祁连造山带玉石沟地幔橄榄岩中挥发分的流体化学和稳定同位素组成及古大洋岩石圈演化意义

Fluid inclusions in olivine and orthopyroxene of mantle peridotites from the Yushigou ophiolite can be divided into three types based on decrepitation temperature,shape and distribution.Type-1 fluid inclusions are characterized by oval or negative crystal shapes and small size(<5μm across).They occur in the cores and mantles of the host crystals,and decrepitated at>840℃.Type- 2 fluid inclusions have irregular or tabular shapes with relatively large size(10～100μm in length).They occur in irregular or circular healed micro-fractures in the host crystals,and decrepitated at 612～710℃.Type-3 fluid inclusions have size and shape,similar to type-2 fluid inclusions but occur in micro-fractures restricted to the margins of the host crystals,and decrepitated at much lower temperature from 190℃to 340℃.The three different types of fluid inclusions are interpreted to represent primary,metasomatic (pseudo-secondary)and secondary inclusions,respectively.Stepwise heating reveals three concentration peaks of volatiles at 200～400℃,400～800℃and 800～1200℃released from olivine and orthopyroxene in harzburgite and dunite from the Yushigou ophiolite, which are considered to correspond to the decrepitation of secondary,metasomatic and primary fluid inclusions at similar temperature ranges.CO2 is a major constituent in the volatiles released at three different temperature intervals.Trace amounts of H_2 and N_2 are present in the volatiles released at<800℃and trace amounts of H_2O and SO_2 are mainly present in the volatiles at 400～800℃.TheδD(-95.2‰,-306.3‰)of H_2O and theδ~(13)C(-15.5～-12.5‰)andδ~(18)O values(1.4～1.9‰)of CO_2 released at<800℃are lower than normal mantle values and suggest the mixing origin of crustal fluids( sedimentary organic)with ocean water,implying that Yushigou AOLM had undergone an intensive metasomatism by a fluid composed of CO_2.H_2O and SO_2,and followed by degassing. In contrast,the volatiles released at 800～1200℃are characterized by trace amounts of H_2 and CO in dunite and SO_2 in harzburgite, much lighterδ~(13)C(-29.1‰～-19.5‰),heavierδ~(13)O(8.8‰)of CO_2 and positive relationship between these isotopic ratios and the concentration of CO_2.Such features can be best explained by mixing of significant terrestrial crustal(organic)and minor mantle volatiles.We proposed that the Yishigou peridotites are more likely to have derived from a continental lithosphere instead of an oceanic lithosphere comprising the Yishigou gabbros and pillowed basalts.A supra-subduction tectonic setting is thus inferred for the Yushigou ophiolite.     

西藏西南部达巴-休古嘎布蛇绿岩带的形成与演化

:该蛇绿岩带的岩体由地幔橄榄岩组成,主要岩石类型是方辉橄榄岩和纯橄榄岩,缺少典型蛇绿岩剖面中的洋壳单元.微量元素和稀土元素特征显示蛇绿岩形成于类似洋中脊的构造环境.笔者提出该区蛇绿岩来源于印度大陆北缘洋盆的洋壳碎片,这个陆缘洋盆与新特提斯洋主体的形成和演化准同步.洋盆的演化模式是:早三叠世,随着印度(冈瓦纳)大陆向南漂移,其北部边缘因引张裂解产生裂谷,于晚三叠世向东开口与新特提斯洋主体连通,洋盆初具洋壳性质,北侧形成阿依拉-仲巴微陆块.侏罗-白垩纪为洋盆洋壳演化期,处于类似洋中脊的构造环境.晚白垩世末洋盆开始闭合.在新特提斯洋板块向北俯冲消减过程中,阿依拉-仲巴微陆块、陆缘洋盆和印度大陆一起随着向北漂移,在印度大陆向北挤压作用下洋盆逐渐收缩以致最终闭合.     

