黑色岩型铂族矿物中铂钯金相态ICP-MS分析方法研究

黑色岩是近年发现的铂族元素重要载体,由于其金属来源的多样性及成矿作用的复杂性,对于铂族元素在该类矿物中的分布及富集形式目前并不十分清楚,这也是造成黑色岩中铂族元素测定不稳定的主要原因。本文根据黑色岩的矿物性质及组成,将黑色岩中Pt、Pd、Au的赋存状态划分为:可交换相、有机结合相、硫化物结合相、残渣相。通过应用硫氰酸钾+氰化钠作为解吸剂,有效抑制了黑色岩中有机碳对各相态中Pt、Pd、Au的吸附,采用分离富集ICP-MS法测定了Pt、Pd、Au在各相态中的分布。结果表明:(1)各元素各相态的提取总量与该元素在样品中的总量之比分别为Pt 94.4%~101.0%,Pd 95.8%~101.0%,Au 96.7%~102.0%,说明本方法具有较好的准确性和重现性;(2)黑色岩矿物中Pt、Pd、Au的富集不仅具备亲硫性,而且与有机碳形成的地质条件、地质背景有明显的相关性,此结果为研究黑色岩中铂族元素所处的地球化学环境及其成矿规律提供了重要信息。     

西准噶尔晚泥盆世碱性玄武岩的地球化学特征及其与塔里木大火成岩省岩浆岩对比

西准噶尔是近年来中亚造山带的研究热点地区之一,发育多条蛇绿混杂岩带。随着研究的深入,蛇绿岩混杂岩带中不断有碱性洋岛玄武岩被识别出来。本文对克拉玛依及达尔布特蛇绿混杂岩中的晚泥盆世枕状玄武岩进行详细的岩石地球化学及Sr?Nd同位素组成研究。结果表明西准噶尔晚泥盆世枕状玄武岩属于碱性玄武岩系列,岩石具有高TiO₂ （2.3%～3.8%）及P₂O₅ （0.38%～0.91%）,低MgO （2.41%～4.97%）,轻、重稀土元素分异较为明显,(La/Yb)_N = 5.1～14.5,无明显Eu异常（Eu/Eu* = 0.96～1.1）,相对富集Rb、Th、U,亏损Ba、K、Sr,没有明显Nb、Ta负异常,这些地球化学特征与洋岛玄武岩（OIB）极其相似。克拉玛依及达尔布特蛇绿混杂岩中枕状玄武岩具正ε_Nd(t)值（3.3～4.4）及年轻的模式年龄（0.83～0.72 Ga）,表明其来源于亏损地幔源区,通过同位素及微量元素研究认为源区可能为富辉石的橄榄岩,或不含橄榄石的辉石岩和角闪石岩,克拉玛依及达尔布特蛇绿混杂岩中的晚泥盆世枕状玄武岩形成于大洋板内与地幔柱有关的海山/大洋岛屿环境。这些明显不同于大陆板内具有富集特征的塔里木大火成岩省,它们分别属于两个明显不同的同位素地球化学省,即以富集型地幔为同位素组成的南部省及以亏损型地幔为同位素组成的北部省。     

Organic matter source and thermal maturity within the Late Cretaceous Niobrara Formation,U.S. Western Interior

The Late Cretaceous sedimentary record of the North American Western Interior Seaway is characterized by cyclic deposition of organic carbon-rich sediments. One notable interval during the late Coniacian-Santonian is recorded by the Niobrara Formation. The organic carbon-rich interval within the Niobrara Formation has been identified as Oceanic Anoxic Event (OAE) 3. Understanding the reason for this distribution of organic carbon within the Niobrara Formation requires a refined understanding of the source and maturity of the organic matter. In this study, we present lipid biomarker records from the USGS Portland #1 core (Cañon City, CO) to constrain the thermal maturity of the organic matter and the differing contributions of organic matter sources. Sterane and hopane thermal maturity indices indicate that the samples are somewhat immature with respect to oil formation and that there is strong agreement between different proxies for thermal maturity. Based on the distribution of n-alkanes, steranes, and hopanes, there is a significant increase in the contribution of algal organic matter during and after OAE 3, coeval with increased organic carbon accumulation. Although a consistent terrestrial contribution is observed, it is only a minor source of organic matter at the Portland core location and does not drive increased organic matter accumulation during OAE 3. Of particular note is the consistent influence of even-over-odd predominantly mid-chain length (C₂₁ to C₂₅) organic matter. This observation within the brackish to marine, not methanogenic WIS represents an expansion of the depositional settings in which even-over-odd predominance has been observed in mid-chain length n-alkanes. Pristane (Pr) and phytane (Ph) abundances are inconsistent with a redox control on Pr/Ph ratios and suggest an increase in the delivery and/or preservation of phototrophic organic matter as the source for pristane and phytane in the Portland core.     

