Secondary phase validation—Phase classification by polarization

A long-standing problem in operational seismology is that of reliable focal depth estimation. Standard analyst practice is to pick and identify a ‘phase’ in the P-coda. This picking will always produce a depth estimate but without any validation it cannot be trusted. In this article we ‘hunt’ for standard depth phases like pP, sP and/or PmP but unlike the analyst we use Bayes statistics for classifying the probability that polarization characteristics of pickings belong to one of the mentioned depth phases given preliminary epicenter information. In this regard we describe a general-purpose PC implementation of the Bayesian methodology that can deal with complex nonlinear models in a flexible way. The models are represented by a data-flow diagram that may be manipulated by the analyst through a graphical-programming environment. An analytic signal representation is used with the imaginary part being the Hilbert transform of the signal itself. The pickings are in terms of a plot of posterior probabilities as a function of time for pP, Sp or PmP being within the presumed azimuth and incident angle sectors for given preliminary epicenter locations. We have tested this novel focal depth estimation procedure on explosion and earthquake recordings from Cossack Ranger II stations in Karelia, NW Russia, and with encouraging results. For example, pickings deviating more than 5° off ‘true’ azimuth are rejected while Pn-incident angle estimate exhibit considerable scatter. A comprehensive test of our approach is not quite easy as recordings from so-called Ground Truth events are elusive.     

Elastic and anelastic anomalies in (Ca,Sr)TiO3 perovskites: Analogue behaviour for silicate perovskites

Values of bulk modulus (K), shear modulus (G) and mechanical quality factor (Q) have been determined for polycrystalline samples across the CaTiO₃ (CST0)–SrTiO₃ (CST100) solid solution by resonant ultrasound spectroscopy. Because of similarities with low frequency elastic and anelastic anomalies due to twin wall motion reported in previous studies, a working hypothesis is developed in which dissipation processes are interpreted in terms of twin wall displacements. At high temperatures in CST50 the stability field of the I4/mcm structure is marked by the disappearance of all resonance peaks (superattenuation). This is attributed to anelastic domain wall sliding. At room temperature the I4/mcm phase of CST70 and CST80 has values of G which are lower than those of cubic or orthorhombic phases, and a concomitant drop in Q is interpreted as implying that the domain wall pinning process reported elsewhere to occur below 400–450 K is only partial. A similar drop in G and Q was found in CST95 below the transition at 238 K. The I4/mcm ↔ Pbcm transition in CST70 at 230 K is marked by an abrupt increase in Q, suggesting that mobile twins in crystals with the I4/mcm structure become effectively immobile in antiferroelectric crystals with the Pbcm structure. The I4/mcm ↔ Pnma transition in CST50 is marked by a similarly abrupt increase in Q, consistent with twin walls becoming effectively immobile also in crystals with the Pnma structure. A fall in Q below 800 K in CST0, however, could imply that a degree of twin wall mobility might develop in Pnma crystals if the tetragonal spontaneous strain departs significantly from zero. The remarkable attenuation behaviour of crystals with the I4/mcm structure at the relatively low stress conditions which apply during resonances of a parallelepiped with edge dimensions of 2–4 mm, is consistent with the view that a characteristic signature for tetragonal CaSiO₃ in the Earth's lower mantle should be a marked attenuation of seismic waves.     

Rb2CO3-CH3CH2OH-H2O三元体系20°C相平衡的研究

研究了Rb2 CO3-CH3CH2 OH -H2 O体系在 2 0°C下的相平衡 ,绘制了相应的溶度图。发现Rb2 CO3·2 .5H2 O的新物相 ,与以往报道的结果不一致     

氯化钾与硫酸钠制硫酸钾工艺的优化

根据 K+ ,Na+∥ Cl-,SO4 2 -— H2 O体系相图 ,提出了氯化钾与芒硝制备硫酸钾工艺中新的工业化生产循环和解决钾芒硝富集问题的具体方案 ,取得良好效果。     

中甸火山-岩浆弧燕山期热林复式岩体演化 与Ar-Ar 定年及铜钼矿化

产于中甸印支期火山一岩浆弧北东缘的燕山期热林复式岩体,从早至晚边部到中部划分出主期由细粒似斑状二长花岗岩→中粒似斑状二长花岗岩和边部补充期二长花岗斑岩5个侵入体组成的同源岩浆细粒→中粒→斑状结构演化系列.岩体岩石化学、稀土和微量元素总体反映为同熔型花岗岩特征.在复式岩体Ⅱ号侵入体中粒似斑状二长花岗岩中获黑云母Ar-Ar同位素等时年龄81.7±1.1Ma,坪年龄82.01±0.86 Ma,属燕山晚期侵入体.铜钼矿主要产于晚期侵入体中,边部细粒花岗岩和角岩内带具有细脉状黄铜矿、团块状辉钼矿化;中部发生二长花岗(斑)岩热液蚀变充填交代辉钼矿化--辉钼矿石英细脉、中粗晶浸染状;以及沿裂隙发育岩浆期后含矿热液充填交代辉钼矿化,构成燕山期花岗斑岩铜钼成矿亚系列.成因类型:蚀变花岗斑岩、石英脉型和角岩型3种,指示了燕山期二长花岗斑岩类具有较好的铜钼找矿潜力.     

