Influence of resonances on the phase and the group refractive indices of air

The Barrell and Sears and Edlen formulae use the Sellmeier form away from resonances, which gives a “smooth” dependence within the visible and near-infrared spectra. All known atlases indicate numerous resonances in these regions, which cause local disturbance of the dispersion curve. Anomalous dispersion may be estimated from an absorption by the Kramer-Kronig ratios. It gives a change of phase refractive index of air in a range from several ppt to 1 ppb within narrow optical regions, causing large local dispersions. Computation of the group refractive index with the use of Rayleigh's ratio shows that the influence of resonance effects may be more than several ppm. For example, the error of the group refractive index for high-precision EDM using HeNe lasers (633 nm) varies between 0.2 and 0.7 ppm, depending on the laser stability. Received: 17 July 1996 / Accepted: 27 March 1997     

GPS船体姿态测量技术研究

论述了应用GPS技术进行船体姿态解算的原理 ,介绍了基于当前技术的可行测量方法 ,对影响测量精度的几种误差源进行分析 ,并提出了系统软件设计的方案及系统设计时应注意的问题。     

相空间中划分大尺度异常雨型的进一步研究

使用1962~2001年的逐日台站降水资料,考察中国夏季大尺度低频降水的时空特征。对于20d以上的低频尺度降水异常,在前8个主要EOF模态支撑的相空间中,采用聚类分析方法划分了6种大尺度异常雨型:东北型、黄河型、秦岭淮河型、长江江南型、华南型和少雨型。分析表明,这些雨型的物理意义明确,具有较好的持续性,优于使用2维概率密度函数的划分结果,从而说明相空间中的聚类分型是整体性和区域性兼顾的划分方式,同时也证实了多维相空间的不均匀性。统计结果显示,新雨型在季节内交替出现,能够反映出大尺度异常降水的低频演变特征,并且具有不同于季风雨带变化的特点。通过分析新雨型在历史上的分布情况,并与以往分型相比较,进一步反映出新雨型划分的客观性和合理性。     

New high-pressure phases in BaCO<Subscript>3</Subscript>

Barium carbonate (BaCO₃) was examined in a diamond anvil cell up to a pressure of 73 GPa using an in situ angle-dispersive X-ray diffraction technique. Three new phases of BaCO₃ were observed at pressures >10 GPa. From 10 to 24 GPa, BaCO₃-IV had a post-aragonite structure with space group Pmmn. There are two molecules in a single unit cell (Z = 2) of the orthorhombic phase, which is same as the high-pressure phases of CaCO₃ and SrCO₃. The isothermal bulk modulus of BaCO₃-IV is K ₀ = 84(4) GPa, with V ₀ = 129.0(7) Å³ when K ₀′ = 4. The c axis of the unit cell parameter is less compressible than the a and b axes. The relative change in volume that accompanies the transformation between BaCO₃-III and BaCO₃-IV is ～6%. BaCO₃-V, which has an orthorhombic symmetry, was synthesized at 50 GPa. As the pressure increases, BaCO₃-V is transformed into tetragonal BaCO₃-VI. This transformation is likely to be second order, because the diffraction pattern of BaCO₃-V is similar to that of BaCO₃-VI, and some single peaks in BaCO₃-VI become doublets in BaCO₃-V. After decompression, the new high-pressure phases transform into BaCO₃-II. Our findings resolve a dispute regarding the stable high-pressure phases of BaCO₃.     

铁(II)-5-Br-PADAP-乳化剂OP体系析相光度法测定微量铁的应用研究

研究了铁 (Ⅱ ) 5 Br PADAP 乳化剂OP体系中的析相、显色反应的条件及其吸收光谱的分析特征 ,拟定了直接测定不同种类样品中痕量铁的分析方法。在pH =5 .0的HAC NaAC缓冲溶液中 ,Fe(Ⅱ ) 5 Br PADAP络合物具有两个吸收峰 ,分别位于λ1 =5 6 1nm与λ2 =75 4nm处。本文选择λ =75 4nm进行测定 ,其摩尔吸光系数为 :ε75 4 =3.9× 10 4L·mol- 1 ·cm- 1 。铁含量在 0～ 2 4μg范围内服从比尔定律。此方法用于样品中痕量铁的测定 ,结果准确     