三种垂向混合方案对HYCOM模拟北太平洋西边界流系的影响研究

基于HYCOM(Hybrid Coordinate Oceanic Circulation Model),以OFES(OGCM for the Earth Simulator)资料为参考,分析了KPP、MY2.5、KT三种不同混合方案对北太平洋西边界流系的模拟结果的影响。结果表明:三种不同混合方案模拟的上层海洋平均流场与OFES资料相似,但在流向和流幅上略有差异,其中KPP方案模拟的流速与OFES资料最为接近,MY2.5方案次之,KT方案与其差别最大。通过代表性断面上流速的对比分析,对模式就北赤道流、棉兰老流、棉兰老潜流、黑潮的模拟效果进行比较,KPP方案模拟的效果同前人的观测和研究最为接近。分析了北赤道流,棉兰老流,棉兰老潜流,黑潮的流量的季节变化特征,其中KPP方案与OFES资料计算的棉兰老流和棉兰老潜流的季节变化特征与前人描述比较一致,表现为春强秋弱。KPP方案和OFES资料的计算结果表明,北赤道流和棉兰老流大致上是同向变化的,而在冬季棉兰老流同黑潮的变化基本上是一致的。     

深海锰结核以煤代焦还原熔炼新工艺研究

针对锰结核焦炭还原熔炼成本高、焦炭生产过程环境污染严重等问题,作者提出了锰结核以煤代焦还原熔炼新工艺,对减少锰结核冶炼环境污染、降低冶炼成本,具有积极意义.以东北太平洋中部深海锰结核为原料,对还原温度、还原时间、硅石加入量、无烟煤加入量对锰结核中Co、Ni、Cu、Fe、Mn回收率的影响进行了研究.结果表明:500 g锰...     

时间滑动相关方法在SST可预报性及可信计算时间研究中的应用

将时间滑动相关方法 STC(sliding temporal correlation)用于研究混沌系统和海洋环流模式的可信计算时间RCT(reliable computation time),Lorenz混沌系统的数值试验表明用STC求得的可预报时间和可信计算时间,与使用传统误差限方法所得结果一致,证明了其有效性。对海洋环流模式LICOM和NEMO的研究发现:1.当海洋模式以非耦合的方式运行时,试验的结果表明其海表温度SST的可信计算时间较长,平均达到6个月以上,这主要是由于海洋模式的运行过程中,采用恢复性边界条件使模拟结果不会太过偏离观测值。对于强迫场从1月开始的试验,LICOM模式的SST可信计算时间在赤道东太平洋和西北太平洋地区存在RCT低值区,其数值不超过2个月。而NEMO模式在赤道太平洋地区全是RCT高值区,NEMO模式的RCT低值区域出现在赤道外的太平洋和大西洋中纬度地区,强迫场从7月开始的试验,RCT纬向平均分布与1月有相反的形式。2.海洋模式以耦合方式运行时,由于去掉了恢复边界条件作用,海洋模式预报的SST可信计算时间明显减小,年平均RCT为1个月左右。按季节平均得到的RCT变化不大,在30~40天之间,RCT的大值区春季位于南半球,而秋季位于北半球,可达2个月以上。耦合模式中所模拟的500 h Pa高度场的RCT与单独运行的大气模式所得结果相差不大,仍在2周以内。3.无论是按季节平均还是按海区平均所得到的RCT分布,都在30~60天左右,只有极少数区域在特定季节可以达到80天以上,这说明在海气耦合模式中,由于计算不确定造成的可预报上限一般不超过2~3个月,这比使用资料分析得到可预报期限短很多,因此根据木桶原理,RCT可能是制约海气耦合模式SST预报能力的一个重要因素。     

一个压力坐标海洋环流模式(PCOM1.0)的基本模拟性能评估

参照Griffies et al.(2009)提出的海洋—海冰耦合模式参考试验(Coordinated Ocean-ice Reference Experiments,COREs),设计了一个800年积分的数值试验,对一个质量严格守恒的压力坐标海洋环流模式(Pressure Coordinate Ocean Model,PCOM1.0)的基本模拟性能进行了评估,并与观测资料和再分析资料进行了对比。结果表明,PCOM1.0模拟的温盐场和基本流场与COREs模式的模拟水平基本接近。其中,模拟的大西洋经向翻转流在45°N附近达到18 Sv(1 Sv=106 m3 s-1),与观测估计值接近;对海表面温度的模拟误差主要集中在北太平洋黑潮区和北大西洋湾流区等中高纬度急流区;模拟的热带太平洋温跃层过于深厚;模拟的经德雷克海峡的体积输送达130 Sv,比大部分COREs模式及再分析资料都更接近于观测估计值。     

The Gulf Stream pathway and the impacts of the eddy-driven abyssal circulation and the Deep Western Boundary Current

