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71.
Organic geochemical studies have been carried out to assess the qualities of source rocks penetrated by four wells (Kemar-1, Murshe-1, Tuma-1 and Ziye-1) in the Nigerian sector of the Chad basin. The Chad basin is a large intracratonic basin in Central West Africa. Commercial hydrocarbon accumulations have been discovered in some sectors of the basin outside the Nigerian border in a structurally related contiguous basin. Fair to poor quality source rocks are inherent in the sequences penetrated by the studied wells. About 80% of all samples have their total organic carbon (TOC) contents more than 0.5 wt.%, the minimum limit for hydrocarbon generation. Juxtaposition of the hydrogen indices against the TOC and Tmax indicates that the source rocks are entirely gas-prone. However, biomarker chromatograms and extract vs. TOC plots indicate the presence of oil shows in Ziye-1 well at a depth of 1210 m. Although generated hydrocarbons (wherever they have accumulated) would be overwhelmingly gaseous, gas is the energy of the future. The gas resources of this part of Nigeria's inland basins can be economically exploited through policies that will increase the tempo of gas-utilization projects and the construction of a national grid of gas pipelines with nodal points of input and output. 相似文献
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73.
C. J. Hapke 《地球表面变化过程与地形》2005,30(6):679-697
High‐resolution historical (1942) and recent (1994) digital terrain models were derived from aerial photographs along the Big Sur coastline in central California to measure the long‐term volume of material that enters the nearshore environment. During the 52‐year measurement time period, an average of 21 000 ± 3100 m3 km?1 a?1 of material was eroded from nine study sections distributed along the coast, with a low yield of 1000 ± 240 m3 km?1 a?1 and a high of 46 700 ± 7300 m3 km?1 a?1. The results compare well with known volumes from several deep‐seated landslides in the area and suggest that the processes by which material is delivered to the coast are episodic in nature. In addition, a number of parameters are investigated to determine what influences the substantial variation in yield along the coast. It is found that the magnitude of regional coastal landslide sediment yield is primarily related to the physical strength of the slope‐forming material. Coastal Highway 1 runs along the lower portion of the slope along this stretch of coastline, and winter storms frequently damage the highway. The California Department of Transportation is responsible for maintaining this scenic highway while minimizing the impacts to the coastal ecosystems that are part of the Monterey Bay National Marine Sanctuary. This study provides environmental managers with critical background data on the volumes of material that historically enter the nearshore from landslides, as well as demonstrating the application of deriving historical digital terrain data to model landscape evolution. Published in 2005 by John Wiley & Sons, Ltd. 相似文献
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H. A. Al-Darwish E. A. Abd El-Gawad F. H. Mohammed M. M. Lotfy 《Environmental Geology》2005,49(2):240-250
Coastal uses and other human activities have inevitably impinged on the Gulf environment; therefore, these regions require continuous monitoring. The investigated area covered the maximum fragments of Dubai coastal region in the Arabian Gulf. The determination of major oxides and trace metal concentrations in Dubai sediments revealed three heavily and moderately contaminated regions. One is in the far northeastern part at Al-Hamriya Sts 1–3 and contaminated by Fe, Cu, Pb, and Zn; the second is in the mid-northeastern part at Dry Docks and contaminated by Cu, Ni, Pb, and Zn; and finally, the third is in the near southwestern part at Dubal and contaminated by Fe, Mg, Cr, Ni, and Zn. Al-Hamriya St 3 represented the highest values of Cu, Pb, and Zn, whereas Dubal exhibited the maximum values of Fe, Mg, Ba, Cr, Mn, Ni, and V. The anthropogenic discharge and natural deposits are the main sources of contamination. In general, all trace and major elements showed the minimal levels at Jebel Ali Sanctuary (Sts 11, 12, 13) except for Sr and Ca, which showed their maximum values. The highest concentrations of Ca and Sr are mainly attributed to carbonate gravel sands and sands, which cover most stations. Each of V and Ni showed negative correlation with TPH, which may be indicated that the source of oil contamination in the region is not related to crude oil but mostly attributable to anthropogenic sources. The significant positive correlation, which was found between trace metals and TOC indicates that organic matter plays an important role in the accumulation of trace metals in case of Cu, Zn, and Pb. 相似文献
76.
