Rb2Ca[B4O5(OH)4]2·8H2O溶解及相转化过程的研究

利用IR光谱和Raman光谱等实验手段,对25℃时Rb2Ca[B4O5(OH)4]2·8H2O的溶解及相转化过程进行了初步探索,结果表明,Rb2Ca[B4O5(OH)4]2·8H2O溶于水后,硼在溶液中主要以B(OH)3和[B(OH)4]-的形式存在,残留固相由开始的无定形水合三硼酸钙,最终部分转变为Ca2[B3O3(OH)5]2·8H2O晶体。     

The crystal and magnetic structure of Li-aegirine LiFe3+Si2O6: a temperature-dependent study

Single crystals of Li-aegirine LiFe³⁺Si₂O₆ were synthesized at 1573?K and 3?GPa, and a polycrystalline sample suitable for neutron diffraction was produced by ceramic sintering at 1223?K. LiFe³⁺Si₂O₆ is monoclinic, space group C2/c, a=9.6641(2)?Å, b= 8.6612(3)?Å, c=5.2924(2)?Å, β=110.12(1)^° at 300?K as refined from powder neutron data. At 229?K Li-aegirine undergoes a phase transition from C2/c to P2₁ /c. This is indicated by strong discontinuities in the temperature variation of the lattice parameters, especially for the monoclinic angle β and by the appearance of Bragg reflections (hkl) with h+k≠2n. In the low-temperature form two non-equivalent Si-sites with 〈SiA–O〉=1.622?Å and 〈SiB–O〉=1.624?Å at 100?K are present. The bridging angles of the SiO₄ tetrahedra O3–O3–O3 are 192.55(8)° and 160.02(9)° at 100?K in the two independent tetrahedral chains in space group P2₁ /c, whereas it is 180.83(9)° at 300?K in the high-temperature C2/c phase, i.e. the chains are nearly fully expanded. Upon the phase transition the Li-coordination changes from six to five. At 100?K four Li–O bond lengths lie within 2.072(4)–2.172(3)?Å, the fifth Li–O bond length is 2.356(4)?Å, whereas the Li–O3?A bond lengths amount to 2.796(4)?Å. From ⁵⁷Fe Mössbauer spectroscopic measurements between 80 and 500?K the structural phase transition is characterized by a small discontinuity of the quadrupole splitting. Temperature-dependent neutron powder diffraction experiments show first occurrence of magnetic reflections at 16.5?K in good agreement with the point of inflection in the temperature-dependent magnetization of LiFe³⁺Si₂O₆. Distinct preordering phenomena can be observed up to 35?K. At the magnetic phase transition the unit cell parameters exhibit a pronounced magneto-striction of the lattice. Below T _N Li-aegirine shows a collinear antiferromagnetic structure. From our neutron powder diffraction experiments we extract a collinear antiferromagnetic spin arrangement within the a–c plane.     

1.0GPa和常温至1100 ℃条件下角闪石斜长片麻岩的V_p变化:实验测量与理论计算

在1．0GPa、常温至1100℃条件下测量了角闪石斜长片麻岩的纵波速度（Vp）,并统计了不同温度实验产物中各种矿物的体积百分含量。结果显示,1．0GPa下,角闪石斜长片麻岩的Vp首先随温度升高（室温至700℃）缓慢降低约6％,然后（700—850℃）快速降低约6％,再（850～950℃）转而急剧升高15％～25％,最后（T〉950℃）又快速下降。实验产物分析表明在高温高压下α-石英-β石英相变和岩石部分熔融是岩石Vp异常变化的主要因素。由取样产物的矿物含量和弹性参数,计算了各温度条件下岩石的Vp得出与实验测量相同的波速-温度变化趋势,即Vp随温度升高先缓慢降低,接着快速降低后又急剧升高,最后又快速减小。实验测量和理论计算对比研究表明,通过高温高压下岩石中的物相变化观测结果进行岩石波速的计算,是检验岩石弹性波速测量结果和研究地球内部地震波结构的一种有效方法。     

