葡萄石的热膨胀性与压缩性及其地质意义

利用同步辐射X射线衍射及拉曼光谱技术对葡萄石分别进行了原位高温及原位高压实验。原位高温实验结果表明葡萄石的热膨胀系数为K=1. 77(3)×10~(-5)K~(-1),轴向热膨胀系数具有各向异性(α_aα_bα_c),葡萄石在1073K时开始发生脱水反应,分解为钙长石及硅灰石。原位高压X射线衍射实验结果表明,在大于12. 4GPa时,葡萄石的晶胞参数发生不连续变化,可能发生了相变;在24. 0GPa左右,葡萄石发生不可逆的非晶化转变。原位高压拉曼光谱表明,葡萄石在12. 6GPa左右发生相变,这一相变很可能与其[(Si,Al)O_4]四面体中的Si发生有序排列有关。结合葡萄石的热膨胀性及压缩性,我们确定了葡萄石在高温高压下的稳定范围,这一结果对认识上地幔中含水矿物的状态以及地幔中水的来源有重要意义。     

Crust and upper mantle heterogeneities in the southwest Pacific from surface wave phase velocity analysis

Direct earthquake-to-station Rayleigh and Love wave data observed on high gain broadband records are analyzed in order to improve the lateral resolution of the uppermost mantle in the southwest Pacific region. We used data of nine permanent Geoscope and Iris stations located in the southern hemisphere and nine other stations as part of two temporary networks, the first one installed in New Caledonia and Vanuatu (hereafter named Cavascope network) by ORSTOM and the EOST from Louis Pasteur University in Strasbourg (France) and the second one installed in the Fiji, Tonga and Niue islands (hereafter named Spase network) by Washington University in St. Louis (USA). In order to collect more significant details on the surficial structures, we included the analysis of short period waves down to 8 s. A multiple frequency filtering technique has been used to recover phase velocities of Rayleigh and Love waves for selected earthquakes with magnitude greater than 5.5 and with known centroid moment tensor (CMT). About 1100 well-distributed seismograms have been processed in the period range 8–100 s and corrections for topography and water depth have been applied to the observed phase velocities. The geographical distribution of phase velocity anomalies have then been computed using the tomographic method developed by Montagner [Montagner, J.P., 1986a. Regional three-dimensional structures using long-period surface waves. Ann. Geophys. 4 (B3), 283–294]. Due to a poor knowledge of dense, well-distributed, crustal thickness values and corresponding velocity models, we did not perform or speculate on the construction of an S-wave 3D velocity model; therefore, we limited this study to the interpretation of the phase velocity distribution. The location of phase velocity anomalies are well determined and the deviations are discussed within the framework of the geological context and compared with other tomographic models. At long periods, from 40 s to 100 s, our results agree well with most of previous studies: the tomographic imaging shows a large contrast between low and high phase velocities along the Solomon, New Hebrides and Fiji–Tonga trenches. The lowest phase velocity anomalies are distributed beneath northern and southern Fiji basins and the Lau basin (corresponding to the volume situated just above the dipping slabs), whereas the highest values are displayed beneath the Pacific plate and the eastern part of Indian plate downgoing under the North Fiji basin. At shorter periods, our results show that the phase velocity distributions are well correlated with the large structural crustal domains. The use of local temporary broadband stations in the central part of the studied area gives us the opportunity to observe surface waves showing well-dispersed trains, allowing extended velocity measurements down to 8 s although aliasing due to multipaths become important. The continental regions (Eastern Australia, New Guinea, Fiji islands and New Zealand) show low velocities which are likely due to thick continental crust, whereas the Tasmanian, D'Entrecasteaux, and the Northern and Southern Fiji basins are characterized by higher velocities suggesting thinner oceanic crust. Additional analysis including the anisotropic case and S-wave velocity inversion with depth is in progress.     

