Quantitative characterization of connectivity and conductivity of sandstone carriers during secondary petroleum migration,applied to the Third Member of Eocene Shahejie Formation,Dongying Depression,Eastern China

Studies on migration pathways remain qualitative, albeit extensive quantification of migration forcing. In this study, hydrocarbon carriers are defined as carrier units and their corresponding carrier beds for the Third Member of Eocene Shahejie Formation in the Dongying Depression, Bohai Bay Basin, eastern China, on the basis of their lithofacies and physical properties, spatial relationships, and data availability; secondary migration conduits are then quantified. A carrier unit is defined as a stratigraphic unit that contains microscopically porous and permeable carrier beds and is covered by regional seals. The carrier beds are macroscopically and physically connected to each other within a carrier unit and are hydrodynamically connected during secondary migration. A method of quantifying sandstone carrier units using common physical properties is developed. First, a carrier unit containing potential carrier beds is identified on the basis of lithofacies and their lateral changes. Second, physical connectivity of sandstone carrier beds is assessed on the basis of percolation theory. Third, the hydrodynamic connectivity of a sandstone carrier unit is analyzed using effective parameters that may reflect the hydraulic circulation in the carrier unit. Last, the conductivity of a sandstone carrier bed is quantitatively characterized using appropriate physical property parameters. The results for sandstone carrier units in the Third Member of the Shahejie Formation are used in numerical models addressing Pleistocene secondary migration. The model results explain the discovered accumulation and hydrocarbon shows well; and the model predictions on exploration targets have been confirmed by drilling.     

因子分析在海河流域石油类污染综合评价中的应用(英文)

基于因子分析对2012~2013年海河流域pH、DO、COD、BOD5、氨态氮和总石油烃等6项水质指标的监测数据进行统计,并对其中四项指标进行水污染综合指数评估,旨在对海河水质进行较为系统的评价。结果显示,BJ1和HB2两个站位水质属于Ⅳ类标准,其余各站位均为Ⅴ类;各站位综合评价结果得到海河流域指数为1.44,说明海河流域处于污染状态,其污染程度超过该流域功能区的标准。因子分析发现,COD、DO和NH3-N之间差异显著(P0.05);主成分分析显示,除pH和BOD5外,其余指标都在0.70以上;COD、DO、NH3-N和TPH的贡献率较高,其中总石油烃的贡献率为100%,因此可以认为该海域的污染类型属于有机污染,且石油烃污染较为突出。     

Organic geochemistry of the Vindhyan sediments: Implications for hydrocarbons

The organic geochemical methods of hydrocarbon prospecting involve the characterization of sedimentary organic matter in terms of its abundance, source and thermal maturity, which are essential prerequisites for a hydrocarbon source rock. In the present study, evaluation of organic matter in the outcrop shale samples from the Semri and Kaimur Groups of Vindhyan basin was carried out using Rock Eval pyrolysis. Also, the adsorbed low molecular weight hydrocarbons, methane, ethane, propane and butane, were investigated in the near surface soils to infer the generation of hydrocarbons in the Vindhyan basin. The Total Organic Carbon (TOC) content in shales ranges between 0.04% and 1.43%. The S₁ (thermally liberated free hydrocarbons) values range between 0.01–0.09 mgHC/gRock (milligram hydrocarbon per gram of rock sample), whereas the S₂ (hydrocarbons from cracking of kerogen) show the values between 0.01 and 0.14 mgHC/gRock. Based on the T_max (temperature at highest yield of S₂) and the hydrogen index (HI) correlations, the organic matter is characterized by Type III kerogen. The adsorbed soil gas, CH₄ (C₁), C₂H₆ (C₂), C₃H₈ (C₃) and nC₄H₁₀, (nC4), concentrations measured in the soil samples from the eastern part of Vindhyan basin (Son Valley) vary from 0 to 186 ppb, 0 to 4 ppb, 0 to 5 ppb, and 0 to 1 ppb, respectively. The stable carbon isotope values for the desorbed methane (δ¹³C₁) and ethane (δ¹³C₂) range between −45.7‰ to −25.2‰ and −35.3‰ to −20.19‰ (VPDB), respectively suggesting a thermogenic source for these hydrocarbons. High concentrations of thermogenic hydrocarbons are characteristic of areas around Sagar, Narsinghpur, Katni and Satna in the Son Valley. The light hydrocarbon concentrations (C₁–C₄) in near surface soils of the western Vindhyan basin around Chambal Valley have been reported to vary between 1–2547 ppb, 1–558 ppb, 1–181 ppb, 1–37 ppb and 1–32 ppb, respectively with high concentrations around Baran-Jhalawar-Bhanpur-Garot regions (Kumar et al., 2006). The light gaseous hydrocarbon anomalies are coincident with the wrench faults (Kota – Dholpur, Ratlam – Shivpuri, Kannod – Damoh, Son Banspur – Rewa wrench) in the Vindhyan basin, which may provide conducive pathways for the migration of the hydrocarbons towards the near surface soils.     