铙钹寨岩体是蛇绿岩吗？——评“也谈铙钹寨超镁铁岩体的成因和构造类型的归属问题”

王希斌等根据铙钹寨岩体恢复的原岩由亏损强烈的方辉橄榄岩、纯橄岩和弱亏损的二辉橄榄岩组成以及有豆荚状铬铁矿存在,认为铙钹寨岩体属于大洋岩石圈地幔,是蛇绿岩的成员;并且还根据岩体存在两种地幔橄榄岩组合进一步推断铙钹寨岩体"可能经历了洋内扩张(形成 MOR 型的地幔残余)和洋内俯冲两个阶段的演化过程"。我们认为,铙钹寨岩体是交代的地幔橄榄岩,它不大可能是蛇绿岩;铙钹寨岩体的特征比较接近大陆岩石圈地慢而非大洋岩石圈地幔;铬铁矿不是判别蛇绿岩的标志;不能根据岩体存在强烈亏损和弱亏损的两种橄榄岩而推断其形成于两种环境。     

The Grenvillian Songshugou ophiolite in the Qinling Mountains, Central China: Implications for the tectonic evolution of the Qinling orogenic belt

The Qinling Mountains in Central China mark a gigantic composite orogenic belt with a complex tectonic evolution involving multiple phases of rifting and convergence. This belt separates the North China and South China Blocks and consists of the South and North Qinling terranes separated by the Shangdan suture. The suture is marked by the Grenvillian Songshugou ophiolite along the southern margin of the North Qinling terrane, which is key to understanding the Proterozoic tectonic evolution of the belt. The ophiolite consists of highly metamorphosed ultramafic and mafic rocks. Three groups of meta-basalts are present: group 1 rocks are LREE depleted and have a MORB compositional affinity. Their low Ta/Yb ratios (<0.1) are consistent with high degrees of partial melting of a depleted asthenospheric mantle. Rocks of group 2 have higher TiO₂ (1.63–2.08 wt%) and Ta/Yb ratios (>0.12), and display slight enrichment of LREE, suggesting that the original magmas were derived from a depleted mantle source mixed with some enriched material. Samples from group 3 are enriched in LREE and other incompatible elements (Ti, Zr, Ta, Nb), suggesting derivation from an enriched mantle source, possibly a plume. All the basalts have high εNd(t) (+4.2 to +6.9), variable εSr(t) and high ²⁰⁷Pb/²⁰⁴Pb and ²⁰⁸Pb/²⁰⁴Pb ratios for given ²⁰⁶Pb/²⁰⁴Pb ratios. These characteristics are compatible with formation at a mid-ocean ridge system above an anomalous Dupal mantle region. The mafic rocks have a Sm–Nd whole-rock isochron age of 1030 ± 46 Ma.The Songshugou ophiolite was emplaced onto the southern margin of the North Qinling terrane, an active continental margin from the Meso-Proterozoic to Neo-Proterozoic.     

西准噶尔石炭纪洋中脊俯冲岩浆活动:以玛里雅蛇绿岩为例

玛里雅蛇绿岩位于新疆准噶尔西缘达拉布特断裂东侧的弧前增生楔内,形成于石炭纪,出露岩石类型齐全,其中硅质岩与火山岩相间出露,多表现为非构造接触。地球化学特征表明,它们大致可以分为四个系列:(1)A系列为岛弧英安岩,Th强烈富集,可能有洋壳沉积物参与,高场强元素Nb亏损,与洋壳的俯冲有关;(2)M系列与典型洋中脊玄武岩的稀土元素配分模式一致,不过Ba强烈富集,可能受到俯冲流体的影响;(3)E系列位于地幔序列N-MORB和E-MORB之间,表明它可能是地幔岩浆的混合产物,未受到地幔岩浆源区之外物质的影响;(4)O系列与典型的洋岛玄武岩基本一致,只是Ta、La和Th含量略偏低,但都处于地幔序列范围内,可能与其他岩浆源有轻微的混合。这种岩浆特征与智利洋中脊俯冲环境下所产生的岩浆特征一致;由于西准噶尔晚古生代仍然发生俯冲消减,因此推测玛里雅蛇绿岩可能形成于洋中脊俯冲环境。     

