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Ludmila A. Pavlova Ludmila Ph. Paradina Olga Yu. Belozerova 《Geostandards and Geoanalytical Research》2001,25(2-3):333-344
In this paper we report the results of electron probe X-ray microanalysis (EPMA) that was used to study environmental materials. The mode of preparation and certification of reference samples based on a basaltic glass matrix for environmental applications of EPMA is described. These samples were prepared containing scandium, strontium and barium (from 0.03 up to 7% m/m) and an evaluation was made of homogeneity, their stability to local heating, followed by analysis by independent methods for certification of composition. Matrix correction procedures for the EPMA technique have been developed for particles having a size commensurable with the volume of X-ray generation. An analytical equation for the size factor is proposed and two techniques for selecting optimum conditions for the analysis of environmental samples by EPMA are reported. These procedures provided satisfactory results when utilized in analysing sediments recovered from snow, coal fly ash and the bones of animals and fish, results from which can be used as indicators for evaluating the pollution level of the lower atmosphere, surface and ground water, as well as revealing pollution mechanisms. 相似文献
123.
利用流动注射在线萃取技术,以MIBK为萃取剂,用火焰原子吸收分析方法测定地质样品中的痕量金,取得了满意的效果。该法精密度好,无污染,操作简便,测定迅速,且样品不需分离。方法检出限Au为0.78×10-9,精密度为2.30%。 相似文献
124.
本文对应用SYC 系列声波仪探测室内受压岩样破裂区域的试验技术进行了分析,提出了一种在稳压阶段及卸荷后测量声波走时的试验方法,并通过试验对时间因素及卸荷产生的走时误差进行了初步探讨,证明这种试验方法是可行的。 相似文献
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126.
Li Bing Ma Xinrong Han Lirong Yang Hongxia 《Geostandards and Geoanalytical Research》2004,28(2):317-323
A simple sample treatment method for the accurate and precise determination of iodine in soil, sediment and biological samples by inductively coupled plasma-mass spectrometry (ICP-MS) is described. Iodine in samples was extracted in screw top PTFE-lined stainless steel bombs using a 10% v/v ammonia solution at 185 C for 18 hours (overnight), after which the extract was introduced into the ICP-MS for direct measurement. 126 Te was employed as the internal standard to compensate for matrix effects and instrument drift. The limit of detection (LOD, three times the standard deviation of the procedural blank solution, expressed as the concentration in the sample solution) was 0.003 ng ml--1 . The limit of quantitation (LOQ, ten times the standard deviation of the procedural blank solution, expressed as the concentration in the solid samples, dilution factor DF = 100) was 0.01 μg g--1 (dry mass). The accuracy and precision of the method were demonstrated by analysing different Chinese geological certified reference materials (soils, stream sediments and a hair sample). The measured concentrations were in a good agreement with the certified values indicating that bias in the method was not significant. The precision (n = 10) for different concentrations ranged from 1.82% to 4.32% RSD. Comparison of the ammonia extraction procedure with a "sintering" method indicated that there was no significant difference in results obtained with the two methods for geological soil and stream sediment samples. However, for biological samples, such as hair, kelp, tea etc., the results obtained by the sintering method were far below those of the ammonia extraction method. The ammonia extraction has advantages, as it is simpler than the "sintering" method, and has a lower procedural blank, better detection limits and reproducibility. Due to the simplicity of the method, a high rate of sample throughput is possible. 相似文献
127.
This annual review of secondary ion mass spectrometry (SIMS) highlights significant progress in the application of the technology for the following areas: U-Pb geochronology (notably in the fields of reference material zircons), sources of uncertainty during analysis and secondary ion yields. Major publications introduced a new zircon reference sample and dealt with an intercomparison study of a suite of established calibrators, some of which have been shown to have certain limitations. Another publication claimed that the principal uncertainty in U-Pb dating is related to variations in the Pb and U relative emission yields over a complete analytical session. 2003 saw the introduction of an automated particle identification procedure applied to the analysis of a chondritic meteorite, as well as new geometries of SIMS hardware (NanoSIMS) and techniques (time-of-flight SIMS). NanoSIMS allows a two to three order of magnitude reduction in sampling volume as a result of a reduced beam diameter, and time-of-flight SIMS allows the study of sample surfaces, and can provide data for elements concurrently. 相似文献
128.
流动注射分析及其在地质样品痕量元素测试中的应用 总被引:1,自引:0,他引:1
简述了流动注射分析方法的发展及其特点,介绍了流动注射在线分析技术,包括流动注射-原子光谱法、流动注射-分光光度法和流动注射-电化学分析法等联用技术在地质样品分析中的应用情况。 相似文献
129.
地质样品中稀土总量的X射线荧光分析法测定 总被引:1,自引:0,他引:1
本文研究了稀土元素Ce的质量分数wCe与由Ce至Lu12元素质量分数之和w12(Nd除外)间的关系,发现wCe和w12间存在明显一致的线性相关性。回归w12-ICe标准工作曲线,实现了w12的直接测定。方法采用直接粉末压片制样,光谱仪测定wCe,wLa,wNd,wY,w12参数条件实现与稀土总量的转换。按本法对标准物质进行单项测定,结果令人满意 相似文献
130.