Study on the geochemical correlation of crude oils of Palaeocene and Jurassic ages from the Potowar Indus Basin in northern Pakistan

This study deals with a detailed geochemical characterization of three crude oils from the Upper Indus Basin, Punjab, Pakistan. The samples were obtained from three productive oil fields of the Datta Formation (Jurassic), Lochhart (Palaeocene) and the Dhak Pass zone (Palaeocene). The GC parameters for and the bulk properties of Datta Formation oils are essentially coincident with those of the oils from the Dhak Pass Formation in the Upper Indus Basin, Pakistan and the oils likely originate from a marine source rock. In contrast, the Lockhart Formation oils show different behaviors and seem to be originated from dirty carbonate rocks although all three crude oils are mature, being of non-biodegraded and somewhat mixed organic matter origin. Low Pr/Ph values and high C₃₅ homohopane index for the Lockhart Formation oils suggest a source of anoxic environment with low Eh while oils from the Datta Formation and Dhak Pass Formation showed different trends, i.e., lower values of C₃₅ homohopane index indicating different depositional environment than oil from the Lockhart Formation. All three crude oils from the Upper Indus Basin are mature for the hopane ratios, i.e., Ts/Ts+Tm, C₃₂22S/(S+R) and C₃₀ αβ/(αβ+βα) and sterane ratios, i.e., C₂₉22S/(S+R) and C₂₉ββ/(ββ+αα) but oils from the Lockhart Formation seem to be less mature than those from the Palaeocene and Datta Formation according to plots like API° vs. homohopane Index, Pr/Ph vs. sterane. The relative composition of 5α(H), 14β(H), 17β(H)-24-ethylecholestanes and the C₂₉20S/20S+20R index, indicate that all three crude oils are equally mature, which makes it unlikely with respect to the above said plots. This difference is may be due to the migratory chromatography which alters the concentrations of sterane and hoapnes and hence gives different results. These oils do not exhibit UCM and have complete n-alkane profiles indicating non-biodegradation.     

(ANTI)SOCIAL CAPITAL IN THE PRODUCTION OF AN (UN)CIVIL SOCIETY IN PAKISTAN*

ABSTRACT. Pakistan is home to some of the most widely admired examples of civil‐society‐based service‐delivery and advocacy groups. Pakistan has also spawned some much‐maligned nongovernmental actors with violent agendas. This article uses the social capital / civil society conceptual lens to view the modes of (anti)social capital mobilization that contribute to the civil and uncivil spaces of Pakistani society. The case examples of Jamaat‐e‐Islami, an Islamic revivalist organization, and the Human Rights Commission of Pakistan are used to understand the geography of social and antisocial forces in Pakistan. It is argued that the processes that mobilize social capital‐whether positive or perverse‐are multiscalar and that, in the Pakistani context, no compelling cultural or religious reason exists for the ascendance of one type of social capital over the other. Positive social capital can be mobilized to contribute to a more civil social discourse in Pakistan, given the right policy choices.     

Focal mechanism study of north Potwar dformed zone, Pakistan

Introduction Northern Pakistan is one of the seismically active regions in the world. Numerous studies have been undertaken to highlight and understand the ongoing collisional process of the Indo-Pakistan plate with the Kohistan island arc. Besides the N-S compression, as a result of the con-vergence, transpressional features have also been recognized. However, in the studied area pres-ence of evaporites (Eocambrian) has led to the development of duplex type models with the basal decollemen…     

Biogeochemical Prospecting of Sulphide Minerals in Winder Valley, Balochistan, Pakistan

