地震沉积学探讨

地震沉积学是用地震手段研究沉积岩及其形成过程的学科,其研究手段主要有90°相位转换和地层切片技术等。90°相位转换使地震相位具有了岩性地层意义,可以用于高频层序地层的解释;地层切片是指对某一层位内进行等比例内插切片之后用来研究各个等时地层单元的沉积体系（相）的平面展布。文章认为：①由于受地震分辨率的限制,地震沉积学目前主要应用于研究宏观的地层、岩石、沉积史和沉积体系,还没有达到全面研究沉积岩及其形成过程的程度,因此,目前的地震沉积学是利用地震手段结合井资料研究宏观的地层、岩石、沉积史和沉积体系的一门学科,它还需要进一步的发展才有可能继地震地层学、层序地层学之后真正成为一门研究沉积岩及其形成过程的新学科;②相位转换技术中转换的角度并不一定局限于90°,可以是其它角度的相位转换,这要根据层位标定的具体情况而定;③地层切片比时间切片和沿层切片更加合理,但是目前的地层切片技术还没有考虑地层的沉积速率随时间的变化,因此,地层切片还不是严格意义上等时的。     

Polymorphic phase transition in Superhydrous Phase B

We synthesized superhydrous phase B (shy-B) at 22 GPa and two different temperatures: 1200°C (LT) and 1400°C (HT) using a multi-anvil apparatus. The samples were investigated by transmission electron microscopy (TEM), single crystal X-ray diffraction, Raman and IR spectroscopy. The IR spectra were collected on polycrystalline thin-films and single crystals using synchrotron radiation, as well as a conventional IR source at ambient conditions and in situ at various pressures (up to 15 GPa) and temperatures (down to −180°C). Our studies show that shy-B exists in two polymorphic forms. As expected from crystal chemistry, the LT polymorph crystallizes in a lower symmetry space group (Pnn2), whereas the HT polymorph assumes a higher symmetry space group (Pnnm). TEM shows that both modifications consist of nearly perfect crystals with almost no lattice defects or inclusions of additional phases. IR spectra taken on polycrystalline thin films exhibit just one symmetric OH band and 29 lattice modes for the HT polymorph in contrast to two intense but asymmetric OH stretching bands and at least 48 lattice modes for the LT sample. The IR spectra differ not only in the number of bands, but also in the response of the bands to changes in pressure. The pressure derivatives for the IR bands are higher for the HT polymorph indicating that the high symmetry form is more compressible than the low symmetry form. Polarized, low-temperature single-crystal IR spectra indicate that in the LT-polymorph extensive ordering occurs not only at the Mg sites but also at the hydrogen sites.     

基于U形卷积神经网络的震相识别与到时拾取方法研究

精确获取震相到时是地震定位和地震走时成像等研究的重要基础.近年来,随着地震台站的不断加密,地震台网监测到的地震数量成倍增长,发展快速、准确、适用性强的震相到时自动拾取算法是地震行业的迫切需求.本文在前人工作基础上,发展了Pg、Sg震相自动识别与到时拾取的U网络算法（Unet_cea）,使用汶川余震和首都圈地震台网记录的89344个不同震级、不同信噪比的样本进行训练和测试.研究表明,U网络能够较好地识别Pg、Sg震相类型和拾取到时,Pg、Sg震相的正确识别率分别为81%和79.1%,与人工标注到时的均方根误差分别为0.41 s和0.54 s.U网络在命中率、均方根误差等性能指标上均明显优于STA/LTA和峰度分析自动拾取方法.研究获得的最优模型可以为区域地震台网的自动处理提供辅助.

     

带相敏检波器的线性可变差动变压器(LVDT)读出电路的设计

本文简单介绍了LVDT、相敏检波器和三角波发生器的工作原理及自行设计的一种实用的LVDT相敏检波读出电路。     

Mercury's integral phase curve: Phase reddening and wavelength dependence of photometric quantities

We present results of a five-filter photometric study of Mercury's integral phase curve in the Johnson-Cousins UBVRI system, performed with the 0.90-m Westerlund Telescope in Uppsala, Sweden. CCD observations were made of the integrated disk for the phase angle range 22-152°, and the study is the first to cover the extended visible spectrum of Mercury. The observations are analyzed with Hapke's semi-empirical radiative transfer-based light-scattering model and photometric quantities are derived. A statistically significant phase reddening effect of is determined for Mercury based on color index observations, which is similar to that of the Moon. Phase coefficients fit to integral absolute magnitude data and Hapke models in combination with color index data provide a phase reddening effect of which does however not provide statistically significant evidence for its presence. Phase coefficients indicate that phase reddening may be decreasing in magnitude with wavelength. As for the case with the Moon, the value of the phase integral increases with wavelength, but at an eight times higher rate. This value is consistent with the difference in the rate of change in the spectral slope-emission angle relation for the two bodies. We attribute these differences with Mercury's redder spectral slope and an increase with wavelength of the backscattering lobe amplitude in the double Henyey-Greenstein particle phase function formulation. The normal albedo of integral Mercury at 1064 nm, pertinent to the return pulse energy of the BepiColombo laser altimeter (BELA), is estimated to 0.23±0.06 with a range of 0.13-0.33 for 99% of the surface.     

