基于边坡渐进破坏特征对传统极限平衡法几点假设的合理分析

边坡的渐进破坏特征一直以来是边坡计算仿真中的一个难点。实际边坡的破坏很少是一个整体达到极限状态,突然滑动的过程,往往是逐步发展由局部破坏到最终整体失稳,即临界状态小扰动导致的链式多米洛骨牌式失稳。利用颗粒流软件,设计了0.1 m粒径高10 m土坡的数值模型,粒间黏聚力为36 kPa,摩擦系数为0.36。初始模型在重力作用下不会发生破坏,通过单独折减粒间黏聚力到18 kPa使得边坡破坏,监测竖向颗粒组group的变化获取每20 000个时间步的边坡破坏形态,实现200 000个时间步内边坡的渐进破坏过程。边坡总是从局部开始破坏,坡体物质的运移造成次一级破坏,形成最终的近似弧形的滑动面,说明滑体不是整体下滑,不是刚体,不是整体达到极限状态;坡体内应力的变化也不是单调的,有涨有落,均区别于当前极限平衡法中有限条块的刚体假设;滑动面上同时达到极限状态假设,问题本身是静不定的,通过给出条间力的传递方式使之静定可解;整体分析不能考虑破坏的局部化和渐进特征。这说明边坡计算方法的未来在于能反映动力问题和材料破坏特征的离散元方法。     

地下水污染源反演的Hooke Jeeves吸引扩散粒子群混合算法

根据污染物质量浓度监测数据进行地下水污染源反演是一类典型的地下水逆问题,该问题可转化为决策变量为污染源位置和强度的最优化问题进行求解。基于Hooke-Jeeves粒子群混合算法,引入吸引扩散粒子群(ARPSO)算法的粒子群发散算子,保证混合算法的种群多样性,并提出HJ-ARPSO混合算法,再结合地下水污染物迁移模型MT3DMS反演地下水污染源的位置和强度信息。在已知污染源位置和未知污染源位置两种情形下,分别利用HJ-ARPSO算法、HJ-PSO算法和GA算法进行地下水污染源反演。在两种情形下,HJ-ARPSO算法均具有较高的寻优成功率(分别对应为100%和90%);与之相比,未引入粒子群发散算子的HJ-PSO算法在未知污染源位置情形下其寻优成功率迅速降为60%;GA算法寻优效率则最低。算例结果表明,HJ-ARPSO算法是一种有效的地下水污染源反演优化算法。     

Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach

Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation.     

北京、郑州和深圳三城市空气中气溶胶单颗粒特征的扫描电镜分析

分别采集北京、深圳和郑州3个城市气溶胶样品,使用场发射扫锚电镜-能谱仪观察气溶胶单颗粒的显微形貌和元素组成,并利用图像分析系统对PM2.5的粒径进行了分析。结果表明,城市气溶胶单颗粒类型以矿物颗粒、烟尘和球形颗粒(飞灰和二次粒子)为主。对比3个城市气溶胶中不同颗粒类型数量百分比发现,矿物颗粒数量最多的城市是北京,飞灰和烟尘数量最多的城市是郑州,而规则矿物颗粒数量最多的城市是深圳。3个城市气溶胶单颗粒的数量-粒径分布均呈单峰分布。深圳气溶胶中颗粒物的粒径相对较小,其次为郑州、北京。3个城市气溶胶中颗粒物来源不同程度上都受到交通污染源影响,而燃煤源对北京和郑州气溶胶中颗粒物来源影响仍然不容忽视。     

A Study of Pretreatment Methods for Terrigenous Grain-Size Analysis of Marine Sediments

The prerequisite for obtaining variations of terrigenous grain-size of marine sediments is how to effectively remove non-terrigenous matters and preserve terrigenous particles synchronously. Combined with observations under biological microscope and scanning electron microscope, a comparative study of biogenic debris removal effect and terrigenous grain-size analysis under different pretreatment condition was performed on core sediments, which were retrieved in the South China Sea during the MD190 cruise. Our new results showed that the main three biogenic particles, namely, organic matter, carbonate, and opal in marine sediments could be removed effectively by 30% H₂O₂ in a stirring water bath at 60 ℃ for 3 h, 0.5% HCl for 1 h, and 2 mol/L Na₂CO₃ in a stirring water bath at 85 ℃ for 5 h, in turn. Such pretreatments achieved the goals of biogenic debris removal efficiency and relatively well-preserved terrigenous particles. Prior to selecting an appropriate pretreatment method, this study suggested that the actual effects of biogenic detritus on grain-size results of diverse marine sediment samples should be taken into account. If the laboratory data are ensured to be closer to the natural grain-size distribution of terrigenous particles, the removals of all biogenic debris are not always needed, and the less pretreatment processes the better. For example, opal particles have little effect on terrigenous grain-size distribution when their percentage is lower than 2%. Thus, there is no use to remove them from marine sediments before laboratory grain-size analysis of terrigenous particles. Additionally, ultrasonic is not suggested through the whole process of terrigenous grain-size analysis because the strong energy of ultrasonic can lead to the fragmentation of some fragile terrigenous particles.     

