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201.
Parham Ahmadi Massimo Coltorti Takeshi Kuritani Yue Cai Anna Maria Fioretti 《International Geology Review》2019,61(2):150-174
Tertiary volcanic rocks in northwestern Firoozeh, Iran (the Meshkan triangular structural unit), constitute vast outcrops (up to 250 km2) of high-Mg basaltic andesites to dacites that are associated with high-Nb hawaiites and mugearites. Whole-rock 40Ar/39Ar ages show a restricted range of 24.1 ± 0.4–22.9 ± 0.5 Ma for the volcanic rocks. The initial ratios of 87Sr/86Sr and 143Nd/144Nd vary from 0.703800 to 0.704256 and 0.512681 to 0.512877, respectively, in the high-Mg basaltic andesites–dacites. High-Th contents (up to 11 ppm) and Sr/Y values (27–100) and the isotopic composition of the subalkaline high-Mg basaltic andesites–dacites indicate derivation from a mantle modified by slab and sediment partial melts. Evidence such as reverse zoning and resorbed textures and high Ni and Cr contents in the evolved samples indicate that magma mixing with mafic melts and concurrent fractional crystallization lead to the compositional evolution of this series. The high-Nb hawaiites and mugearites, by contrast, have a sodic alkaline affinity and are silica undersaturated; they are also enriched in Nb (up to 47 ppm) and a wide range of incompatible trace elements, including LILE, LREE, and HFSE. Geochemistry and Sr–Nd isotopic compositions of the high-Nb hawaiites and mugearites suggest derivation from a mantle source affected by lower degrees of slab melts. Post-orogenic slab break-off is suggested to have prompted the asthenospheric upwelling that triggered partial melting in mantle metasomatized by slab-derived melts. 相似文献
202.
Lipid biomarkers widely dotted in marine sediments, as their distribution characteristics accurately record huge information on the metabolism of the original organisms and migration and transformation of these organic components, are often used to reconstruct the paleoclimatic and paleoenvironmental conditions. This paper reviewed the progress in the study of paleoclimatic-environmental changes during the late Quaternary using abundant core lipids Glycerol Dialkyl Glyceryl Tetraethers (GDGTs) and long-chain alkyl diols in marginal sea sediments. It is pointed out that clarifying the “source-sink” process of lipid biomarkers buried in marine sediments is a prerequisite for paleoclimatic-environmental reconstruction. It is believed that the use of multiple indicators that are less affected by early diagenesis can increase the accuracy of reconstructing paleoclimatic changes. In the large-river dominated marginal seas, the mechanism of land-sea climate coupling evolution stimulated by the paleoclimatic-environmental changes can be elucidated based on paleoclimatic records reconstructed from core lipids GDGTs and long-chain alkyl diols in marine sediments. It is hoped that this paper can provide reliable technical means and a solid theoretical basis for predicting future temperature and rainfall changes. 相似文献
203.
边缘海沉积物是海洋重要的碳储库,其内部的碳循环主要是由有机质矿化分解过程来驱动的。有机碳进入边缘海沉积物后,矿化分解为溶解无机碳(DIC)进入沉积物孔隙水并扩散到上层水柱,参与海洋系统碳循环;同时还有部分DIC与钙镁等离子结合形成自生碳酸盐,保存于沉积物碳库。从生物地球化学角度探讨有机质埋藏机制和效率,在此基础上重点综述沉积物硫酸盐还原、产甲烷和甲烷厌氧氧化过程的耦合机制,以及有机质矿化对自生碳酸盐形成的影响等方面的研究进展,以期加深对陆架边缘海沉积物在全球碳循环收支平衡中的作用及其气候环境效应的认识。 相似文献
204.