非线性时间序列分析的最新进展及其在地球科学中的应用前景

评述了非线性时间序列分析的最新进展,包括相空间重构、序列性质的鉴别、建模与预报,同时介绍了非线性时间序列分析在地球科学中的应用概况。     

青藏高原东北缘及周边地区基于程函方程的面波层析成像

利用"中国地震科学台阵探测"在南北地震带北段布设的670套宽频带地震台站记录到的面波资料,使用新近发展的程函方程面波层析成像方法,获得了青藏高原东北缘及周边地区12~60 s周期范围比以往成像结果具有更高分辨率的瑞利面波相速度分布图像.青藏高原东北缘的祁连褶皱系西段、秦岭褶皱系西段和松潘一甘孜褶皱系,在16~60s周期范围内均显示出明显的低速异常分布,表明该地区的地壳力学强度较低,在强烈的构造应力作用下易发生形变.与西段不同,祁连褶皱系东段和秦岭褶皱系中段的相速度分布特征揭示,其中下地壳的速度明显高于高原内部区域.鄂尔多斯块体整体上表现为稳定块体具有的高速特征,但其西部边缘在中上地壳的速度比块体中部地区偏低,且存在一定的不均匀性.鄂尔多斯块体西北缘的临河断陷盆地和西缘的银川断陷盆地,在较短的周期范围内(12~20 s)表现为局部低速特征,但与银川断陷盆地不同,临河断陷盆地的低速特征可一直延续至60 s周期以上,表明该盆地下方地壳及上地幔速度明显偏低,可能与深部热作用有关.阿拉善块体与其北部地区的速度差异主要表现在中上地壳,这一现象值得今后进一步探讨.基于程函方程面波层析成像方法给出了青藏高原东北缘及周边地区高分辨率的成像结果,揭示了以往面波层析成像难以获得的深部细节特征,为该地区的深部构造研究提供了新的信息.     

基于TIE方程的空间域相位恢复迭代算法

利用同步辐射X射线同轴显微层析(CT)方法对页岩进行扫描成像是一种无损的,对研究页岩孔裂隙大小、形态、三维结构及连通性等微观结构特征有重要意义的方法.同步辐射的引入将在物理上为提高页岩成像的分辨率提供了可能,在相位-吸收二重性假设下利用光强传递TIE(transport-of-intensity)方程可以较好地抑制由于相位信息带来的"边缘增强"效应,但该问题本质上是不适定的反演问题.本文根据实际问题构造模型,提出了一种与传统基于频域方法不同的,基于空间域的相位恢复迭代算法,并采用迭代Tikhonov正则化在数值上解决了噪声干扰下的不稳定性·问题.研究结果表明,新方法的残差仅为频域方法的1%左右,该方法可用于未来实际数据的处理.     

Analytical approach for sheet flow transport in purely acceleration-skewed oscillatory flow

An instantaneous analytical approach is developed to predict sheet flow transport in purely acceleration-skewed oscillatory flow. The approach is derived from exponential approximations of velocity and concentration profiles above a mobile seabed, and it particularly considers factors of phase lead; phase lag (i.e. phase residual and phase shift); acceleration modification; and asymmetries in shear stress, roughness height, and boundary layer development. The approach can predict net boundary layer flow above a mobile seabed, and can revert to the classical bedload model. Instantaneous and net sediment transport rates are studied using the approach. The instantaneous sediment transport rate in an onshore flow stage can be approximated by a power function of velocity in which the exponent is confirmed to range between 1 and 5 with a decrease in the phase residual. The net sediment transport rate predicted using the approach is validated using a considerable amount of measured data, and compared with existing instantaneous and half-period type models that consider the phase lag or acceleration modification. For the net sediment transport rate in purely acceleration-skewed oscillatory flow, the phase residual is less important than the acceleration-skewed boundary layer difference between onshore and offshore acceleration stages.     

