and Mn reducing conditions and, unlike in the overlying levels, sulfidic conditions were not observed. This unusual redox zonation was attributed to the occurrence of two distinct sediment layers: an upper layer comprising muddy organic-rich sediments underlain by a layer of relatively sandy and organic-poor sediments. The sandy sediments were in place before the building of the marina, whereas the muddy layer was deposited later. In the muddy layer, large quantities of Fe and Mo were removed in summer linked to the formation of insoluble sulfide phases. Mn, which can adsorb on Fe-sulfides or precipitate with carbonates, was also removed from pore waters. Uranium was removed probably through reduction and adsorption onto particles. In winter, in the absence of detectable pore water sulfides, removal of Mo was moderate compared to summer.Cu was released into solution at the sediment water interface but was efficiently trapped by the muddy layer, probably by precipitation with sulfides. Due to efficient trapping, today the Cu sediment profile reflects the increase in its use as a biocide in antifouling paints over the last 40 years.In the sandy layer, Fe, Mn, Mo and As were released into solution and diffused toward the top of the profile. They precipitated at the boundary between the muddy and sandy layers. This precipitation accounts for the high (75 μg g⁻¹) As concentrations measured in the sediments at a depth of 24 cm.     

Nano-scale pore structure and fractal dimension of organic-rich Wufeng-Longmaxi shale from Jiaoshiba area,Sichuan Basin: Investigations using FE-SEM,gas adsorption and helium pycnometry

Much attention have been recently paid to the upper Ordovician Wufeng shale (O₃w) and lower Silurian Longmaxi shale (S₁l) in the Jiaoshiba area of Sichuan Basin, which is now the largest producing shale gas field in China. Field emission scanning electron microscopy (FE-SEM), low pressure gas (N₂ and CO₂) adsorption, helium pycnometry, X-ray diffraction and geochemical analyses were performed to investigate the pore structure and fractal dimension of the pores in O₃w-S₁l shale formation in the Jiaoshiba area. FE-SEM images show that organic matter (OM) pores are dominant in the organic-rich samples and these pores are often irregular, bubble-like, elliptical and faveolate in shape, while in organic-poor samples, limited and isolated interparticle (interP), intraparticle (intraP) and OM pores are observed. Reversed S-shaped isotherms obtained from nitrogen adsorption are type Ⅱ, and hysteresis loops indicate that the shape of micropore in the samples is slit-or plate-like. BET surface areas and total pore volume vary from 12.2 to 27.1 m²/g and from 1.8 × 10⁻² to 2.9 × 10⁻² cm³/g, with an average of 19.5 m²/g and 2.3 × 10⁻² cm³/g, respectively. Adsorption volume from both N₂ and CO₂ adsorption increases with respect to TOC contents. Porosities obtained from helium porosimetry are comparable with these from gas (CO₂ and N₂) adsorption in O₃w-S₁l shale. However, porosity determined by quantitative FE-SEM analysis is much smaller, which is mainly related to limited resolution and the small areas of investigation.Based on the Frenkel-Halsey-Hill (FHH) model of low-pressure N₂ adsorption, fractal dimensions of the pores varied from 2.737 to 2.823. Relationships between pore structure parameters and TOC content, mineral composition and fractal dimension reveal that the fractal dimension is mainly associated with micropores. Samples with higher TOC content, higher quartz content and lower clay content tend to contain more heterogeneous micropores, resulting in higher fractal dimensions and more complicated pore structure in shales. Therefore, fractal dimension is an effective parameter to reflect the complexity of pore structure and the degree of micropore development in O₃w-S₁l shale.     

