Field and geochemical characteristics of the Mesoarchean ( 3075 Ma) Ivisaartoq greenstone belt, southern West Greenland: Evidence for seafloor hydrothermal alteration in supra-subduction oceanic crust

The Mesoarchean (ca. 3075 Ma) Ivisaartoq greenstone belt in southern West Greenland includes variably deformed and metamorphosed pillow basalts, ultramafic flows (picrites), serpentinized ultramafic rocks, gabbros, sulphide-rich siliceous layers, and minor siliciclastic sedimentary rocks. Primary magmatic features such as concentric cooling-cracks and drainage cavities in pillows, volcanic breccia, ocelli interpreted as liquid immiscibility textures in pillows and gabbros, magmatic layering in gabbros, and clinopyroxene cumulates in ultramafic flows are well preserved in low-strain domains. The belt underwent at least two stages of calc-silicate metasomatic alteration and polyphase deformation between 2963 and 3075 Ma. The stage I metasomatic assemblage is composed predominantly of epidote (now mostly diopside) + quartz + plagioclase ± hornblende ± scapolite, and occurs mainly in pillow cores, pillow interstitials, and along pillow basalt-gabbro contacts. The origin of this metasomatic assemblage is attributed to seafloor hydrothermal alteration. On the basis of the common presence of epidote inclusions in diopside and the local occurrence of epidote-rich aggregates, the stage I metasomatic assemblage is interpreted as relict epidosite. The stage II metasomatic assemblage occurs as concordant discontinuous layered calc-silicate bodies to discordant calc-silicate veins commonly associated with shear zones. The stage II metasomatic assemblage consists mainly of diopside + garnet + amphibole + plagioclase + quartz ± vesuvianite ± scapolite ± epidote ± titanite ± calcite ± scheelite. Given that the second stage of metasomatism is closely associated with shear zones and replaced rocks with an early metamorphic fabric, its origin is attributed to regional dynamothermal metamorphism. The least altered pillow basalts, picrites, gabbros, and diorites are characterized by LREE-enriched, near-flat HREE, and HFSE (especially Nb)-depleted trace element patterns, indicating a subduction zone geochemical signature. Ultramafic pillows and cumulates display large positive initial ε_Nd values of + 1.3 to + 5.0, consistent with a strongly depleted mantle source. Given the geological similarities between the Ivisaartoq greenstone belt and Phanerozoic forearc ophiolites, we suggest that the Ivisaartoq greenstone belt represents Mesoarchean supra-subduction zone oceanic crust.     

Facies architecture of a silicic intrusion-dominated volcanic centre at Highway–Reward, Queensland, Australia

The Highway–Reward massive sulphide deposit is hosted by a silicic volcanic succession in the Cambro-Ordovician Seventy Mile Range Group, northeastern Australia. Three principal lithofacies associations have been identified in the host succession: the volcanogenic sedimentary facies association, the primary volcanic facies association and the resedimented syn-eruptive facies association. The volcanogenic sedimentary facies association comprises volcanic and non-volcanic siltstone and sandstone turbidites that indicate submarine settings below storm wave base. Lithofacies of the primary volcanic facies association include coherent rhyolite, rhyodacite and dacite, and associated non-stratified breccia facies (autoclastic breccia and peperite). The resedimented volcaniclastic facies association contains clasts that were initially formed and deposited by volcanic processes, but then redeposited by mass-flow processes. Resedimentation was more or less syn-eruptive so that the deposits are essentially monomictic and clast shapes are unmodified. This facies association includes monomictic rhyolitic to dacitic breccia (resedimented autoclastic facies), siltstone-matrix rhyolitic to dacitic breccia (resedimented intrusive hyaloclastite or resedimented peperite) and graded lithic-crystal-pumice breccia and sandstone (pumiceous and crystal-rich turbidites). The graded lithic-crystal-pumice breccia and sandstone facies is the submarine record of a volcanic centre(s) that is not preserved or is located outside the study area. Pumice, shards, and crystals are pyroclasts that reflect the importance of explosive magmatic and/or phreatomagmatic eruptions and suggest that the source vents were in shallow water or subaerial settings.The lithofacies associations at Highway–Reward collectively define a submarine, shallow-intrusion-dominated volcanic centre. Contact relationships and phenocryst populations indicate the presence of more than 13 distinct porphyritic units with a collective volume of 0.5 km³. Single porphyritic units vary from <10 to 350 m in thickness and some are less than 200 m in diameter. Ten of the porphyritic units studied in the immediate host sequence to the Highway–Reward deposit are entirely intrusive. Two of the units lack features diagnostic of their emplacement mechanism and could be either lavas and intrusions. Direct evidence for eruption at the seafloor is limited to a single partly extrusive cryptodome. However, distinctive units of resedimented autoclastic breccia indicate the presence nearby of additional lavas and domes.The size and shape of the lavas and intrusions reflect a restricted supply of magma during eruption/intrusion, the style of emplacement, and the subaqueous emplacement environment. Due to rapid quenching and mixing with unconsolidated clastic facies, the sills and cryptodomes did not spread far from their conduits. The shape and distribution of the lavas and intrusions were further influenced by the positions of previously or concurrently emplaced units. Magma preferentially invaded the sediment, avoiding the older units or conforming to their margins. Large intrusions and their dewatered envelope may have formed a barrier to the lateral progression and ascent of subsequent batches of magma.     