Thermoelastic properties of the high-pressure phase of SnO2 determined by in situ X-ray observations up to 30 GPa and 1400 K

 In situ synchrotron X-ray experiments in the system SnO₂ were made at pressures of 4–29 GPa and temperatures of 300–1400 K using sintered diamond anvils in a 6–8 type high-pressure apparatus. Orthorhombic phase (α-PbO₂ structure) underwent a transition to a cubic phase (Pa3ˉ structure) at 18 GPa. This transition was observed at significantly lower pressures in DAC experiments. We obtained the isothermal bulk modulus of cubic phase K ₀= 252(28) GPa and its pressure derivative K ^′=3.5(2.2). The thermal expansion coefficient of cubic phase at 25 GPa up to 1300 K was determined from interpolation of the P-V-T data obtained, and is 1.7(±0.7) × 10⁻⁵ K⁻¹ at 25 GPa. Received: 7 December 1999 / Accepted: 27 April 2000     

地壳俯冲与折返过程的变质作用演化:来自高压-超高压榴辉岩相平衡模拟的证据

本文以大别山双河柯石英榴辉岩为基础,在NCKMnFMASHO体系中计算了P-T、T-M(H₂O)和P-M(H₂O)一系列相图。这些相图表明在地壳冷俯冲(地热梯度约为6℃·km^-1)过程中饱和水的变质基性岩通过脱水反应导致矿物组合演化,随着P-T条件增加,约在2.2GPa(80km)处,绿泥石被滑石取代,在2.4GPa处,蓝闪石消失,在2.5GPa处,滑石消失,在2.9GPa(105km)处,硬柱石消失。相应地可出现硬柱石蓝片岩、蓝闪石-硬柱石榴辉岩、硬柱石榴辉岩和多硅白云母榴辉岩等高压-超高压组合。俯冲基性岩中即使含有很少量的水(如0.3%~0.5%),都会在超高压硬柱石榴辉岩相条件下达到饱和。因此硬柱石会广泛出现于经历冷俯冲地壳的变质基性岩中。高压-超高压榴辉岩的折返过程受折返温度及峰期矿物组合的控制。当峰期矿物组合中含有硬柱石(±蓝闪石±滑石,T=540~600℃)时,其早期折返发生在硬柱石稳定域,受脱水反应控制,难以保存峰期矿物组合;晚期折返发生在绿帘石稳定域,岩石处于流体缺失状态,有利于保存硬柱石消失后的高压矿物组合。当峰期矿物组合中含有绿泥石、硬柱石和蓝闪石时(T<540℃),其折返过程中的脱水作用仅发生在硬柱石与绿帘石共生的狭窄区域,在硬柱石稳定域的早期折返与绿帘石稳定域的晚期折返阶段,都不发生脱水作用,岩石处于流体缺失状态,因此,虽然峰期形成的硬柱石难以保存,但峰期形成的其他矿物可能仅受轻微改造。当硬柱石消失 (T>600℃) 后,多硅白云母高压-超高压榴辉岩中含有很少量水,在早期折返过程中的很大压力范围内,岩石保持水含量不变,更容易保留峰期矿物组合。高压-超高压榴辉岩在减压至1.5GPa以下时,由于外来流体注入,发生部分水化,形成含有钠钙质、钙质角闪石榴辉岩, 它们一般不是平衡矿物组合。榴辉岩中名义上的无水矿物在减压过程中释放的水有助于榴辉岩部分水化,但不足以形成水饱和的斜长角闪岩。     

