CaCO3－CO2－H2O岩溶系统的平衡化学及其分析

在介绍了CaCO3- CO2 - H2O岩溶系统平衡化学的原理后,对平衡化学的控制因素,包括温度、CO2 分压、体系的开放程度、离子强度效应、同离子效应、酸效应、碱效应、离子对效应进行了分析,并与CaMg ( CO3 )2 - CO2 - H2O 岩溶系统平衡化学作了对比。结果显示,天然开放的岩溶系统的平衡pH值范围为6. 80～8. 40,在此pH值范围内,水中的碳组分主要以HCO-3 形式存在; 与开放系统相比,在其它条件相同情况下,封闭系统的平衡pH值较高,而平衡[ Ca2+ ]和平衡[ HCO-3 ]较低,特别是在低CO2 分压时,两者的差异更明显;在封闭系统条件下,两种不同的纯CaCO3 - CO2- H2O饱和溶液相混合,将导致溶液对CaCO3 重新具有侵蚀性;离子强度效应、酸效应和离子对效应使方解石的溶解度增加,而同离子效应和碱效应使方解石的溶解度降低; 与方解石溶解平衡相比,其它条件相同时,白云石溶解平衡pH较高,在温度< 70℃时溶解度较大,但在温度> 70℃时溶解度较小。      

O3浓度增加对冬小麦影响的试验研究

利用OTC 1型开顶式气室对冬小麦进行不同O3 浓度处理的试验研究。结果表明 ,O3 浓度增加 ,冬小麦发育期表现为开花前期有所延迟 ,开花后期的各发育期明显提前 ,生育期缩短 ,植株矮化 ,干物质累积量明显下降。无论是长时期通气处理还是阶段性通气处理 ,产量均明显降低     

Multi-Source Emission Determination Using an Inverse-Dispersion Technique

Inverse-dispersion calculations can be used to infer atmospheric emission rates through a combination of downwind gas concentrations and dispersion model predictions. With multiple concentration sensors downwind of a compound source (whose component positions are known) it is possible to calculate the component emissions. With this in mind, a field experiment was conducted to examine the feasibility of such multi-source inferences, using four synthetic area sources and eight concentration sensors arranged in different configurations. Multi-source problems tend to be mathematically ill-conditioned, as expressed by the condition number κ. In our most successful configuration (average κ = 4.2) the total emissions from all sources were deduced to within 10% on average, while component emissions were deduced to within 50%. In our least successful configuration (average κ = 91) the total emissions were calculated to within only 50%, and component calculations were highly inaccurate. Our study indicates that the most accurate multi-source inferences will occur if each sensor is influenced by only a single source. A “progressive” layout is the next best: one sensor is positioned to “see” only one source, the next sensor is placed to see the first source and another, a third sensor is placed to see the previous two plus a third, and so on. When it is not possible to isolate any sources κ is large and the accuracy of a multi-source inference is doubtful.     

内蒙古呼伦湖水量平衡计算与分析

根据呼伦湖的实际水文过程,计算1963-1980年月水量平衡,在此基础上,分析库容与径流、径流+降雨、径流+降雨-蒸发的相关性.利用累积和分析水位、径流、降雨、蒸发年均值的突变情况,进而重点论述了2000年后水位持续降低的原因.同时,探讨各水平衡项的年内分布规律及相互关系.结果表明,2000年后水位的急剧降低是气候变化(暖干化)造成的.河川径流对水位的影响程度最大,其次为湖面降雨.每年4、5月,冰封期积累的降雪融化渗入地下补给湖泊,其他时间则由湖泊补给地下水.     

天然水开放与封闭系统中CaCO_3溶解或沉淀的水化学后果比较

本文以4个水样的水化学分析结果为例,对开放系统与封闭系统中CaCO_3溶解或沉淀所造成的水化学后果进行了计算和比较;在此基础上,还对天然条件下水中CaCO_3溶解或沉淀可能造成的水化学结果进行了讨论.     

Opening GIScience: A process-based approach

Many scholars have demonstrated growing interest in GIScience in recent years, including use of open data portals, shared code and options for open access publication. These practices have made both research and data more transparent and accessible for a broad audience. This research may be open only in a limited sense for populations without expertise in the technology and methods undergirding these data. Based on two case studies using RStudio’s Shiny web platform, we argue that a process-based approach focusing on how analysis is opened throughout the research process provides a supplementary way to define and reflect upon public facing geographic research. Reflecting upon decisions we made at key points in each case study project, we identify four key tensions inherent to work in open GIScience: standardized vs. flexible tools, expert vs. community-led design, single vs. multiple audiences and established vs. emerging metrics.     

Plastic pollution and the open burning of plastic wastes

The open burning of plastic wastes is a practice that is highly prevalent across the globe, toxic to human and environmental health, and a critical—but often overlooked—aspect of plastic pollution. Most of the countries where such burning is widespread have laws and policies in place against it; open burning continues nevertheless. In this article, using data from ethnographic fieldwork in urban and rural sites in India, Indonesia, the Philippines, and Zambia, we examine local practices of open burning and investigate why regulations to tackle it have proven largely ineffective. Adopting a harm reduction approach, we then suggest preliminary measures to mitigate the health risks of open burning by targeting those plastics and packaging types that are most toxic when burned.     

垂直地壳运动的均衡失稳条件探讨

根据Lyapunov稳定理论和耗散结构理论,分析了在均衡力作用下,地壳的均衡调整运动和地壳的反均衡运动的稳定性;推导了判断均衡地壳垂直运动失稳时的熵产生判据和条件;讨论了非线性运动过程中均衡地壳运动系统的反馈性质。作为均衡地壳非稳定性运动的两个实际例子,对青海门源6.4级地震前的重力水准资料和甘肃礼县5.0级地震前的重力水准资料进行了计算,得出了与理论基本一致的结果。     

Access to land reconsidered: The land grab,polycentric governance and Tanzania’s new wave land reform

Inspired by Ostrom’s concept of polycentric governance, this article aims to refine the analytical framework through which contemporary access to land is analysed. By drawing on extensive fieldwork and conducting a review of the existing literature on the making and implementation of Tanzania’s 1999 land reform, it challenges some of the main assumptions behind the land access and land grabbing literatures about the level at which agency is placed. Processes governing access to land are more contingent than they are most often depicted, involving actors at the local, national and international levels. National and local level actors are often more important than, in particular, the land grab literature tends to suggest. This implies that the state should be seen not merely as a site of ‘legitimate theft’, but also as one in which rights may be upheld. Based on the experience of Tanzania, the article suggests that analytical a priori assumptions about where agency is placed should be abandoned and replaced with empirical research into the relations between actors at all levels.     

Establishing a framework for Open Geographic Information science

When conducting research within a framework of Geographic Information Science (GISc), the scientific validity of this work can be argued as highly dependent upon the extent to which the methods employed are reproducible, and that, in the strictest sense, can only be fully achieved by implementing transparent workflows that utilize both open source software and openly available data. After considering the scientific implications of non-reproducible methods, we provide a review of both open source Geographic Information Systems (GIS) and openly available data, before describing an integrated model for Open GISc. We conclude with a critical review of this embryonic paradigm, with directions for future development in supporting spatial data infrastructure.