Sorption and Chemical Reactions of PAHs with Dissolved Humic Substances and Related Model Polymers

Sorption coefficients measured for PAHs on dissolved humic substances by SPME and FQT were found to be inevitably different and method‐dependent – SPME provides activity‐based and FQT concentration‐based sorption coefficients. Poly(acrylic acid) esters as well‐defined model polymers were used in sorption experiments, leading to the conclusion that short aliphatic chains are more effective in binding PAHs than aromatic moieties. FQT was inappropriate to measure sorption coefficients for the interaction of pyrene with poly(acrylic acid) esters but the experiments revealed a characteristic shift in the fluorescence spectrum. Using pyrene as a probe for the molecular environment in the sorbed state, the observed spectral shift indicated a highly hydrophobic microenvironment. The empirical relationships between lg K_DOC and lg K_OW were generalized on the basis of a modified Flory‐Huggins concept. Introducing only one sorbent‐specific parameter, the solubility parameter δ_DOM, the calculation of sorption coefficients became possible for a wide range of HOCs using fundamental data readily available from the literature. Long‐term experiments showed that reactive PAHs (such as acenaphthylene and 9‐methylanthracene) are able to react with HAs under strictly abiotic and anoxic conditions, whereas less reactive PAHs (such as naphthalene and dihydroanthracene) do not form bound residues. The HA reveals two functions in the interaction, behaving as a reaction partner and as a protecting ligand.     

GPS相位平滑伪距差分定位中若干问题的探讨

伪距差分定位方法是利用基准站的伪距差对流动站的观测伪距进行改正,得到流动站改正后的伪距观测值后再解算流动站坐标。而利用载波相位历元间的差值对伪距进行平滑,可以减少测量噪声从而提高定位精度,但这都需要在一定的条件下才能得到保证。比如粗差的探测与周跳修复（算法中要利用载波相位观测量）等问题,介绍了自行编制的软件对相关问题的处理方法,并通过试验验证了方法的有效性。     

Quick Phase Identification for Dense Seismic Array with Aid from Long Term Phase Records of Co-located Sparse Permanent Stations

The phase identification and travel time picking are critical for seismic tomography, yet it will be challenging when the numbers of stations and earthquakes are huge. We here present a method to quickly obtain P and S travel times of pre-determined earthquakes from mobile dense array with the aid from long term phase records from co-located permanent stations. The records for 1 768 M ≥ 2.0 events from 2011 to 2013 recorded by 350 ChinArray stations deployed in Yunnan Province are processed with an improved AR-AIC method utilizing cumulative envelope and rectilinearity. The reference arrivals are predicted based on phase records from 88 permanent stations with similar spatial coverage, which are further refined with AR-AIC. Totally, 718 573 P picks and 512 035 S picks are obtained from mobile stations, which are 28 and 22 times of those from permanent stations, respectively. By comparing the automatic picks with manual picks from 88 permanent stations, for M ≥ 3.0 events, 81.5% of the P-pick errors are smaller than 0.5 second and 70.5% of S-pick errors are smaller than 1 second. For events with a lower magnitude, 76.5% P-pick errors fall into 0.5 second and 69.5% S-pick errors are smaller than 1 second. Moreover, the Pn and Sn phases are easily discriminated from directly P/S, indicating the necessity of combining traditional auto picking and integrating machine learning method.     

利用远震研究四川盆地及其周缘瑞利面波相速度和方位各向异性

基于四川盆地及周边的245个宽频带台站2010年9月—2014年9月期间的远震记录,提取双台路径瑞利面波相速度频散资料,反演得到四川盆地20～120s的高分辨率瑞利面波相速度及各向异性空间分布.在丰富区域地球物理基础数据的同时,结合已有研究成果对地壳上地幔变形耦合进行探讨,结果表明短周期(20～30s)的相速度分布与四川盆地的地质构造特征相吻合,作为川滇地块、松潘—甘孜地块和四川盆地之间的边界——龙门山断裂带和鲜水河断裂带对上述三个地块上地壳的速度结构具有明显的控制作用;松潘—甘孜地块,特别是川滇地块中下地壳普遍表现为明显的低速异常,表明中下地壳相对软弱;而四川盆地的中下地壳整体呈现相对高速,表明四川盆地具有相对坚硬的中下地壳.研究区域东南角接近北扬子地块与南扬子地块的缝合部位,呈现高速异常.四川盆地南部和东南邻区不同周期均具有较强的各向异性,且快波方向较为一致,反映这些地区不同深度变形耦合较好.四川盆地西部、北部及东北部邻区,不同周期的各向异性快波方向变化较大,不同深度变形耦合较差.这些特征与绕喜马拉雅东构造结的物质流动被扬子地块的高速地壳阻挡的宏观认识基本一致.