鄂西电线积冰微物理观测研究

对2009年2月25日—3月4日湖北恩施雷达站的一次电线积冰过程,使用自动气象站、能见度仪、雾滴谱仪、雨滴谱仪等实测资料进行深入研究,分析了多种气象要素的演变,发现积冰期比无积冰期平均气温低5.6℃。对积冰期间3种天气状况下雾滴谱和降水粒子谱的特征进行了分析,结果表明:雾天和雨天的雾滴谱为单峰型,雨夹雪天为双峰型;雨天和雨夹雪天的降水粒子谱都为单峰型;雾滴平均数密度从大到小依次是:雨天(223.5 cm-3)、雨夹雪天(181.3 cm-3)、雾天(138.7 cm-3);雨天雨滴平均数密度为335.6 cm-3;雨夹雪天降水粒子平均数密度为1 502.1 cm-3。另外,实测数据表明积冰增长率从大到小依次是:雨夹雪天、雨天、雾天。     

Scattering Properties of Atmospheric Aerosols over Lanzhou City and Applications Using an Integrating Nephelometer

The data, measured by a three-wavelength Integrating Nephelometer over Lanzhou City during the winters of 2001/2002 and 2002/2003 respectively, have been analyzed for investigating the scattering properties of atmospheric aerosols and exploring their relationship and the status of air pollution. The aerosol particle volume distribution is inverted with the measured spectral scattering coefficients. The results show that the daily variation of the aerosol scattering coefficients is in a tri-peak shape. The average ratio of backscattering coefficient to total scattering coefficient at 550 nm is 0.158; there exists an excellent correlation between the scattering coefficients and the concentration of PM10. The average ratio of the concentration of PM10 to the scattering coefficients is 0.37 g m-2, which is contingent on the optical parameters of aerosol particles such as the size distribution, etc.; an algorithm is developed for inverting the volume distribution of aerosol particles by using the histogram and Monte-Carlo techniques, and the test results show that the inversion is reasonable.     

Aerosol spectra and new particle formation observed in various seasons in Nanjing

The aerosol number spectrum and gas pollutants were measured and the new particle formation （NPF） events were discussed in Nanjing. The results showed that the size distributions of aerosol number concen- trations exhibited distinct seasonal variations, implying the relations of particle sizes and their sources and sinks. The number concentrations of particles in the nuclei mode （10-30 nm）, Aitken mode （30-100 nm）, accumulation mode （100 -1000 nm） and coarse mode （〉1μm） varied in the order of summer 〉 spring 〉 autumn, summer 〉 autumn 〉 spring, autumn 〉 summer 〉 spring, and spring 〉 autumn 〉summer, re- spectively. The diurnal variation of total aerosol number concentrations showed three peaks in all observed periods, which corresponded to two rush hours and the photochemistry period at noon. In general, the NPF in summer occurred under the conditions of east winds and dominant air masses originating from marine areas with high relative humidity （50%-70%） and strong solar radiations （400 -700 W m-2）. In spring, the NPF were generally accompanied by low relative humidity （14%-30%） and strong solar radiations （400-600 W m-2）. The new particle growth rates （GR） were higher in the summertime in the range of 10- 16 nm h-1. In spring, the GR were 6.8-8.3 nm h-1. Under polluted air conditions, NPF events were seldom captured in autumn in Nanjing. During NPF periods, positive correlations between 10- 30 nm particles and 03 were detected, particularly in spring, indicating that NPF can be attributed to photochemical reactions.     

长江口潮滩有机质稳定碳同位素时空分布与来源分析

通过测定长江口潮滩悬浮颗粒有机质和表层沉积有机质在枯水季节 (2006年2月 )和洪水季节 (2006年8月 )的稳定碳同位素值,对有机质潜在来源及局部岸段改造作用进行了分析。结果显示,悬浮颗粒有机质稳定碳同位素值在2月明显低于8月,变化范围分别在-25.8‰~-23.4‰和-25.1‰~-22.9‰,主要是受径流量枯洪季变化和浮游生物生长季节变化两种因素的叠加作用。表层沉积有机质2月和8月的稳定碳同位素分别为-25.0‰~-20.4‰和-24.7‰~-19.5‰,季节变化不明显,主要来自悬浮颗粒物的沉降。除受大背景环境因素影响,局部环境对潮滩有机质也有一定的改造作用,污水、支流河水的输入对悬浮颗粒有机质碳同位素有一定的影响,埋藏的潮滩植物和底栖微藻则对沉积有机质有部分贡献。     

一次东北冷涡过程的宏微观物理特征分析

利用2019年5月20日机载DMT和SPEC粒子测量系统获取的飞机云微物理探测资料,结合高空、地面、卫星云图产品等常规气象数据,分析了东北冷涡在发展成熟期的云宏微观结构特征。结果表明:飞机探测区域为冷性层积混合云,云水充沛。云粒子探头(CDP)和二维云粒子图像探头(CIP)探测到的最大粒子数浓度分别为362.10cm-3、191.08L-1,液态含水量变化范围为0~0.88g/m3;CDP粒子谱呈指数型下降,谱宽较窄;CIP粒子谱呈双峰结构。云粒子图像探测仪CPI表明,层积云上部主要为冰雪晶粒子,以冰晶的核化和凝华增长为主;中上部粒子主要为小冰晶形态,也有冰晶聚合体和枝状冰晶;中下部是过冷水和冰晶粒子的共存区,过冷水较为丰富。