准噶尔北部蛇绿岩形成时限新证据及其东、西准噶尔蛇绿岩的对比研究

准噶尔北部出露有塔尔巴哈台库吉拜蛇绿岩、洪古勒楞-和布克赛尔蛇绿岩及扎河坝-阿尔曼太蛇绿岩。洪古勒楞蛇绿岩中的堆晶辉长岩样品进行SHRIMP U-Pb定年,结果为472±8.4Ma(MSWD=1.4),限定洪古勒楞-和布克赛尔蛇绿岩形成于早奥陶世。对扎河坝蛇绿岩中斜长花岗岩采用SHRIMP U-Pb方法测定年龄为495.9±5.5Ma(MSWD=2.7),证实扎河坝蛇绿岩形成于晚寒武世-早奥陶世。塔尔巴哈台蛇绿岩、和布克赛尔-洪古勒楞蛇绿岩以及扎河坝-阿尔曼太蛇绿岩均在早奥陶世已经形成,大部分以断层侵位的形式侵位于泥盆纪-石炭系火山-沉积地层中。准噶尔北部东西三段蛇绿岩在形成时代、区域地质以及地球物理特征等方面具有可对比性,认为它们构成一条贯穿东、西准噶尔的蛇绿岩带,这为新疆北部及邻区古生代构造格局的重建以及区域构造的对比连接提供了重要信息。     

义敦型镁铁—超镁铁岩的主要特征及其与蛇绿岩的对比

“义敦型”相当于文献中通称的阿尔卑斯型,但却不是蛇绿岩。蛇绿岩代表洋壳和地慢的岩石组合,而义敦型镁铁-超镁铁岩体则是由陆壳下的地幔及其部分熔融的产物组成的。因此,蛇绿岩与义敦型岩体的构造含意不同,后者的分布与古缝合带无关。在造山带中区分开蛇绿岩和非蛇绿岩是至关重要的。义敦型镁铁-超镁铁岩组合的认定在理论上和找矿实践上都是有意义的。     

A conceptual hydrogeological model of ophiolite hard-rock aquifers in Oman based on a multiscale and a multidisciplinary approach

Ophiolites are found all over the world: from the Alps to the Himalayas, in Cuba, Papua-New Guinea, New Caledonia, Newfoundland, etc. They are composed of hard rocks—basalt, dolerite, gabbro and peridotite, which are formed at the mid-oceanic ridges, with specific ridge-related tectonic fracturing and intense hydrothermal alteration. Their geological and thus their hydrogeological properties differ from those of both granite or classical gabbro and classical basaltic lava. A conceptual hydrogeological model of these hard-rock aquifers was developed based on the convergent results of a multidisciplinary approach at several spatial scales, from rock-sample (centimetre) to catchment (kilometre), on well-preserved ophiolite rocks in Oman. In ophiolite rocks, groundwater circulation takes place mostly in the fissured near-surface horizon (50 m thick), and, to a lesser degree, in the tectonic fractures. Hydrograph analysis (Water Resour Res 34:233–240, 1977), interpretation of numerous pumping tests using both classical Theis and dual porosity models [Water Resour Res 32:2733–2745, 1996; Comput Geosci J (in press)], and mercury porosity and hydraulic conductivity lab-measurements support the aquifer parameter estimates. The hydraulic conductivity K of the fissured horizon is estimated at 10^–5 to 10^–6 m/s for gabbro and dolerite, and 10^–7 m/s for peridotite. The storage coefficient S of the peridotite aquifer is estimated at 10^–3 and appears to be controlled mainly by microcracks (20 to 100 m wide). Tectonic fractures in the ophiolite have similar hydrodynamic properties regardless of lithology (10^–1<T<10^–4 m²/s and 10^–1<S<10^–3) though the probability of obtaining productive wells is two to three times greater in gabbro and dolerite than in peridotite. Some of the tectonic fractures produce small hydrothermal, hyperalkaline springs in the peridotite. The water budget and hydrochemistry of the Oman ophiolite are characterized and support the conceptual hydrogeological model. Despite low annual rainfall, a relatively low hydraulic conductivity and a significant storage coefficient explain why most of the streams in peridotite are perennial.

