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31.
I. Brandariz P. Castro M. Montes F. Penedo M.E. Sastre de Vicente 《Marine Chemistry》2006,102(3-4):291-299
Acid–base equilibrium constants of triethanolamine (TEA) have been determined by potentiometric titrations with a glass electrode, at 25 °C. Ionic strength was kept constant with only one electrolyte (using one of these salts: NaCl, KCl, MgCl2 or CaCl2), with binary mixtures of MgCl2 and CaCl2, and finally, in a solution with a composition approximately similar to that of natural seawater without sulfate. Equilibrium constants have been expressed in function of ionic strength by means of Pitzer equations and interaction parameters proposed in this theory have been obtained. It has been found that acid–base behaviour of TEA depends greatly on the salt used: basicity of TEA is decreased by CaCl2, while it is increased by the other electrolytes used in this work. 相似文献
32.
33.
研究了连续变量函数的全局最优化问题 ,给出了动态隧道方法。该动态隧道方法由局部搜索和动态隧道 2个阶段构成。在局部搜索阶段用了动态系统方法。对全局最优化问题的实例进行了数值实验 ,数值结果表明了该方法的稳健性和有效性。 相似文献
34.
Abstract. Two sediment cores were collected in the southern Baltic Sea and sliced into 1.0cm-thick layers. Sediments of each layer were analysed for activities of 210Pb, 137Cs, 134Cs and for the density of meiobenthic organisms (meiofauna). Zones with the rapid mixing occur in the uppermost layers (0–3 cm) of the cores based on I34Cs profiles. The extent and density of meiofauna confirmed the rapid mixing and revealed layers with slow mixing (4–8 cm). Sedimentation rates were derived from 210Pb profiles below the mixing zones (1.21 and 1.72 mm a-I) and were confumed by 137Cs distribution. Of twenty-one major meiofauna taxa commonly found in the Baltic sediments, three were present in the cores. 相似文献
35.
中太平洋CP25岩心的矿物、稀土元素及Sr、Nd同位素组成--晚新生代海底火山活动的证据 总被引:3,自引:0,他引:3
中太平洋CP25岩心沉积物中钙十字沸石、蒙脱石/伊利石比值(M/I)、稀土元素含量、铈异常(δCe)、铕异常(δEu)及Sr、Nd同位素特征作为海底火山活动的证据,揭示了中太平洋海盆晚新生代以来火山活动和沉积的历史。其结果是,早中新世约20~17MaB.P.间,火山活动逐渐强烈,在17MaB.P.最强烈,使得沉积物具有高M/I和∈Nd、低δCe和87Sr/86Sr。17~1MaB.P.发生沉积间断。1MaB.P.至现代,火山活动较早中新世减弱 相似文献
36.
《矿物岩石》2008,(4)
采用等温蒸发法研究简单四元体系Na ∥Cl-,CO32-,B4O72--H2O273K时的介稳相平衡,并测定该体系273K平衡液相中各组分的溶解度及密度,该体系的介稳相图和密度组成图显示:该四元体系在273K时的相图由3条溶解度单变量线、3个结晶区及1个共饱和点组成。体系属简单共饱型,无复盐或固溶体形成,3个结晶区分别对应单盐Na2CO3·10H2O,NaCl和Na2B4O7·10H2O。共饱点E处于Na2CO3·10H2O,NaCl及Na2B4O7·10H2O3盐共饱和,所对应的平衡液相组成为w(Na2CO3)=6.81%,w(NaCl)=21.69%,w(Na2B4O7)=0.65%,w(H2O)=70.85%。研究体系在273K下,Na2CO3·10H2O是碳酸钠盐的唯一析出形式,且硼酸钠对碳酸钠有盐析作用。 相似文献
37.
38.
岩石中的渗透率、流体流动及热液成矿作用 总被引:4,自引:0,他引:4
热液成因的固体金属矿床形成过程中都曾拥有一段流动的历史。成矿物质以溶液的形式从矿源地穿过孔隙或断裂达到了现在的栖身之所,在此过程中流体通过的路径决定了它们的走向,而溶液本身也改变了路径的特征。因此,对于此类矿床的研究不能仅仅囿于眼之所见,而应将古流体流动的观念融入其中,并考察它们的跋涉之路。文中总结了近年来国内外在岩石孔隙、断裂介质及与其相关渗透率对热液成矿作用的控制等领域的研究成果和最新进展,对岩石渗透率、渗透率的影响因素、岩石中流体流动的特征等问题进行了阐述,讨论了渗透率对于热液成矿作用深度、成矿规模、矿质沉淀机制等方面的重要影响,藉此在固体金属矿床研究中强化流"体运动"的观念,并促进构造地质学和成矿作用地球化学间一个新研究方向的发展。 相似文献
39.
V.B. Vasilenko A.V. Tolstov V.A. Minin L.G. Kuznetsova N.V. Surkov 《Russian Geology and Geophysics》2008,49(12):894-907
The intensity of postmagmatic processes in the Botuobinskaya pipe kimberlites was estimated from the calculated content of normative secondary quartz (Q). Several simple algorithms are proposed to calculate the Q content from chemical analyses of kimberlites. Ten groups of altered kimberlites have been recognized from the Q contents. The contents of MgO, some trace elements, and LREE in the groups, the contents of Cr and Ca of crimson garnets, the diamond contents of kimberlites, and the average weight of diamonds decrease as the Q content increases. It is shown that the negative SiO2–MgO correlation is the most effective indicator of the postmagmatic alteration of kimberlites. As the degree of their secondary alteration increases, the kimberlites transform into an assemblage of quartz and clay minerals enriched in some trace elements and almost completely lacking REE and diamonds. 相似文献
40.
Angelo Paone 《International Journal of Earth Sciences》2008,97(3):635-650
A compilation of B–Be–Li data on rocks that cover the entire eruptive history of Somma-Vesuvius is presented and interpreted
in the light of evolution models for the Somma-Vesuvius rocks. Using major and trace element data, fractional crystalllization
models are presented for different geochemical units. These data were used to constrain the source mineralogy of the Somma-Vesuvius
rocks (ol-opx-cpx-gar-amp of 0.4-0.3-0.1-0.1-0.1), the amount of sediment added (5–10%) and the melt fraction from batch partial
melting computations (0.05–0.1). From the B–Li data it is inferred that the main process responsible for the B isotopic signature
is sediment recycling. However, the B–Li data show a major variation in Li abundances respect to B which is explained with
Li dehydration before the fluid enriched the mantle wedge that produced the arc magmas. The Somma-Vesuvius B isotope composition
is intermediate between that of the Campi Flegrei and the broad field of the Eolian Island arc. A low Be isotopes in the recent
volcanic rocks can be explained as: (a) the top 1–22 m of the incoming sediment is accreted, (b) large amounts of sediment
erosion, (c) a slow rate of subduction which have provoked a long magmatic history for the Vesuvius magma, (d) the sediment
component takes several Myr longer than the subducting plate to reach the magma source region beneath Italy. 相似文献