Abstract: The Mor Range is mountainous terrain in southern Balochistan dominantly occupied by exposures of rocks of the Ferozabad Group which is comprised of Lower‐Middle Jurassic carbonates and siliciclastics. This group contains syngenetic and epigenetic Zn–Pb–Ba mineralization classified as Stratiform Sediment‐Hosted (SSH) and Mississippi Valley Type (MVT) deposits. Three important flora of the Saharo–Sindian, phytogeographical region of Pakistan, namely Tamarix aphyl–la, Salvadora oleoides and Acacia arabica have been studied as a mineralization prospecting tool. Samples of these species were collected from Winder Valley adjoining the Mor Range to prospect for new areas of mineralization, besides the known sulphide deposits. This study revealed the Draber, Thorar, Raj, Mithi and Kanrach localities as new prospect. Quantitative estimation of biophile elements (Zn–Cu–Pb) from the three species was made. A number of new Zn, Cu and Pb anomalies were distinguished in the area. The variation in the constituents of these species from different localities possibly varies with nature and distance from bedrock, mobility, climate, average abundance in the plant ash and exclusion mechanism of the flora. Acacia arabica with deep penetrating roots shows the best results and could be used to delineate new horizons of mineralization. In these species Zn and Cu are relatively concentrated whereas Pb shows limited enrichment. Lead therefore is the element best suited for pinpointing the mineralization owing to its relatively less mobile character. Relationships among Zn–Cu–Pb have been established using scattergrams and triangular variation diagram, which also demonstrate their genetic affiliation. Statistical analyses, such as determination of mean, mode, median, standard deviation, and coefficient of correlation, were also made to improve the raw geochemical data. These biogeochemical methods appear to be suitable in arid climate of Balochistan, if proper attention is paid to species selection.     

Geochemical Investigations of Stratabound Gunga Barite Deposits of Khuzdar (Balochistan), Pakistan

Abstract: The Gunga barite deposits occur in carbonate clastic marine sequence of Jurassic age. These rocks are widely spread in Khuzdar-Lasbela belt which host important stratabound barite and zinc-lead deposits of Pakistan. These rocks are intricately folded and extensively faulted. The Gunga are low temperature hydrothermal deposits occurring as a series of disconnected lenses a few meters thick. Two mineralized horizons are recognized: barite in the upper zone, sphalerite and galena in the lower zone. Four types of barite mineralization occurs in Gunga stratabound replacement associated with 1) fracture filling, 2) open space fillings in solution collapsed breccia, 3) replacement in fault, and 4) veinlets associated with all these three types. The wall rocks of the Gunga deposits have also been altered by silicification, leaching and ferruginization.
The sulfur isotope values of most of the Gunga barite samples range from 23.8 to 27.8 per mil with an average of 26.4 per mil, which is very close to the average of isotopic values of epigenetic carbonate hosted Late Paleozoic Missouri barite deposits. The Gunga like other barite and sulfide deposits of Khuzdar-Lasbela belt are Mississippi Valley type, stratabound and of replacement origin precipitated from connate brines expelled during the incipient rifting of India from Gondwana land in the Late Jurassic and Early Cretaceous periods. The low content of copper, lead and zinc in the Gunga barite deposits suggests that these deposits were not formed in proximity to an igneous source of the ore solution.
The Gunga deposits are epigenetic and stratabound as their mineralization is structure controlled. There is an evidence of transgressive nature of host rock and wall rock alteration which are absent in stratiform or bedded deposits.     

Steppin' in it: postcoloniality in northern Pakistan

This paper examines the transcultural relations between researchers and research subjects in a postcolonial research setting. I draw from my experience doing dissertation research in northern Pakistan to discuss how my research subjects' effectively constructed me as a sahib, or what I saw as a colonial subject position. I examine the ways that my research subjects and I co-constructed, although unequally, my position and location as a researcher. The asymmetries of power relations in research are exacerbated by postcolonial relations in this contact zone. The contribution of those I researched is significant towards understanding our locations as postcolonial subjects in this research setting, and the location from which I produced the research. While it was difficult to do research as anyone other than a sahib during my research, the stories I tell and metaphors I employ in this paper attempt to destabilize my location as a colonial sahib, an authority. The scatological references that run throughout this paper are an attempt to write against the inherently colonial epistemologies that underpin geographic research more generally.     

Linking Access and Vulnerability: Perceptions of Irrigation and Flood Management in Pakistan

This article reports the results of a survey conducted in four villages in central Pakistan regarding people's perceptions about irrigation‐ and flood‐related issues. The article uses the perception studies methodology from the human ecology school to address the political ecology agenda in resource and hazards geography. The log‐linear analysis of the survey data shows that people are knowledgeable about social power differentials and interactions between various social factors in influencing their access to resources and vulnerability to floods. The article further demonstrates that water users and vulnerable populations are much more likely to suggest social explanations than naturalistic or fatalistic explanations for their differential access to irrigation water and vulnerability to flood hazard.     