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Résumé Les ophiolites se trouvent partout dans le monde : des Alpes à lHymalaya, à Cuba, Papouasie Nouvelle-Guinée, Nouvelle Calédonie, etc. Les ophiolites sont composées de roches dures basaltiques, de dolérites, gabbros et péridotites, qui sont formées aux rides mi-océaniques, avec, en relation avec les rides, une fracturation tectonique et une altération hydrothermale intense. Leurs propriétés géologiques et hydrogéologiques diffèrent de celles des granites ou des gabbros classiques ou des laves basaltiques classiques. Un modèle hydrogéologique conceptuel des aquifères de hard-rock a été développé sur les résultats convergents dune approche multidisciplinaire à différentes échelles spatiales, de léchantillon de roche de quelques centimètres à la taille du bassin versant en kilomètres, des ophiolites bien conservées dOman. Dans les roches ophiolitiques, la circulation des eaux souterraines est surtout localisée dans les fissures dun horizon de surface de plus dune cinquantaine de mètres et à un degré moindre dans les fractures tectoniques. Lanalyse des hydrographes (Water Resour Res 34:233–240, 1977), linterprétation des nombreux essais de pompage utilisant des modèles classiques de Theis et des modèles à double porosité (Water Resour Res 32:2733–2745, 1996; Comput Geosci J (Soumis), la porosité au mercure et la conductivité hydraulique calculée en laboratoire supportent lestimation des paramètres de laquifère. La conductivité hydraulique K de lhorizon fissuré est estimée entre 10^–5 et 10^–6 m/s pour les gabbros et les dolérites, et 10^–7 m/s pour les péridotites. Le coefficient demmagasinement S de laquifère de péridotite est estimé à 10^–3 et semble être contrôlé par les micro-fractures (20 à 100 m de largeur). Les fractures tectoniques dans les ophiolites possèdent des propriétés hydrodynamiques en regard de la lithologie (10-1<T<10-4 m²/s et 10-1/S/10-3) bien que la probabilité dobtenir des puits productifs est trois plus grand dans le grabbro et la dolérite que la péridétite. Quelques unes des fractures tectoniques produisent de petites sources hydrothermales hyperalcalines dans la péridotite. Le bilan hydrologique et hydrochimique de lophiolite dOman caractérise le modèle hydrogéologique conceptuel. Malgré des faibles précipitations annuelles, une relativement basse conductivité hydraulique et un coefficient demmagasinement significatif expliquent pourquoi la plus part des cours deau sur les péridotites ne sont jamais taris.

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Resumen Las rocas ofiolitas se encuentran en muchas partes del mundo desde los Alpes a los Himilaya, Newfoundland, Nueva Caledonia etc. Son rocas duras compuestas de basalto, dolerita, gabro y peridotita que son formadas por los cordones medio-oceánicos y por fracturación relacionada con los cordones tectónicos específicos y alteración hidrotermal intensa. La geología y los propiedades hidrogeológicas varian entre las de granito y gabro clásico y lava de basalto clásico. Se desarrolló un modelo conceptual de los acuíferos de las rocas duras Basado en los resultados convergentes de un enfoce multidisciplinario a varias escalas a partir de muestras de roca (centímetro) a cuenca kilómetro) enfocado en las rocas ofilíticas bien preservados en Oman. En las rocas ofiolíticas la circulación de agua ocurre principalmente en el horizonte de fisuras cercanas a la superficie (>50 m de espesor) y en un grado menos importante en fracturas tectónicas. Los estimados de los parámetros de estos acuíferos se basan en análisis de hidrógrafos (Water Resour Res 34:233–240, 1977), en la interpretación de pruebas de bombeo usando los modelos clásicos de Theis y de porosidad doble (Hamm y Bidaux 1996; Lods y Gouze, [en prensa]), y porosidad de mecurio y conductividad hidraúlica medida en el laboratorio. La conductividad hidraúlica K del horizonte fisurado se estima en 10E-5 a 10E-6 m-s para gabro y dolerita y 10E-7 para peridotita. El coeficiente de abastecimiento S del acuífero peridotita se estima en 10–3 y parece ser controlado principalmente por microfracturas (20 to 100 m de ancho). Las fracturas tectónicas en la ofiolita tienen propiedades hidrodinámicas similares independientes de la litología (10–1<T<10–4 m²/s and 10–1<S<10–3) pero la probabilidad de obtener pozos productivos es dos o tres veces mayor en gabro que en dolerita o peridotita. Algunas de las fracturas tectónicas producen pequeñas descargas de agua hidrotermal hiperalcalina en la peridotita. El presupuesto e hidroquímica de las ofilitas de Omán se caracteriza y apoya en el modelo conceptual hidrogeológico. La baja lluvia anual, una conductividad hidraúlica relativamente baja y un coeficiente de abastecimiento importante explican porqué la mejoría de los drenajes en peridotita es peremne.