Geochemical evidence for Late Cretaceous marginal arc-to-backarc transition in the Sabzevar ophiolitic extrusive sequence,northeast Iran

The ophiolitic extrusive sequence, exposed in an area north of Sabzevar, has three major parts: a lower part, with abundant breccia, hyaloclastic tuff, and sheet flow, a middle part with vesicular, aphyric pillow lava, and an upper part with a sequence of lava and volcanic-sedimentary rocks. Pelagic limestone interlayers contain Late Cretaceous (Maastrichtian–Late Maastrichtian) microfauna. The supra-ophiolitic series includes a sequence of turbidititic and volcanic-sedimentary rocks with lava flow, aphyric and phyric lava, and interlayers of pelagic limestone and radiolarian chert. Paleontological investigation of the pelagic limestone and radiolarite interlayers in this series gives a Late Cretaceous age, supporting the idea that the supra-ophiolitic series formed in a trough, synchronous with the Sabzevar oceanic crust during the Late Cretaceous. Geochemical data indicate a relationship between lava in the upper part of the extrusive sequence and lava in the supra-ophiolitic series. These lavas have a calc-alkaline to almost alkaline characteristic, and show a clear depletion in Nb and definite depletions in Zr and Ti in spider diagrams. Data from these rocks plot in the subduction zone field in tectonomagmatic diagrams. The concentration and position of the heavy rare earth elements in the spider diagrams, and their slight variation, can be attributed to partial melting of the depleted mantle wedge above the subducted slab, and enrichment in the LILE can be attributed to subduction components (fluid, melt) released from the subducting slab. In comparison, the sheet flow and pillow lava of the lower and middle parts of the extrusive sequence show OIB characteristics and high potassium magmatic and shoshonitic trends, and their spider diagram patterns show Nb, Zr, and Ti depletions. The enrichment in the LILE in the spider diagram patterns suggest a low rate of partial melting of an enriched, garnet-bearing mantle. It seems that the marginal arc basin, in which the Sabzevar ophiolite was forming, experienced lithospheric extension in response to slab rollback. This process, which formed a backarc basin, may have aborted the embryonic arc, stopped arc magmatism, and led to the rise of mantle diapirs. The extrusive ophiolite sequence, north of Sabzevar probably formed during the transition from a marginal arc basin to a backarc basin during the Late Cretaceous.     

Geochemistry of basaltic lavas from the southern Lau Basin: input of compositionally variable subduction components

We present new major element, trace element, and Sr–Nd–Pb isotope data for 18 basaltic lavas and six glasses collected in situ from the Eastern Lau Spreading Centre (ELSC) and the Valu Fa Ridge (VFR). All lava samples are aphanitic and contain rare plagioclase and clinopyroxene microlites and microphenocrysts. The rocks are sub-alkaline and range from basalt and basaltic andesite to more differentiated andesite. In terms of trace element compositions, the samples are transitional between typical normal mid-ocean ridge basalt (MORB) and island arc basalt. Samples from the VFR have higher large ion lithophile element/high field strength element ratios (e.g. Ba/Nb) than the ELSC samples. VFR and ELSC Sr–Nd isotopic compositions plot between Indian MORB and Tonga arc lavas, but VFR samples have higher ⁸⁷Sr/⁸⁶Sr for a given ¹⁴³Nd/¹⁴⁴Nd ratio than ELSC analogues. The Pb isotopic composition of ELSC lavas is more Indian MORB-like, whereas that of VFR lavas is more Pacific MORB-like. Our new data, combined with literature data for the Central Lau Spreading Centre, indicate that the mantle beneath the ELSC and VFR spreading centres was originally of Pacific type in composition, but was displaced by Indian-type mantle as rifting propagated to the south. The mantle beneath the spreading centres also was variably affected by subduction-induced metasomatism, mainly by fluids released from the altered, subducting oceanic crust; the influence of these components is best seen in VFR lavas. To a first approximation, the effects of underflow on the composition and degree of partial melting of the mantle source of Lau spreading centre lavas inversely correlate with distance of the spreading centres from the Tonga arc. Superimposed on this general process, however, are the effects of the local geographic contrasts in the composition of subduction components. The latter have been transferred mainly by dehydration-generated fluids into the mantle beneath the Tonga supra-subduction zone.     