A hydrodynamic model of the subtropical Atlantic basin and the Intra-Americas Sea (9–47°N) is used to investigate the dynamics of Gulf Stream separation from the western boundary at Cape Hatteras and its mean pathway to the Grand Banks. The model has five isopycnal Lagrangian layers in the vertical and allows realistic boundary geometry, bathymetry, wind forcing, and a meridional overturning circulation (MOC), the latter specified via ports in the northern and southern boundaries. The northward upper ocean branch of the MOC (14 Sv) was always included but the southward Deep Western Boundary Current (DWBC) was excluded in some simulations, allowing investigation of the impacts of the DWBC and the eddy-driven mean abyssal circulation on Gulf Stream separation from the western boundary. The result is resolution dependent with the DWBC playing a crucial role in Gulf Stream separation at 1/16° resolution but with the eddy-driven abyssal circulation alone sufficient to obtain accurate separation at 1/32° resolution and a realistic pathway from Cape Hatteras to the Grand Banks with minimal DWBC impact except southeast of the Grand Banks. The separation from the western boundary is particularly sensitive to the strength of the eddy-driven abyssal circulation. Farther to the east, between 68°W and the Grand Banks, all of the 1/16° and 1/32° simulations with realistic topography (with or without a DWBC) gave similar generally realistic mean pathways with clear impacts of the topographically constrained eddy-driven abyssal circulation versus very unrealistic Gulf Stream pathways between Cape Hatteras and the Grand Banks from otherwise identical simulations run with a flat bottom, in reduced-gravity mode, or with 1/8° resolution and realistic topography. The model is realistic enough to allow detailed model-data comparisons and a detailed investigation of Gulf Stream dynamics. The corresponding linear solution with a Sverdrup interior and Munk viscous western boundary layers, including one from the northward branch of the MOC, yielded two unrealistic Gulf Stream pathways, a broad eastward pathway centered at the latitude of Cape Hatteras and a second wind plus MOC-driven pathway hugging the western boundary to the north. Thus, a high resolution model capable of simulating an inertial jet is required to obtain a single nonlinear Gulf Stream pathway as it separates from the coast. None of the simulations were sufficiently inertial to overcome the linear solution need for a boundary current north of Cape Hatteras without assistance from pathway advection by the abyssal circulation, even though the core speeds of the simulated currents were consistent with observations near separation. In the 1/16° simulation with no DWBC and a 1/32° simulation with high bottom friction and no DWBC the model Gulf Stream overshot the observed separation latitude. With abyssal current assistance the simulated (and the observed) mean Gulf Stream pathway between separation from the western boundary and 70°W agreed closely with a constant absolute vorticity (CAV) trajectory influenced by the angle of the coastline prior to separation. The key abyssal current crosses under the Gulf Stream at 68.5–69°W and advects the Gulf Stream pathway southward to the terminus of an escarpment in the continental slope. There the abyssal current crosses to deeper depths to conserve potential vorticity while passing under the downward-sloping thermocline of the stream and then immediately retroflects eastward onto the abyssal plain, preventing further southward pathway advection. Thus specific topographic features and feedback from the impact of the Gulf Stream on the abyssal current pathway determined the latitude of the stream at 68.5–69°W, a latitude verified by observations. The associated abyssal current was also verified by observations.     

南海温盐流数值产品构建及评估

基于区域海洋模式ROMS构造了一套覆盖中国南海的40年（1980—2019年）温盐流数值产品OCEAN＿SCS。OCEAN＿SCS的变量包含了温度、盐度、流速、流向以及海表高度。OCEAN＿SCS的水平空间分辨率为0.1°×0.1°,垂向分层40层（0～5 000 m）,时间分辨率为1小时,包含潮汐信息。利用独立的观测资料对OCEAN＿SCS进行了初步评估,评估对象包括温度、盐度、海表高度、海流、潮位和增水。在不包含资料同化的前提下,OCEAN＿SCS的模拟精度达到了较高的水准。OCENA＿SCS的构建将为南海海洋环境的研究提供数据支撑,并服务于南海海洋环境保障。     

正压准平衡海洋模型及其解（Ⅰ）：中纬度大尺度风场强迫情况

本文建立了风场强迫下考虑瑞利摩擦的水平二维正压准平衡海洋模型,并对中纬度大尺度风场强迫的情况做了解析求解。结果表明,在近地面西风急流的强迫下,在理想海洋的西海岸以东会出现由气旋涡与反气旋涡构成的涡旋偶;当西风强迫越大,粘性越小时其强度越大,而β越大,β通道的半宽越小,则其沿纬向的变化越剧烈;该涡旋偶的性质属准平衡的涡旋波。将该结果与北太平洋上层流场异常的复EOF分析的第一模态作比较后可见,两者有类似之处。最终,该海洋模型的解则趋于该风场强迫特解。