The crystal and magnetic structure of Li-aegirine LiFe3+Si2O6: a temperature-dependent study

Single crystals of Li-aegirine LiFe³⁺Si₂O₆ were synthesized at 1573?K and 3?GPa, and a polycrystalline sample suitable for neutron diffraction was produced by ceramic sintering at 1223?K. LiFe³⁺Si₂O₆ is monoclinic, space group C2/c, a=9.6641(2)?Å, b= 8.6612(3)?Å, c=5.2924(2)?Å, β=110.12(1)^° at 300?K as refined from powder neutron data. At 229?K Li-aegirine undergoes a phase transition from C2/c to P2₁ /c. This is indicated by strong discontinuities in the temperature variation of the lattice parameters, especially for the monoclinic angle β and by the appearance of Bragg reflections (hkl) with h+k≠2n. In the low-temperature form two non-equivalent Si-sites with 〈SiA–O〉=1.622?Å and 〈SiB–O〉=1.624?Å at 100?K are present. The bridging angles of the SiO₄ tetrahedra O3–O3–O3 are 192.55(8)° and 160.02(9)° at 100?K in the two independent tetrahedral chains in space group P2₁ /c, whereas it is 180.83(9)° at 300?K in the high-temperature C2/c phase, i.e. the chains are nearly fully expanded. Upon the phase transition the Li-coordination changes from six to five. At 100?K four Li–O bond lengths lie within 2.072(4)–2.172(3)?Å, the fifth Li–O bond length is 2.356(4)?Å, whereas the Li–O3?A bond lengths amount to 2.796(4)?Å. From ⁵⁷Fe Mössbauer spectroscopic measurements between 80 and 500?K the structural phase transition is characterized by a small discontinuity of the quadrupole splitting. Temperature-dependent neutron powder diffraction experiments show first occurrence of magnetic reflections at 16.5?K in good agreement with the point of inflection in the temperature-dependent magnetization of LiFe³⁺Si₂O₆. Distinct preordering phenomena can be observed up to 35?K. At the magnetic phase transition the unit cell parameters exhibit a pronounced magneto-striction of the lattice. Below T _N Li-aegirine shows a collinear antiferromagnetic structure. From our neutron powder diffraction experiments we extract a collinear antiferromagnetic spin arrangement within the a–c plane.     

地震沉积学探讨

地震沉积学是用地震手段研究沉积岩及其形成过程的学科,其研究手段主要有90°相位转换和地层切片技术等。90°相位转换使地震相位具有了岩性地层意义,可以用于高频层序地层的解释;地层切片是指对某一层位内进行等比例内插切片之后用来研究各个等时地层单元的沉积体系（相）的平面展布。文章认为：①由于受地震分辨率的限制,地震沉积学目前主要应用于研究宏观的地层、岩石、沉积史和沉积体系,还没有达到全面研究沉积岩及其形成过程的程度,因此,目前的地震沉积学是利用地震手段结合井资料研究宏观的地层、岩石、沉积史和沉积体系的一门学科,它还需要进一步的发展才有可能继地震地层学、层序地层学之后真正成为一门研究沉积岩及其形成过程的新学科;②相位转换技术中转换的角度并不一定局限于90°,可以是其它角度的相位转换,这要根据层位标定的具体情况而定;③地层切片比时间切片和沿层切片更加合理,但是目前的地层切片技术还没有考虑地层的沉积速率随时间的变化,因此,地层切片还不是严格意义上等时的。     

多功能定时控制器的设计

介绍了一种多功能定时控制器的设计方法,它是由８９Ｃ５１单片机和几个主要的集成电路芯片构成,并给出了监控软件的结构框图。     

岩石圈中水的临界奇异性——大规模成矿的根源

水的临界奇异性是岩石圈中许多重大地质作用的关键和枢纽,有独特的地质意义、超乎常识。水在临界点发生二级相变,许多物理化学性质奇异性突变,特别是溶解行为和热压的突变,对成矿作用影响极大。     

冷迳流的稳定性及其解析解的分析

本文利用相法讨论了y方向无限伸延的冷迳流方程.首先发现其非线性项作用由于z方向上的补偿作用而消失,即其相空间的方程是四阶线性常微分方程.利用Hurwitz方法分析其稳定时,证明了唯有中性大气符合冷迳流的稳定性条件.其解析解的趋势表明与观测结果类似.