Controls on reservoir heterogeneity of tight sand oil reservoirs in Upper Triassic Yanchang Formation in Longdong Area,southwest Ordos Basin,China: Implications for reservoir quality prediction and oil accumulation

Compared to conventional reservoirs, pore structure and diagenetic alterations of unconventional tight sand oil reservoirs are highly heterogeneous. The Upper Triassic Yanchang Formation is a major tight-oil-bearing formation in the Ordos Basin, providing an opportunity to study the factors that control reservoir heterogeneity and the heterogeneity of oil accumulation in tight oil sandstones.The Chang 8 tight oil sandstone in the study area is comprised of fine-to medium-grained, moderately to well-sorted lithic arkose and feldspathic litharenite. The reservoir quality is extremely heterogeneous due to large heterogeneities in the depositional facies, pore structures and diagenetic alterations. Small throat size is believed to be responsible for the ultra-low permeability in tight oil reservoirs. Most reservoirs with good reservoir quality, larger pore-throat size, lower pore-throat radius ratio and well pore connectivity were deposited in high-energy environments, such as distributary channels and mouth bars. For a given depositional facies, reservoir quality varies with the bedding structures. Massive- or parallel-bedded sandstones are more favorable for the development of porosity and permeability sweet zones for oil charging and accumulation than cross-bedded sandstones.Authigenic chlorite rim cementation and dissolution of unstable detrital grains are two major diagenetic processes that preserve porosity and permeability sweet zones in oil-bearing intervals. Nevertheless, chlorite rims cannot effectively preserve porosity-permeability when the chlorite content is greater than a threshold value of 7%, and compaction played a minor role in porosity destruction in the situation. Intensive cementation of pore-lining chlorites significantly reduces reservoir permeability by obstructing the pore-throats and reducing their connectivity. Stratigraphically, sandstones within 1 m from adjacent sandstone-mudstone contacts are usually tightly cemented (carbonate cement > 10%) with low porosity and permeability (lower than 10% and 0.1 mD, respectively). The carbonate cement most likely originates from external sources, probably derived from the surrounding mudstone. Most late carbonate cements filled the previously dissolved intra-feldspar pores and the residual intergranular pores, and finally formed the tight reservoirs.The petrophysical properties significantly control the fluid flow capability and the oil charging/accumulation capability of the Chang 8 tight sandstones. Oil layers usually have oil saturation greater than 40%. A pore-throat radius of less than 0.4 μm is not effective for producible oil to flow, and the cut off of porosity and permeability for the net pay are 7% and 0.1 mD, respectively.     

Geological control factors of micro oil distribution in tight reservoirs

Understanding the oil distribution characteristics in unconventional tight reservoirs is crucial for hydrocarbon evaluation and oil/gas extraction from such reservoirs. Previous studies on tight oil distribution characteristics are mostly concerned with the basin scale. Based on Lucaogou core samples, geochemical approaches including Soxhlet extraction, total organic carbon (TOC), and Rock-Eval are combined with reservoir physical approaches including mercury injection capillary pressure (MICP) and porosity-permeability analysis, to quantitatively evaluate oil distribution of tight reservoirs on micro scale. The emphasis is to identify the key geological control factors of micro oil distribution in such tight reservoirs. Dolomicrites and non-detrital mudstones have excellent hydrocarbon generation capacity while detritus-containing dolomites, siltstones, and silty mudstones have higher porosity and oil content, and coarser pore throat radius. Oil content is mainly controlled by porosity, pore throat radius, and hydrocarbon generation capacity. Porosity is positively correlated with oil content in almost all samples including various lithologies, indicating that it is a primary constraint for providing storage space. Pore throat radius is also an important factor, as oil migration is inhibited by the capillary pressure which must be overcome. If the reservoir rock with suitable porosity has no hydrocarbon generation capacity, pore throat radius will be decisive. As tight reservoirs are generally characterized by widely distributed nanoscale pore throats and high capillary pressure, hydrocarbon generation capacity plays an important role in reservoir rocks with suitable porosity and fine pore throats. Because such reservoir rocks cannot be charged completely. The positive correlation between hydrocarbon generation capacity and oil content in three types of high porosity lithologies (detritus-containing dolomites, siltstones, and silty mudstones) supports this assertion.     