非线性时间序列分析的最新进展及其在地球科学中的应用前景

评述了非线性时间序列分析的最新进展,包括相空间重构、序列性质的鉴别、建模与预报,同时介绍了非线性时间序列分析在地球科学中的应用概况。     

Analytical approach for sheet flow transport in purely acceleration-skewed oscillatory flow

An instantaneous analytical approach is developed to predict sheet flow transport in purely acceleration-skewed oscillatory flow. The approach is derived from exponential approximations of velocity and concentration profiles above a mobile seabed, and it particularly considers factors of phase lead; phase lag (i.e. phase residual and phase shift); acceleration modification; and asymmetries in shear stress, roughness height, and boundary layer development. The approach can predict net boundary layer flow above a mobile seabed, and can revert to the classical bedload model. Instantaneous and net sediment transport rates are studied using the approach. The instantaneous sediment transport rate in an onshore flow stage can be approximated by a power function of velocity in which the exponent is confirmed to range between 1 and 5 with a decrease in the phase residual. The net sediment transport rate predicted using the approach is validated using a considerable amount of measured data, and compared with existing instantaneous and half-period type models that consider the phase lag or acceleration modification. For the net sediment transport rate in purely acceleration-skewed oscillatory flow, the phase residual is less important than the acceleration-skewed boundary layer difference between onshore and offshore acceleration stages.     

Sorption and Chemical Reactions of PAHs with Dissolved Humic Substances and Related Model Polymers

Sorption coefficients measured for PAHs on dissolved humic substances by SPME and FQT were found to be inevitably different and method‐dependent – SPME provides activity‐based and FQT concentration‐based sorption coefficients. Poly(acrylic acid) esters as well‐defined model polymers were used in sorption experiments, leading to the conclusion that short aliphatic chains are more effective in binding PAHs than aromatic moieties. FQT was inappropriate to measure sorption coefficients for the interaction of pyrene with poly(acrylic acid) esters but the experiments revealed a characteristic shift in the fluorescence spectrum. Using pyrene as a probe for the molecular environment in the sorbed state, the observed spectral shift indicated a highly hydrophobic microenvironment. The empirical relationships between lg K_DOC and lg K_OW were generalized on the basis of a modified Flory‐Huggins concept. Introducing only one sorbent‐specific parameter, the solubility parameter δ_DOM, the calculation of sorption coefficients became possible for a wide range of HOCs using fundamental data readily available from the literature. Long‐term experiments showed that reactive PAHs (such as acenaphthylene and 9‐methylanthracene) are able to react with HAs under strictly abiotic and anoxic conditions, whereas less reactive PAHs (such as naphthalene and dihydroanthracene) do not form bound residues. The HA reveals two functions in the interaction, behaving as a reaction partner and as a protecting ligand.     

Monte Carlo simulation of mixing in Ca3Fe2Ge3O12–Ca4Ge4O12 garnets and implications for the thermodynamic stability of pyrope–majorite solid solution

Static lattice energy calculations, based on empirical pair potentials, were performed for a large set of structures differing in the arrangement of octahedral cations within the garnet 2 × 2 × 2 supercell. The compositions of these structures varied between Ca₃Fe₂Ge₃O₁₂ and Ca₄Ge₄O₁₂. The energies were cluster expanded using pair and quaternary terms. The derived ordering constants were used to constrain Monte Carlo simulations of temperature-dependent mixing properties in the ranges of 1,073–3,673 K and 0–10 GPa. The free energies of mixing were calculated using the method of thermodynamic integration. The calculations predict a wide miscibility gap between Fe-rich (cubic) and Fe-pure (tetragonal) garnets consistent with recent experimental observations of Iezzi et al. (Phys Chem Miner 32:197–207, 2005). It is shown that the miscibility gap arises due to a very strong cation ordering at the Fe-pure composition, driven by the charge difference between Ca²⁺ and Ge⁴⁺ cations. The structural and thermodynamic analogies between Ca–Ge and Mg–Si systems suggest that a similar miscibility gap should exist between pyrope and Mg–Si-majorite.