Geodynamic significance of the Cretaceous pillow basalts from North Anatolian Ophiolitic Mélange Belt (Central Anatolia,Turkey): geochemical and paleontological constraints

The most widespread blocks within the Cretaceous ophiolitic mélange (North Anatolian ophiolitic mélange) in Central Anatolia (Turkey) are pillow basalts, radiolarites, other ophiolitic fragments and Jurassic-Cretaceous carbonate blocks. The pillow basalts crop out as discrete blocks in close relation to radiolarites and ophiolitic units in Cretaceous ophiolitic mélange.

The geochemical results suggest that analyzed pillow basalts are within-plate ocean island alkali basalts. The enrichment of incompatible elements (Nb, Ta, Light REE, Th, U, Cs, Rb, Ba, K) demonstrates the ocean island environment (both tholeiites and alkali basalts) and enriched MORB. Dated calcareous intrafills and biodetrital carbonates reveal an age span of Callovian—Early Aptian. The thin-shelled protoglobigerinids, belonging to the genus Globuligerina, in the calcareous intrafills between pillow basalt lobes indicates a Callovian—Barremian age interval, most probably, Valanginian to Late Barremian. The volcanic and radiolarite detritus-bearing orbitolinid—Baccinella biodetrital carbonates dated as Late Barremian-Early Aptian in age, were probably deposited around atolls and have a close relationship with the ocean island pillow basalts.

The results collectively support the presence of a seamount on the Neo-Tethyan oceanic crust during the Valanginian—Late Barremian and atolls during the Late Barremian-Early Aptian interval. The presence of an oceanic crust older than that seamount along the Northern Branch of Neo-Tethys is conformable with the geodynamic evolution of the Tethys.     

海南岛晚古生代洋岛玄武岩(OIB型)的发现及地球动力学暗示

海南岛西部的军营-邦溪地区产出一套变质的、晚古生代镁铁质-超镁铁质熔岩系列.根据地质学、岩石学、矿物学和地球化学研究,该套岩石可划分为高镁和低镁两个系列,前者以高镁(Mg# =76.9～81.3)为特征,后者以低镁(Mg#=40.7～48.4)、高钛含量(2.34％ ～3.27％)为特征.这套镁铁质-超镁铁质熔岩具有LREE富集[(La/Yb)N =2.40～7.58]和无明显Eu异常的稀土配分模式,以及无Nb亏损、但略具轻微Ta正异常的微量元素原始地幔标准化曲线;87Sr/86Sr (270Ma)和εNd(270Ma)比值的变化范围分别为0.70645 ～0.70956和+4.7～ +6.5,这些地球化学特征与洋岛玄武岩(OIB)极其相似.一些反映源区特征的比值,如Ta/Hf、Th/Nb、Nb/Zr、La/Ta、La/Sm、(La/Nb)PM、(Th/Ta)PM等均指示其地幔柱成因,是石榴子石二辉橄榄岩地幔低程度部分熔融形成的产物.橄榄石斑晶的矿物化学进一步揭示,岩石的高镁性质是由橄榄石堆晶引起的,而橄榄石斑晶低的Fo(68 ～77)值,暗示其原始岩浆为低镁的玄武质岩浆;低镁系列相对于高镁系列明显低的Cr、Ni含量,说明岩浆随后发生了橄榄石和单斜辉石的分离结晶作用.军营-邦溪地区晚古生代OIB型洋岛玄武岩可能代表了东古特提斯洋在海南岛的又一记录,该认识对深入探讨华南古特提斯洋的演化及其在海南岛的响应提供了新的证据.     