20世纪40年代初以来中国大陆沿海主要海湾形态变化

受气候变化和人类活动的影响,中国海岸带正在经历各种剧烈的变化,海湾形态变化是其中的一个重要方面.基于地形图资料与遥感影像提取20世纪40年代初至2014年7个时相的中国大陆沿海主要海湾的空间信息,进而分析海湾岸线类型结构,开发利用程度和空间位置的变化特征,以及海湾面积,形状和重心分布的变化特征.结果表明,20世纪40年代初以来,中国大陆沿海主要海湾的形态变化显著且复杂,主要体现为:海湾岸线的结构变化显著,自然岸线的长度和比例急剧减少;海湾岸线的开发利用程度持续增强;海湾岸线普遍背陆向海运动;海湾面积普遍大幅萎缩;海湾形状总体趋向复杂但个体间的差异在缩小;海湾重心分布位置普遍背陆向海迁移;海湾变化具有显著的时空差异性等.总的来说,以围填海为主的人类活动是导致海湾发生上述变化特征的主要原因.通过研究,指出应该对中国的海湾进行功能定位划分和分类管理,通过强化以海湾为基本单元的管理,促进中国海岸带综合管理能力的提高和管理目标的实现.     

Pore structure and heterogeneity of shale gas reservoirs and its effect on gas storage capacity in the Qiongzhusi Formation

Fine characterization of pore systems and heterogeneity of shale reservoirs are significant contents of shale gas reservoir physical property research.The research on micro-control factors of low productivity in the Qiongzhusi Formation(Fm.)is still controversial.The lower Cambrian Qiongzhusi Fm.in the Qujing,Yunnan was taken as the object to investigate the influence of mineral compositions on the phys-ical properties of the reservoir and the heterogeneity of shale,using the algorithm to improve the char-acterization ability of Atomic Force Microscopy(AFM).The results showed that:(1)The pores are mainly wedge-shaped pores and V-shaped pores.The pore diameter of the main pore segment ranges from 5 to 10 nm.Mesopores are mainly developed in the Qiongzhusi Fm.shale in Well QD1,with the average pore diameter of 6.08 nm.(2)Microscopic pore structure and shale surface properties show strong hetero-geneity,which complicates the micro-migration of shale gas and increases the difficulty of identifying high-quality reservoirs.(3)The increase of clay mineral content intensifies the compaction and then destroys the pores.Conversely,brittle minerals can protect pores.The support and protection of brittle minerals to pores space depend on their content,mechanical properties and diagenesis.(4)Compression damage to pores,large microscopic roughness and surface fluctuations and strong pore structure heterogeneity are the reasons for the poor gas storage capacity of the Qiongzhusi Fm.,which will lead to poor productivity in the Qiongzhusi Fm.     

潮汐形变前驱波的时空特征

分析了潮汐形变观测记录的14个震例中36个前驱波图像的特点、形态、量级,总结了潮汐形变前驱波的时空特征主震震级Ms≥5.9时出现的可能性大,出现的时间多为震前0.1~6.5天;台站对Ms=5、6、7、≥7.9地震的有效监测距离分别为70、300、400、2000km。     

大型桥梁钢沉井下沉过程局部冲刷研究

钢沉井下沉过程中局部冲刷的研究是同类桥墩设计和施工十分关心的重要课题,它对保证钢沉井安全有效施工、桥梁设计中施工期桥墩最大冲深、失稳和安全计算有重要参考价值。通过室内试验研究了钢沉井下沉过程中的局部冲刷机理和冲刷形态,探讨了桥墩下部钢沉井基础施工的相对高程对局部冲刷的变化规律,并将试验研究所获得的局部冲刷规律和影响因素,采用墩型系数方法引入局部冲刷计算中,给出了计算公式。研究成果补充了国家行业规范内容,对同类工程的设计、施工具有借鉴和指导意义。     

雅安市雨城区壶穴形态特征

以雅安市雨城区的严桥河和周公河流域的河床壶穴为研究对象,对128处壶穴形态规模与几何参数进行详细测量。运用定量统计方法分析壶穴的分布规模和形态特征。结果表明:周公河流域壶穴大多分布在岸边大石块上,严桥河流域壶穴主要分布于河床的岩坎上;两地壶穴平均分布密度为0.43个/m2,相对其他区域较小,且壶穴的长短轴和平均口径与深度都有相对明显的规律。在平面形态上,壶穴形态多样,周公河以近圆型壶穴最多,占52.5%,严桥河以椭圆型壶穴最多,占63.6%。在垂直剖面形态上,周公河处壶穴90%属于U型,其余为V型;严桥河处壶穴V型和U型分别占52.3%和44.3%,还有3.4%属倒Ω型;两地壶穴都以浅型为主。