     

The Wuqbah peridotite, central Oman Ophiolite: Petrological characteristics of the mantle in a fossil overlapping ridge setting

The Wuqbah peridotites (Wuqbah massif, central Oman Ophiolite) constitute the mantle part of a complete ophiolitic sequence and their field deformation geometry is thought to reflect mantle dynamics in a fossil overlapping ridge settings (Girardeau et al., 2002). These peridotites comprise dominantly residual harzburgites and dunites. Nearly 70% of the harzburgites are clinopyroxene-free, and the rest contains less than 1%. The mineral chemistry of olivine, pyroxenes and spinel, and whole rock major and rare-earth element data, indicate that the Wuqbah peridotites are all strongly refractory and that they record a major percolation event, marked by strong enrichments in incompatible elements. At the massif scale, the Central Zone contains rocks with the most refractory features (20% melt extraction), as expected in an area of mantle upwelling. In the overlapping ridge senario, it corresponds to the overlap zone whose formation is discussed.     

Melt impregnation phases in the mantle section of the Ślęża ophiolite (SW Poland)

The ultramafic member of the Variscan Ślęża Ophiolite (SW Poland) consists of heavily serpentinised, refractory harzburgites. Those located down to 1.5 km below paleo-Moho contain scarce grains or aggregates of olivine, clinopyroxene and spinel. Non-serpentine phases occur in various assemblages: M1—olivine (Fo 90.2–91.0%, NiO 0.38–0.47 wt.%) and rounded or amaeboidal aluminous chromite, rimmed by Al poor chromite and magnetite; M2—olivine (Fo 90.5–91.5, NiO 0.32–0.44 wt.%), olivine with magnetite inclusions (Fo 87.1–92.5, NiO 0.01–0.68 wt.%), rounded, cleavaged clinopyroxene I (Mg# 91.1–93.2, Al₂O₃ 3.00–4.00 wt.%, Cr₂O₃ 1.00–1.40 wt.%) and elongated clinopyroxene II and clinopyroxene from symplectites with magnetite (Mg# = 92.2–94.1, Al₂O₃ 2.20–3.20 wt.% and Cr₂O₃ 0.80–1.20 wt.%). Clinopyroxene is depleted in REEs relative to chondrite. The M3 assemblage consists of intergrown olivine (Fo 90.8–92.7, NiO 0.20–0.38 wt.%) and clinopyroxene (Mg# = 96.0–98.1, Al₂O₃ 0.00–1.00 wt.% and Cr₂O₃ 0.20–0.60 wt.%).The M1 assemblage contains chromite which records greenschist-facies metamorphism. Textural relationships and chemical composition of clinopyroxene occurring in the M2 assemblage are similar to those formed in oceanic spreading centres by LREE depleted basaltic melt percolation. Olivine occurring in M1 assemblage and part of that from M2 have composition typical of residual olivine from the abyssal harzburgites and of olivine formed in those rocks by melt percolation. The olivine with magnetite inclusions (M2 assemblage) and that from M3 record later deserpentinization event, which supposedly produced also M3 clinopyroxene. The non-serpentine phases from the Ślęża ophiolite mantle member, albeit very poorly preserved, document depleted basaltic melt percolation in the Variscan oceanic spreading centre.