Lithium isotopic composition of Central American Volcanic Arc lavas: implications for modification of subarc mantle by slab-derived fluids

Li contents and isotopic compositions were determined for a suite of well-characterized basaltic lavas from the Central American Volcanic Arc (CAVA). Variable Li/Y (0.2–0.5), Li/Sc (0.1–0.4), and δ⁶Li values (+2.6 to −7.7‰) attest to significant compositional heterogeneity in the subarc mantle. Within specific arc segments, these parameters correlate strongly with each other and with a number of other constituents (e.g., K, Rb, Ba, B/La, ¹⁰Be/⁹Be, ⁸⁷Sr/⁸⁶Sr, U/Ce, and ²³⁰Th/²³²Th, among others); these correlations are particularly strong for Nicaragua samples. Coupling of this particular set of constituents is best explained in terms of addition of ‘subduction components' to the subarc mantle. Moreover, their selective enrichment with respect to relatively fluid-immobile incompatible elements signifies the dominance of fluid vs. silicate melt transport of slab components to the subarc mantle. Several interesting nuances are revealed by the Li data. First, although Li and B are strongly correlated in both Costa Rica and Nicaragua, there are systematic along-strike variations in Li/B that are consistent with these elements having different ‘fluid release patterns' from subducted slab segments. For example, Li/B is highest in Costa Rica where auxiliary evidence indicates higher subduction zone temperatures; apparently B is preferentially depleted and Li retained in the slab under warmer conditions. The same relations are reflected in Li/¹⁰Be and other subduction tracer systematics, all of which point to larger subduction contributions below Nicaragua. Yet, even Nicaragua lavas vary widely in levels of subduction enrichment. High-Ti basalts from Nejapa are the least enriched and have the highest δ⁶Li (1.4 to 2.6‰); these values are greater than in fresh MORB (ca. −4‰) and are not easily explained by additions of subducted Li because most oceanic crustal rocks and marine sediments have lower δ⁶Li than MORB (with typical values between −8 and −20‰). Thus, it appears the Nejapa data may be representative of isotopically light mantle domains. Relatively light δ⁶Li values in an undepleted spinel lherzolite (+11.3‰) from Zabargad Is. (Red Sea) and in primitive backarc basalts (−1.6 to −0.5‰) from Lau Basin support this conclusion. Considering representative fluid and mantle endmember compositions, the CAVA data are consistent with limited (up to a few percent) additions of slab-derived fluids to a heterogeneous mantle containing variably depleted and enriched domains to form the respective magma sources. In our view, the subarc mantle is heterogeneous on a small scale, but some arc sectors clearly received greater slab inputs than others.     

Palaeointensity studies of a late Permian lava succession from Guizhou Province, South China: implications for post-Kiaman dipole field behaviour

Palaeomagnetic results are presented from a volcanic sequence in Zhijin County, Guizhou Province, Southern China. The lavas and associated volcanic breccias comprising the sequence represent a southern extension of the Emeishan volcanic province. Biostratigraphic dating of interbedded limestone units and stratigraphic constraints indicate that the section formed during the late Permian (∼263–255  Ma), and is thus somewhat older than the Emei stratotype section in Sichuan Province, and close in age to reported estimates of the termination of the Permo-Carboniferous (Kiaman) reverse superchron. Rock magnetic analyses and reflected light microscopy indicate that the magnetic mineralogy of the lava units is dominated by fresh, primary magnetites containing a significant fraction of single-domain grains. Thermal demagnetization behaviour of the breccia units is poor, but most lava samples have one or two components of remanence above 250 °C. The normal polarity characteristic remanence held by the lavas implies a post-Kiaman age for this succession and suggests that the termination of the Kiaman occurred prior to 263  Ma, supporting recently published estimates. According to standard criteria, Thellier palaeointensity results from the lavas are of good quality and reveal that the dipole field strength was comparatively low shortly after the termination of the superchron. 80 per cent of samples record relative VDM values in the range 42–52 per cent of the present-day value, supporting recent studies of mid-Kiaman field intensity. This suggests that a low-energy dipole existed at least between 300 and 255  Ma and does not appear to have been confined to the stable reverse polarity interval.     

辽东半岛早元古宙枕状熔岩特征

辽东半岛枕状熔岩位于辽河群大石桥组底部的变质基性岩中。呈椭球状个体,具白色硅铝质外壳。岩枕分带明显,由外向内可分为枕壳、冷凝边、枕内相。枕状熔岩的岩石学、岩石化学和地球化学研究表明,它是海底玄武岩的产物。枕状熔岩的发现为揭示广泛发育于辽东半岛早元古宙变质基性岩的成因提供了证据。