The orogenic gold deposits in Southeast Guizhou are an important component of the Xuefeng polymetallic ore belt and have significant exploration potential, but geochronology research on these gold deposits is scarce. Therefore, the ore genetic models are poorly constrained and remain unclear. In the present study, two important deposits(Pingqiu and Jinjing) are investigated, including combined Re-Os dating and the He-Ar isotope study of auriferous arsenopyrites. It is found that the arsenopyrites from the Pingqiu gold deposit yielded an isochron age of 400 ± 24 Ma,with an initial ~(187)Os/~(188)Os ratio of 1.24 ± 0.57(MSWD = 0.96). An identical isochron age of 400 ± 11 Ma with an initial ~(187)Os/~(188)Os ratio of 1.55 ± 0.14(MSWD = 0.34) was obtained from the Jinjing deposit. These ages correspond to the regional Caledonian orogeny and are interpreted to represent the age of the main stage ore. Both initial ~(187)Os ratios suggest that the Os was derived from crustal rocks. Combined with previous rare earth element(REE), trace elements, Nd-Sr-S-Pb isotope studies on scheelite, inclusion fluids with other residues of gangue quartz, and sulfides from other gold deposits in the region, it is suggested that the ore metals from Pingqiu and Jinjing were sourced from the Xiajiang Group. The He and Ar isotopes of arsenopyrites are characterized by ~3 He/~4 He ratios ranging from 5.3 × 10~(-4) Ra to 2.5 × 10~(-2) Ra(Ra = 1.4 × 10~(-6), the ~3 He/~4 He ratio of air), 40 Ar=/~4 He ratios from 0.64 × 10~(-2) to 15.39×10~(-2), and ~(40)Ar/~(36)Ar ratios from 633.2 to 6582.0. Those noble gas isotopic compositions of fluid inclusions also support a crustal source origin,evidenced by the Os isotope. Meanwhile, recent noble gas studies suggest that the amount of in situ radiogenic ~4 He generated should not be ignored, even when Th and U are present at levels of only a few ppm in host minerals. 相似文献
205.
The vast expanse of Mesozoic igneous rocks in Hong Kong contain important geological records of late Mesozoic magmatic events and tectonic processes from the coastal region of Southeast China. Of these,the Ping Chau Formation in the northwestern New Territories is the youngest known stratum. We perform a detailed study of the volcanic rocks of the Ping Chau Formation utilizing zircon U-Pb dating,with major and trace elements geochemistry. LA-ICP-MS zircon U-Pb data reveal Early Cretaceous age from two volcanic rock samples, with zircon crystallization from magmas at 140.3 ± 0.8 Ma and 139.3 ± 0.9 Ma,respectively. These rocks have high contents of total alkalis(Na_2O + K_2O = 5.58-9.45 wt.%), high-field-strength elements and light rare earth elements, conspicuous negative Eu anomalies, and depletions in Nb, Ta, Ti, Sr, Ba and P. Using this data, in combination with previous studies on the late Mesozoic volcanic belt in Southeast China, we propose that the volcanic rocks of the Ping Chau Formation probably originated from deep melting of the crust in a back-arc extensional setting induced by the subduction of the paleo-Pacific Plate. This formation represents the final stages of Early Cretaceous volcanic activity in Hong Kong, as associated with large-scale lithospheric extension, thinning and magmatism. Our results provide new information that can be used in evaluating the significance of Early Cretaceous volcanism and tectonics in Southeast China. 相似文献
206.