Simulation of structural phase transition in NaNO3 and CaCO3

 The order-disorder phase transitions in NaNO₃ and CaCO₃ are simulated by molecular dynamics. The simulations are based on the potentials calculated from the Gordon–Kim modified electron gas formalism extended to molecular ions. We successfully reproduced the transition temperature T _c and the abnormally large c axis thermal expansion observed in experiment. The phase transitions in NaNO₃ and CaCO₃ were found to be initiated by ±60 and ±180° reorientation of the NO₃ and CO₃ ions about the c axis. The orientations of NO₃ and CO₃ ions are continuous with six preferred calcite-type orientations above the phase-transition temperature. Received: 30 January 2001 / Accepted: 11 May 2001     

The crystal chemistry of synthetic potassium-bearing neighborite, (Na1− x K x )MgF3

A series of fluoride perovskites related to neighborite was investigated using X-ray and neutron diffraction techniques, and Rietveld profile refinement of powder diffraction data. The series (Na_{1? x} K _x )MgF₃ comprises orthorhombic (Pbnm, a?≈? , b?≈? , c?≈?2a _p , Z=4) perovskites in the compositional range 0?≤?x?≤?0.30, tetragonal perovkites (P4/mbm, a?≈? , c?≈?a _p , Z=2) in the range 0.40?≤?x?≤?0.46, and cubic phases (Pm3¯m, Z=1) for x?>?0.50. The structure of the orthorhombic neighborite is derived from the perovskite aristotype by rotation of MgF₆ octahedra about the [110] and [001] axes of the cubic subcell. The degree of rotation, measured as a composite tilt Φ about the triad axis, varies from 18.2° at x=0 to 11.2° at x=0.30 (as determined from the fractional atomic coordinates). Orthorhombic neighborite also shows a significant displacement of Na and K from the “ideal” position (≤0.25?Å). The tetragonal members of the neighborite series exhibit only in-phase tilting about the [001] axis of the cubic subcell (φ) ranging from 4.5° to 4.8° (determined from the atomic coordinates). The solid solution (Na_{1? x} K _x )MgF₃, shows a regular variation of unit-cell dimensions with composition from 3.8347?Å for the end-member NaMgF₃ (reduced to pseudocubic subcell, a _p ) to 3.9897?Å for KMgF₃. This variation is accompanied by increasing volumes of the A-site polyhedra, whereas the volume of MgF₆ octahedra initially decreases (up to x=0.40), and then increases concomitantly with K content. The polyhedral volume ratio, V _A /V _B , gradually increases towards the tetragonal structural range, in agreement with diminishing octahedral rotation in the structure. The P4/mbm-type neighborite has an “anomalous” polyhedral volume ratio (ca. 5.04) owing to the critical compression of MgF₆ polyhedra.     

Ages of peak HP-UHP metamorphism of eclogites from Chinese southwestern Tianshan: Evidence from Lu-Hf geochronologySCIEI北大核心CSCD

新疆西南天山蓝片岩-榴辉岩带是全球少有的几个经历超高压变质作用的洋壳俯冲带之一,近年来的同位素年代学研究表明其变质作用主要发生于石炭纪。然而,该蓝片岩-榴辉岩带峰期变质作用,特别是超高压变质作用的时代还未精确限定。本文选取来自该带的典型钠云母黝帘石榴辉岩(样品211-3和H76-10),在详细的岩石学和相平衡研究基础上,开展了Lu-Hf同位素年代学研究,以期获得其峰期变质作用时代。相平衡模拟结果表明两榴辉岩中石榴石均记录了升温降压型折返P-T(温度-压力)轨迹。其中,样品211-3经历了超高压变质作用,其压力峰期P-T条件为~540℃、~2.9GPa,石榴石-绿辉石-全岩Lu-Hf等时线年龄为326.9±1.3Ma;样品H76-10仅经历了高压变质作用,其压力峰期P-T条件为~490℃、~2.4GPa,石榴石-绿辉石-全岩Lu-Hf等时线年龄为306±11Ma。结合前人年代学数据,获得新疆西南天山超高压榴辉岩峰期变质作用时代为327~326Ma,高压榴辉岩峰期变质作用时代为316-306Ma。本文获得的超高压变质作用确切年龄326.9±1.3Ma,对于揭示古南天山洋深俯冲和闭合的时间具有重要意义。