“一带一路”背景下巴基斯坦投资环境及区位选择

“一带一路”倡议以及中巴经济走廊建设为中国同巴基斯坦的经贸合作带来新的机遇,从发展趋势看,中国企业在巴基斯坦投资空间呈逐渐扩大之势;中国企业在巴基斯坦如何进行有效的区位选择,是文章要解决的问题。首先,从基础竞争力、核心竞争力、辅助竞争力3个维度,计算了巴基斯坦2000—2018年整体投资环境。结果显示：整体投资环境年均增长率36.05%,其中基础竞争力年均增长率28.32%,最为显著;表明巴基斯坦投资环境不断改善,特别是基础设施领域适合中国企业投资。其次,梳理了现有中国企业进入巴基斯坦投资的区位选择。结果表明,目前中国企业在信德省和旁遮普省的投资项目较多。最后,分别从趋于经济中心区、边界地区、社会联系密切区和安全形势良好区4个角度,分析了该国的主要省区和城市投资区位。结果表明,从趋于经济中心区的角度,信德省和旁遮普省存在经济上的优势;从趋于边界地区的角度,开伯尔-普什图省和瓜达尔港具有优势;从趋于社会联系密切地区角度,卡拉奇、拉合尔和伊斯兰堡具有优势;从趋于形势安全的角度,旁遮普省和信德省存在投资安全的优势。     

The trophic ecology of key megafaunal species at the Pakistan Margin: Evidence from stable isotopes and lipid biomarkers

The Arabian Sea is subject to intense seasonality resulting from biannual monsoons, which lead to associated large particulate fluxes and an abundance of organic carbon, a potential food source at the seafloor for benthic detritivores. We used the stable isotopes of carbon and nitrogen alongside lipid analyses to examine potential food sources (particulate and sedimentary organic matter, POM and SOM respectively) in order to determine trophic linkages for the twelve most abundant megafaunal species (Pontocaris sp., Solenocera sp., Munidopsis aff. scobina, Actinoscyphia sp., Actinauge sp., Echinoptilum sp., Pennatula aff. grandis, Astropecten sp. Amphiura sp. Ophiura euryplax, Phormosoma placenta and Hyalinoecia sp.) at the Pakistan Margin between 140 and 1400 m water depth. This transect spans a steep gradient in oxygen concentrations and POM flux. Ranges of δ¹³C and δ¹⁵N values were narrow in POM and SOM (4‰ and 2‰ for δ¹³C and δ¹⁵N, respectively) with little evidence of temporal variability. Labile lipid compounds in SOM originating from phytoplankton did exhibit seasonal change in their concentrations at the shallowest sites, 140 and 300 m. Benthic megafauna had broad ranges in δ¹³C and δ¹⁵N (>10‰ and >8‰ for δ¹³C and δ¹⁵N, respectively) suggesting they occupy several trophic levels and utilize a variety of food sources. There is evidence for feeding niche separation between and within trophic groups. Lipid biomarkers in animal tissues indicate a mixture of food sources originating from both phytoplankton (C_20:5(n-3) and C_22:6(n-3)) and invertebrate prey (C_20:1 and C_22:1). Biomarkers originating from phytodetritus are conserved through trophic transfer to the predator/scavengers. Six species (Pontocaris sp., Solenocera sp., Actinoscyphia sp., Echinoptilum sp., Amphiura sp. and Hyalinoecia sp.) showed a significant biochemical response to the seasonal supply of food and probably adapt their trophic strategy to low food availability. Biotransformation of assimilated lipids by megafauna is evident from polyunsaturated fatty acid distributions, for example, Echinoptilum sp. converts C_20:5(n-3) to C_24:6(n-3).     

Numerical storm surge model for India and Pakistan

The northeastern sector of the Arabian Sea, which covers the Gujarat coast of India and western coast of Pakistan, is a region vulnerable to extreme sea levels associated with tropical cyclones (TCs). Although the frequency of tropical cyclones in the Arabian Sea is not high, the coastal regions of India and Pakistan suffer in terms of loss of life and property caused by the surges. In view of this a location-specific fine resolution model is developed for the Gujarat coast of India and adjoining Pakistan coast. The east–west and north–south grid distance is about 3.0 km. Using this model, numerical experiments are carried out to simulate the surges generated by 1999 and 2001 cyclones which struck the Pakistan coast. The model computed surges are in agreement with the available observational estimates.