Paleoproterozoic volcanic rocks in the southern margin of the North China Craton,central China:Implications for the Columbia supercontinent 总被引:1,自引:0,他引:1
The volcanic rocks of the Xiong'er Group are situated in the southern margin of the North China Craton(NCC).Research on the Xiong er Group is important to understand the tectonic evolution of the NCC and the Columbia supercontinent during the Paleoproterozoic.In this study,to constrain the age of the Xiong'er volcanic rocks and identify its tectonic environment,we report zircon LA-ICP-MS data with Hf isotope,whole-rock major and trace element compositions and Sr-Nd-Pb-Hf isotopes of the volcanic rocks of the Xiong'er Group.The Xiong'er volcanic rocks mainly consist of basaltic andesite,andesite.dacite and rhyolite,with minor basalt.Our new sets of data combined with those from previous studies indicate that Xiong'er volcanism should have lasted from 1827 Ma to 1746 Ma as the major phase of the volcanism.These volcanics have extremely low MgO.Cr and Ni contents,are enriched in LREEs and LILEs but depleted in HFSEs(Nb,Ta,and Ti),similar to arc-related volcanic rocks.They are characterized by negative zircon ε_(Hf)_(t) values of-17.4 to 8.8,whole-rock initial ~(87)Sr/~(86)Sr values of 0.7023 to 0.7177 andε_(Nd)(t) values of-10.9 to 6.4.and Pb isotopes(~(206)Pb/~(204)Pb =14.366-16.431,~(207)Pb/~(204)Pb =15.106-15.371,~(208)Pb/~(204)Pb= 32.455-37.422).The available elemental and Sr-Nd-Pb-Hf isotope data suggest that the Xiong'er volcanic rocks were sourced from a mantle contaminated by continental crust.The volcanic rocks of the Xiong'er Group might have been generated by high-degree partial melting of a lithospheric mantle that was originally modified by oceanic subduction in the Archean.Thus,we suggest that the subduction-modified lithospheric mantle occurred in an extensional setting during the breakup of the Columbia supercontinent in the Late Paleoproterozoic,rather than in an arc setting. 相似文献
207.
Large dams and reservoirs alter not only the natural flow regimes of streams and rivers but also their flooding cycles and flood magnitudes. Although the effect of dams and reservoirs has been reported for some vulnerable locations, the understanding of the inner-basin variation with respect to the effects remains limited. In this study, we analyse the Three Gorges Dam (TGD) built on the Changjiang mainstream (Yangtze River) to investigate the dam effect variations in the system of interconnected water bodies located downstream. We investigated the effect of flow alterations along the downstream river network using discharge time series at different gauging stations. The river–lake interactions (referring to the interactions between the Changjiang mainstream and its tributary lakes i.e. the Dongting and Poyang lakes) and their roles in modifying the TGD effect intensity were also investigated in the large-scale river–lake system. The results show that the water storage of the tributary lakes decreased after the activation of the TGD. Severe droughts occurred in the lakes, weakening their ability to recharge the Changjiang mainstream. As a consequence, the effect of the TGD on the Changjiang flow increase during the dry season diminished quickly downstream of the dam, whereas its impact on the flow decrease during the wet season gradually exacerbated along the mainstream, especially at sites located downstream of the lake outlets. Therefore, when assessing dam-induced hydrological changes, special attention should be paid to the changes in the storage of tributary lakes and the associated effects in the mainstream. This is of high importance for managing the water resource trade-offs between different water bodies in dam-affected riverine systems. 相似文献
208.
Understanding the hydrological processes of colloids within the karst vadose zone is vital to the security of karst groundwater and providing appropriate paleohydrological explanations of colloid-facilitated metals in speleothem. This study addresses the mobilization mechanisms driving colloidal organic matter (COM) transport in the karst vadose zone using a 15-year long monthly monitoring dataset from a cave drip point (HS4) in Heshang Cave, Qingjiang Valley, China. Variations in COM concentrations were reported as the fluorescence difference values of raw and filtered (<0.22 μm) samples at an excitation wavelength of 320 nm and emission wavelength of ~400 nm. A fluorescence humification index (HIX) lower than 0.8 and an autochthonous index (BIX) higher than 1.2 indicated that the origin of COM was mainly from the karst vadose zone, rather than the soil zone. The COM concentration varied from 0.001 to 0.038 Raman Unit (RU), with evident seasonal fluctuations. Rising limbs for COM values occurred prior to rising limbs within a dripwater hydrograph; moreover, the COM peak values corresponding to the beginning of the increasing hydrograph generally suggested that the mobilization of COM reflected the movement of the air–water interface (AWI) in the karst vadose zone rather than rainfall intensity or flow velocity. COM peak values were positively correlated with the antecedent drying duration and negatively correlated with HIX values. These phenomena may be explained by the increased amount of organic matter that was aggregated and absorbed on the surface of carbonate in the karst vadose zone during a longer drying duration. Moreover, the longer drying duration was also beneficial to autochthonous biological activity, which subsequently decreased the HIX value of the organic matter in the karst vadose zone. The movement of AWI and the drying duration are both controlled by the outside weather conditions. This study is therefore conducive to evaluating the security of karst groundwater in response to climate change, and challenges prevailing paleoclimate interpretations of colloid-facilitated metal abundance timeseries reported from speleothems. 相似文献
209.