Modelling landslides in unsaturated slopes subjected to rainfall infiltration using material point method
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This paper presents a dynamic fully coupled formulation for saturated and unsaturated soils that undergo large deformations based on material point method. Governing equations are applied to porous material while considering it as a continuum in which the pores of the solid skeleton are filled with water and air. The accuracy of the developed method is tested with available experimental and numerical results. The developed method has been applied to investigate the failure and post‐failure behaviour of rapid landslides in unsaturated slopes subjected to rainfall infiltration using two different bedrock geometries that lie below the top soil. The models show different failure and post‐failure mechanisms depending on the bedrock geometry and highlight the negative effects of continuous rain infiltrations. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
77.
通过野外采样、化学分析、电子探针(EPMA)和X射线衍射(XRD)分析等手段,研究了贵州织金地区黑色页岩矿物成分、化学组分、微量元素、稀土元素特征。研究区矿样化学成分以SiO_2和Al_2O_3为主,且具有高K低Na的特征。电子探针和X射线衍射分析表明,研究区黑色页岩主要矿物组成有石英、粘土矿物、白云石及黄铁矿等。织金黑色页岩中Pb、Ni、U、V、Cr等金属元素存在不同程度的富集,稀土元素总量为153.2×10~(-6)~224.89×10~(-6),属轻稀土元素富集型。同时从多金属层、页岩气、页岩提钾及近底部含磷铀矿资源等方面讨论了织金黑色页岩资源化利用。织金黑色页岩多金属层含有Mo、V、Ni、Ag及U等多金属元素,具综合利用价值;其中有机碳含量达到页岩气开发大于2%的条件,可进一步开展研究;页岩中伊利石含量较多,可提取黑色页岩中的钾制备含钾复合肥;黑色页岩底部与磷矿层接触带产出磷铀矿,主要为胶状磷铀矿,接触带可作为铀矿找矿的标志层。 相似文献
78.
Fluctuations in lacustrine sedimentary environments significantly affect distributions of organic matter (OM), uranium, and other elements in shales. In this study a high-resolution geochemical record of fluctuations in the paleo-depositional environment of a terrestrial lake basin is provided on the basis of extensive samples collected from the Member 3 of the Paleogene Shahejie Formation (Es3) of the Niu-38 well in the Dongying Depression, Eastern China. These samples were tested for total organic carbon (TOC), element concentrations, and biomarkers to study the evolution and fluctuation in the depositional environments of an ancient lake basin and associated geochemical response. The evolution and fluctuation of the sedimentary environment from a deep lake to a semi-deep lake and then to a shallow lake delta were indicated by geochemical response. During this evolution, the values of TOC, S1, S2, Sr, and Ts/(Ts + Tm) remarkably decreased, whereas those of Co, Ni, Rb, Na, Fe/Mn, Fe/(Ca + Mg), and C29 mortane/C29 hopane significantly increased. The deep lake basin shows depositional fluctuations, as indicated by rock lithofacies and their geochemical parameters. A close interrelationship was observed among U concentration, TOC content, and inorganic element content. Uranium concentrations are positively correlated with TOC contents, Ca and Sr concentrations, and Sr/Ba and Ca/Mg ratios but negatively with K, Na, Ba, and Rb contents and Fe/(Ca + Mg) and Fe/Mn ratios. The observed increase in U concentration in the lower Es3 section is closely related to surface adsorption by clay minerals and OM, together with some replacements of Ca and Sr by U in the shales. 相似文献
79.
Copper Speciation in a Collection of Geochemical Reference Materials Using Sequential Extraction and Evaluation of the Validity Using XANES Spectroscopy
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Copper speciation in a collection of Japanese geochemical reference materials (JSO‐1, JLk‐1, JSd‐1, ‐2, ‐3 and ‐4, JMs‐1 and JMs‐2) was achieved by sequential extraction and characterised using X‐ray absorption near‐edge structure spectroscopy. In the first step of the extraction, referred to as the acid fraction, between 1% and 20% total Cu within the reference materials was extracted. Such a result is typically accounted for by absorption of Cu onto clay minerals. However, the presence of Cu sulfate (an oxidation product of chalcopyrite) was observed in some of the stream sediments affected by mining activity (JSd‐2 and JSd‐3) instead. Copper was extracted in the reducible fraction (targeting Fe hydroxide and Mn oxide) (2–49% total Cu). Between 2% and 51% Cu was extracted in the oxidised fraction (targeting sulfides and organic matter). X‐ray absorption near‐edge structure spectroscopy clarified that the reducible fraction consisted of Cu bound to Fe hydroxide, whereas the oxidised fraction was a mixture of Cu bound to humic acid (HA) and Cu sulfide. In the oxidisable fraction, chalcopyrite was the predominant species identified in JSd‐2, and Cu bound to HA was the major species identified in JSO‐1 (a soil sample). 相似文献
80.