Heat capacity and phase equilibria of wadeite-type K2Si4O9

The low-temperature heat capacity (C _p) of Si-wadeite (K₂Si₄O₉) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured heat capacity data is 253.8 ± 0.6 J mol⁻¹ K⁻¹, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the system K₂O–Al₂O₃–SiO₂ are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order approximations were undertaken to calculate the phase diagram in the system K₂Si₄O₉ at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure phase relations of the K₂Si₄O₉ polymorphs. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

三元体系CaCl2?SrCl2?H2O的相平衡及其在钙锶分离中的应用

采用等温溶解平衡法研究了三元体系CaCl₂?SrCl₂?H₂O温度从323.15 K到353.15 K范围内的相平衡。基于该三元体系多温下的相平衡数据,设计开展了实验室模拟南翼山油田卤水中氯化钙和氯化锶在温度323.15 K下的分离实验。实验室模拟钙锶分离实验结果表明,在323.15 K下时分离一次固相产品中的钙锶摩尔比可以从25.46:1降至1.73:1,SrCl₂的回收率为52.47 %,所得一次固相产品在323.15 K下溶解并再次蒸发。钙和锶的摩尔比从1.73:1降至1.1:1,SrCl₂的回收率为78.67 %。     

LiMn_2O_4的溶胶─凝胶─酯化法合成及性能Ⅱ 立方尖晶石的形成及其形貌

以溶胶-凝胶-酯化法在220℃即可得到纯相的LixMn2O4（0.762＜x＜1.139）尖晶石粉体材料。它在880℃时发生立方相向四方相的转变：900℃－1000℃间,四方相渐变为正交相LiMnO2,过程中有Li2MnO3生成。应用SEM、TEM观测了材料的粘度及形貌,其粒度10－40nm,粒子间极易团聚成为1-206μm的团块。以BET法测其比表面为3.6m2／g。     

岩石圈中水的临界奇异性——大规模成矿的根源

水的临界奇异性是岩石圈中许多重大地质作用的关键和枢纽,有独特的地质意义、超乎常识。水在临界点发生二级相变,许多物理化学性质奇异性突变,特别是溶解行为和热压的突变,对成矿作用影响极大。     

地震沉积学探讨

地震沉积学是用地震手段研究沉积岩及其形成过程的学科,其研究手段主要有90°相位转换和地层切片技术等。90°相位转换使地震相位具有了岩性地层意义,可以用于高频层序地层的解释;地层切片是指对某一层位内进行等比例内插切片之后用来研究各个等时地层单元的沉积体系（相）的平面展布。文章认为：①由于受地震分辨率的限制,地震沉积学目前主要应用于研究宏观的地层、岩石、沉积史和沉积体系,还没有达到全面研究沉积岩及其形成过程的程度,因此,目前的地震沉积学是利用地震手段结合井资料研究宏观的地层、岩石、沉积史和沉积体系的一门学科,它还需要进一步的发展才有可能继地震地层学、层序地层学之后真正成为一门研究沉积岩及其形成过程的新学科;②相位转换技术中转换的角度并不一定局限于90°,可以是其它角度的相位转换,这要根据层位标定的具体情况而定;③地层切片比时间切片和沿层切片更加合理,但是目前的地层切片技术还没有考虑地层的沉积速率随时间的变化,因此,地层切片还不是严格意义上等时的。     

多功能定时控制器的设计

介绍了一种多功能定时控制器的设计方法,它是由８９Ｃ５１单片机和几个主要的集成电路芯片构成,并给出了监控软件的结构框图。     

相空间中划分大尺度异常雨型的初步研究

文中针对以往雨型研究中的不足 ,从动力学角度将相空间引入到大尺度异常雨型的划分 ,通过估计EOF相平面上的概率密度函数、并确定局部极大值区域来划分主要雨型。分析表明 ,新雨型不仅再现了传统的 3类雨型特征 ,还得到了其他分型 ,并且能够反映出异常降水分布的季节内低频变化 ;分别采用 10和 2 0d低通滤波数据划分的雨型形态比较接近 ,但其种类、持续性和季节内分布等特征存在一定差异 ;雨型的气候分布与季风雨带有一定对应关系 ,其形成与夏季风异常关系密切。通过对简单直观的二维相平面问题的探讨 ,不仅证实了在相空间中划分大尺度雨型的可行性 ,也为进一步在高维空间中讨论雨型问题提供了依据。