Forest ecohydrological feedbacks complicate the threshold behaviour of stormflow response to precipitation or wetting conditions on a long-term scale (e.g. several years). In this study, the threshold behaviours in an evergreen-deciduous mixed forested headwater catchment in southern China were examined during 2009–2015, when damaged vegetation was recovering after the great 2008 Chinese ice and snowstorm. The non-uniqueness of the thresholds and the slow and rapid responses of stormflow at the outlet of the catchment in different hydro-climate datasets with different maximum values of gross precipitation (P) and sums of precipitation and antecedent soil moisture index (P + ASI) were assessed. The thresholds of P and P + ASI required to trigger stormflows (i.e. ‘generation thresholds’) and the transition from slow to rapid responses of stormflow (i.e. ‘rise thresholds’) were compared both seasonally and annually. The results indicated significant differences in the analysed datasets, highlighting the need to compare thresholds with care to avoid misinterpretation. Seasonal variations in threshold behaviours in the catchment suggested that vegetation canopy interception contributed to higher rise thresholds, and wetter conditions resulted in higher runoff sensitivity to precipitation during the growing and rainy seasons. Furthermore, the generation thresholds were higher in the dormant season, possibly due to drier soil moisture conditions in the near-channel areas. During the vegetation recovery period, the annual generation thresholds increased, however the rise thresholds did not exhibit a similar trend. The rapid stormflow response above the threshold decreased, possibly due to transpiration and interception of the recovered vegetation. However, the slow stormflow response to small rainfall events below the thresholds was higher in wetter years but lower in drier years, suggesting that the total water input dominated the stormflow response during small rainfall events. In conclusion, the seasonal and annual variations in threshold behaviours highlight that vegetation recovery and hydro-climatic conditions had a notable impact on the stormflow response. 相似文献
210.
Infiltration into frozen soil plays an important role in soil freeze–thaw and snowmelt-driven hydrological processes. To better understand the complex thermal energy and water transport mechanisms involved, the influence of antecedent moisture content and macroporosity on infiltration into frozen soil was investigated. Ponded infiltration experiments on frozen macroporous and non-macroporous soil columns revealed that dry macroporous soil produced infiltration rates reaching 103 to 104 mm day−1, two to three orders of magnitude larger than dry non-macroporous soil. Results suggest that rapid infiltration and drainage were a result of preferential flow through initially air-filled macropores. Using recorded flow rates and measured macropore characteristics, calculations indicated that a combination of both saturated flow and unsaturated film flow likely occurred within macropores. Under wet conditions, regardless of the presence of macropores, infiltration was restricted by the slow thawing rate of pore ice, producing infiltration rates of 2.8 to 5.0 mm day−1. Reduced preferential flow under wet conditions was attributed to a combination of soil swelling, due to smectite-rich clay (that reduced macropore volume), and pore ice blockage within macropores. In comparison, dry soil column experiments demonstrated that macropores provided conduits for water and thermal energy to bypass the frozen matrix during infiltration, reducing thaw rates compared with non-macroporous soils. Overall, results showed the dominant control of antecedent moisture content on the initiation, timing, and magnitude of infiltration and flow in frozen macroporous soils, as well as the important role of macropore connectivity. The study provides an important data set that can aid the development of hydrological models that consider the interacting effects of soil freeze–thaw and preferential flow on snowmelt partitioning in cold regions. 相似文献