东营凹陷金东—柳桥地区油气化探数据中的地表干扰与排除

东营凹陷南斜坡金东—柳桥地区地表条件复杂,化探信号干扰强烈,造成假异常大面积出现。在对金东—柳桥地区油气化探数据中干扰类型识别的基础上,用Mallat小波分析法,发现分析尺度为3时的连续序列呈现出地表干扰信息,由此进行了地表干扰排除。经过封盖条件校正与异常识别,获得了该区油气化探异常。干扰排除后的异常与断层、圈闭及已发现的油气藏或油气显示相吻合,表明这些异常主要反映的是地下油气藏信息。     

List of members of the Editorial Board

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山东金亭岭金矿矿床地球化学异常分带模型

通过对山东金亭岭金矿各类微量元素和烃类组分在该矿床不同中段的含量变化以及在纵向上的异常展布和富集规律进行分析和总结,建立了该矿床的地球化学叠加异常分带理想模型,得出矿床地球化学异常轴向分带序列确定为:甲烷、乙烷、丙烷、正丁烷、异丁烷、乙烯、丙烯、Sb(前缘晕)→As、Hg(矿头晕)→Au、Ag、Pb、Zn、Cu、Mn(矿中晕)→Co、Ni、Mo、Bi(矿尾晕),并总结了找矿预测标志,为其深部找矿预测提供了一定的科学借鉴依据。     

鄂尔多斯盆地延长探区低渗致密油气成藏理论进展及勘探实践

延长石油集团在鄂尔多斯盆地大力推动石油、天然气、页岩气勘探开发理论研究和技术攻关,多类型资源协同发展,取得显著效果。在石油勘探方面,提出延长组特低渗石油“交替式”成藏理论认识,建立盆地中生界多期差异性成藏新模式,近10年特低渗石油年均探明地质储量超1×10⁸ t。建立细粒沉积风暴、地震等控砂理论,以及甜点预测方法,致密油累计探明地质储量2.1×10⁸ t。针对致密气田砂体成因机理不明、天然气运聚成藏规律不清等主要难题,揭示了“浅水环境岸线频繁迁移控砂”机制,建立了致密砂岩气优质储层成储模式,明确纯石英砂岩和富石英低塑性颗粒岩屑砂岩是致密气分布的“甜点”,形成了基于多要素、全过程天然气运聚模拟的目标优选技术。经勘探实践,发现了延安气田,累计探明天然气地质储量7 635×10⁸ m³。页岩气方面,提出陆相页岩气“三元”成藏富集地质理论的创新认识,认为湖相优质页岩是陆相页岩气富集高产的物质基础,多类型、跨尺度的复杂孔隙网络决定页岩气赋存条件,厚层页岩自封闭能力及高压是保存的关键,实现陆相页岩气产量突破。未...     

AHDEB油田白垩系油藏油气充注期次的流体包裹体证据

伊拉克AHDEB油田油藏成藏规律对油田后期开发具有重要意义, 与埋藏史相结合的流体包裹体研究是揭示油藏油气成藏期次和时间的有效手段.利用伊拉克AHDEB油田白垩系油藏储层样品对流体包裹体特征进行了分析, 并且通过流体包裹体的显微观察、荧光颜色、单一包裹体的红外光谱和均一温度测定, 结合地质背景对该油田的油充注期次进行了研究.研究表明, 油包裹体以发绿色和黄绿色荧光为主, 少数发浅黄色和黄褐色荧光.油包裹体的显微傅立叶红外光谱测定结果计算的CH_2a/CH_3a、X_inc、X_std可划分油的成熟度, 表明存在两种成熟度的油.最后, 根据均一温度测定结果, 结合埋藏史和热史, 认为该油田可能存在4期油充注成藏相关的流体活动: 第1成藏期发生在95.0~96.5Ma, 相当于晚白垩世早期; 第2成藏期为71.0~78.5Ma, 相当于晚白垩世晚期, 第1期和第2期烃源岩排烃规模小, 产生中-重质油, 后期遭受氧化而形成沥青; 第3成藏期发生在14.0~15.0Ma, 相当于中中新世, 处于生排烃高峰期, 为主要成藏期; 第4期发生在10.0Ma左右, 与第3期为多幕连续充注.      

风化煤及提腐植酸后残渣热解行为与动力学分析

应用热重-质谱(TG-MS)联用技术对风化煤(WC)及其腐植酸提取后残渣(WCR)的热解行为进行了研究,分析了非烃类(H2、H2O、CO和CO2)、低碳烃类(CH4、C3H6和C3H7)和芳烃类(C6H6)的实验结果,并利用Coast-Redfern积分法对其热解和烃类生成动力学进行了探讨,获得了热解过程和烃类生成动力学参数。结果表明:热解过程中风化煤的质量损失率(38.9%)略大于其腐植酸提取后残渣(36.6%);除CO和CO2外,残渣中非烃类、低碳烃类和芳烃类产物的逸出量都稍微或显著多于风化煤中各类组分的逸出量。用Coast-Redfern积分法求得的动力学参数很好地解释了这一结果。