White-light promoted degradation of leucopterin and related pteridines dissolved in seawater, with evidence for involvement of complexation from major divalent cations of seawater

The photochemical instability of several related pteridines in seawater was investigated by aseptic incubation of solutions at 20–22°C under illumination from cool-white light of intensity 6 kerg cm⁻² sec⁻¹, and the chemical changes were spectrophotometrically monitored. All the pteridines showed markedly accelerated degradation from this illumination relative to their behaviour in total darkness.Pterin and lumazine were degraded very slowly with zero-order reaction kinetics, while the other pteridines photolysed rapidly (according to first-order kinetics) with decomposition rates increasing in the order dioxylumazine (2,4,6,7-tetrahydroxypteridine) < leucopterin < isoxanthopterin < xanthopterin < oxylumazine (2,4,6-trihydroxypteridine). Excepting leucopterin and dioxylumazine, the photolysis rates were attributable to the pH of seawater and not its salt content; this was also the case with oxylumazine which required the salt content of seawater for decomposition in darkness. Leucopterin and dioxylumazine (both 6,7-dihydroxylated pteridines) gave evidence of complexation with the major divalent cations (Ca²⁺, Mg²⁺) of seawater, by virtue of which their photolytic degradation rates were enhanced to magnitudes obtained in pH-10 buffer without seawater. It is proposed that such complexation produces structural forms of these pteridines analogous to their normal ionic forms at pH 10–12.The photolysis of the 6-hydroxylated pteridines (xanthopterin, oxylumazine) proceeded via intermediate formation of their corresponding 7-hydroxylated derivatives (leucopterin, dioxylumazine).     

Preliminary optical classification of lakes and coastal waters in Estonia and south Finland

A preliminary optical classification of lakes in Estonia and south Finland which can also be used for small bays of the Baltic Sea is elaborated. The classification is based on the optical properties of water (diffuse attenuation coefficient, diffuse reflectance) and parameters that are routinely monitored in water bodies (Secchi depth, concentration of chlorophyll-a, total suspended matter and yellow substance). The data complex used for our classification covers different types of water ecosystems (ranging from oligotrophic to hypertrophic) and the variability of water constituent concentrations in the ice-free period in Estonia and south Finland. Using cluster analysis, we found 5 optical classes of waters: clear (C), moderate (M), turbid (T), very turbid (V) and brown (B). There is satisfactory correspondence between class of water, shape of diffuse attenuation coefficient and diffuse reflectance spectra and trophic state of the lakes.     

青岛浮山野生花卉种质资源

本文简要叙述了青岛浮山野生花卉的种类、生长环境、园林用途及开花结果日期，为把这些野生花生花卉引进城市园林提供科学依据。     

Exchange flow of oil and sea-water in a ruptured submarine pipeline

The rupture of a submarine oil pipeline starts various mechanisms leading to an oil spill. Among these mechanisms the leakage of oil driven by the difference in specific gravities of oil and sea-water is difficult to estimate. A simple mathematical model has been developed and laboratory experiments have been carried out to obtain an insight into the density-driven exchange flow and to determine the leak rate. The mathematical model is predictive and takes account of the effects of friction, inclination of the pipeline, and inertia of the fluid. The experiments were done in a horizontal model pipeline. Theoretical and experimental results are in satisfactory agreement.     

浙、闽海域仙菜科[CERAMIACEAE(RHODOPHYTA)]海藻研究Ⅰ

根据1957～1987年期间采自浙江和福建沿岸的仙菜科海藻标本，初步鉴定有7属14种。分两次报道，首先报道其中的5屑7种：复羽多孢藻Pleonosporiumvenustissimum、日本对丝藻Antithamnionnipponicum和卡洛绢丝藻Callithamnioncallophyllidicola为我国首次较全面描述和绘图记录；赫勒对丝藻Antithamnionhubbsii为浙、闽海域首次报道；而如下三个种纵胞藻Centrocerasclavulatum、日本凋毛藻Griffithsiajaponica和对公藻Antithammioncruciatum在浙、闽海区早有报道。     

正弦锁相环路方程的调和解、浑沌与分支

讨论调频输入正弦锁相环路方程的调和解、浑饨与分支。利用Melnikov方法确定了产生浑沌与次谐波分支及其稳定性的条件，同时我们证明了当方程的参数适当小时，它必存在调和解。     

任意曲线曲面上重磁位场转换的B样条函数法

提出用B样条函数求解曲线、曲面上重磁位场的向上延拓,水平、垂向导数计算,磁异常分量互换的方法。该方法的特点是:原理简明,程序通用性强,计算精度高。     

山西能源重化工基地建设研究

山西能源重化工基地建设关系到全国四个现代化的实现,被列为国家重点建设工程,制定了《山西能源重化工基地综合规划》。本文分析了80年代山西省经济建设的成就与问题。提出了“整体创新,综合开发”,把山西能源重化工基地建设成内陆经济开放区的战略大思路,为此,90年代应完成11项大型经济战略工程,同时展望了经济发展改革前景。     

浅层SH反射波法和多道瞬态面波法 进行联合工程勘察的讨论

针对目前单一工程物探方法调查浅部地质结构的局限性,提出采用弹性波法勘察中研究浅部地质结构的SH波反射勘察和多道瞬态面波法勘察这2种有效手段进行联合勘探,提高其可靠性和精度,并给出了3个实例,指出了在数据采集和处理时应注意的问题。