黔西北大方地区龙潭组海陆过渡相烃源岩特征及评价

黔西北大方地区龙潭组以泥页岩、煤层与砂岩交替互层发育为特点,具有典型的海陆过渡相特征。文章在剖面实测和样品采集的基础上,结合全岩和黏土矿物XRD分析、总有机碳(TOC)含量测定、岩石热解、干酪根显微组分及镜质体反射率(R_O)等分析,对研究区龙潭组烃源岩发育特征进行了研究和评价。结果表明: ① 龙潭组矿物以黏土矿物为主,具有较强的吸附能力,但黏土矿物含量与石英含量呈明显的负相关关系(R>0.8),尤其是泥页岩中70%以上的黏土含量以及较低的脆性指数增加了压裂开发的难度。 ② 龙潭组有机质丰度受岩性变化控制明显。煤层具有最高的TOC含量(平均值42.9%)和生烃潜量(平均值为2.68 mg/g),显示强大的煤层气生烃潜力;泥页岩生烃潜量均小于2 mg/g,但约有80%样品的TOC含量超过2%,页岩气资源潜力不及煤层气;粉砂岩生烃潜力最差,生烃潜量平均值为0.13 mg/g,TOC含量为1.4%~5.6%,显示一定的致密气潜力。 ③ 龙潭组有机显微组以壳质组和镜质组占主导,干酪根以Ⅲ型为主,Ⅱ₂型为辅,热演化程度高,处于高-过成熟的生干气阶段。 ④ 煤层更为发育的龙潭组中段是大方地区煤层气、页岩气和致密砂岩气联合勘探的有利层段。     

层序和体系域的有机相构成及其研究意义

层序地层学为沉积盆地的充填史分析和储层预测提供了有效的格架，但其在源岩评价和预测中的意义未能引起充分的重视。本文对莺海、琼东甫盆地的各沉积层序进行了有机相分析，发现（１）浅水型沉积层序中各体系域的机相构成基本相同，且有机相的侧向变化不明显；（２）在深水型层序中，海进体系域上部和高位体系域下部有机质丰度较高、类型较好，有机相层序呈Ｓ性，但有机的侧向变化明显；（３）多层序有机相的总体演化趋势反映了盆地     

旅游溶洞内氡污染和从业人员的辐射防护

在我国南方许多已辟为旅游景区(点)的溶洞中,氡及其子体浓度严重偏高,有的甚至超过放射性矿区坑道作业面上最大容许浓度,危害旅游从业人员和游客的健康,应引起有关部门的重视。     

采矿环境地球化学研究

阐述了采矿对环境造成的负面影响 ,包括 :尾矿或废石堆中的杂质元素会进入表生地球化学循环 ,在不同气候条件下 ,呈现不同的特征模式 ,尾矿氧化带的酸性水的排放 ;矿山污染源对周围土壤和植物的影响使重金属元素等进入食物链 ,对人类和动物健康造成威胁。根据国内外的最新研究动向 ,指出建立环境地球化学模式 ,对采矿环境污染作出客观的监测和评价 ,能为防止污染和治理环境提供可靠的地球化学依据。     

鄂尔多斯盆地盐池-定边地区长7烃源岩有机地球化学特征及沉积环境研究

通过对鄂尔多斯盆地盐池-定边地区长7段烃源岩的分析,研究区长7段烃源岩有机碳平均含量为3.22%,生烃潜量均值为12.8 mg/g,氯仿沥青“A”均值为0.55%,可以划分为较好-好的烃源岩,具有良好的生烃潜力。利用有机岩石学分析、热解分析,并结合饱和烃生物标志物分析,发现研究区长7段烃源岩有机质类型以Ⅱ₁型和Ⅱ₂型为主,有机质以菌藻类生源为主,并伴有部分高等植物生源。烃源岩有机质成熟度R_o值介于0.42%~0.76%之间,并且热解T_max也主要集中在440~455 ℃之间,并且正构烷烃分布特征及甾、藿烷异构化参数说明烃源岩有机质处于低熟-成熟度阶段。根据饱和烃中甾藿烷参数、三环萜烷参数、伽马蜡烷指数、β-胡萝卜烷相对含量以及姥植比参数特征,研究区长7段烃源岩沉积环境为湖相淡水弱氧化-弱还原环境。     

Fault Systems and their Control of Deep Gas Accumulations in Xujiaweizi Area

A study of faults and their control of deep gas accumulations has been made on the basis of dividing fault systems in the Xujiaweizi area. The study indicates two sets of fault systems are developed vertically in the Xujiaweizi area, including a lower fault system and an upper fault system. Formed in the period of the Huoshiling Formation to Yingcheng Formation, the lower fault system consists of five fault systems including Xuxi strike-slip extensional fault system, NE-trending extensional fault system, near-EW-trending regulating fault system, Xuzhong strike-slip fault system and Xudong strike-slip fault system. Formed in the period of Qingshankou Formation to Yaojia Formation, the upper fault system was affected mainly by the boundary conditions of the lower fault system, and thus plenty of multi-directionally distributed dense fault zones were formed in the T2 reflection horizon. The Xuxi fault controlled the formation and distribution of Shahezi coal-measure source rocks, and Xuzhong and Xudong faults controlled the formation and distribution of volcanic reservoirs of Y1 Member and Y3 Member, respectively. In the forming period of the upper fault system, the Xuzhong fault was of successive strong activities and directly connected gas source rock reservoirs and volcanic reservoirs, so it is a strongly-charged direct gas source fault. The volcanic reservoir development zones of good physical properties that may be found near the Xuzhong fault are the favorable target zones for the next exploration of deep gas accumulations in Xujiaweizi area.     

Detrital zircon ages and Hf isotopic compositions of metasedimentary rocks in the Wuqia area of Southwest Tianshan,NW China: implications for the early Paleozoic tectonic evolution of the Tianshan orogenic belt

ABSTRACT

The Chinese Southwest Tianshan Orogenic Belt is located along the boundary between the Central Asian Orogenic Belt (CAOB) and the Tarim Block (TB), NW China. It records the convergence of the Tarim Block and the Middle Tianshan, and is, therefore, a crucial region for understanding the Eurasia continental growth and evolution. The Wulagen (geographical name) metasedimentary rocks of the Wuqia area (mainly metamorphic sandstones and mica schists) form one of the metamorphic terranes in the Southwestern Tianshan Orogenic Belt. The geochronology of these rocks is poorly known, which hampers our understanding of the tectonic evolution of the belt. We analyzed 517 zircon grains for detrital zircon U–Pb dating and 93 zircon grains for in situ Lu–Hf isotopic compositions from the Wulagen metasedimentary rocks. The analyzed zircon grains yield Neoarchean to late Paleozoic U–Pb ages with major age peaks at ~2543 Ma, 1814 Ma, 830 Ma, 460 Ma, and the youngest cluster of zircon (magmatogene) ages is 395 Ma. The zircon U–Pb data show that the late Paleozoic (Early Devonian) is the maximum depositional age of the Wulagen metasedimentary rocks, rather than the previously considered Precambrian period. The zircons with Paleozoic ages yield εHf(t) values of ?22.0 to +11.3 and two-stage model ages (TDM₂) of 3.95 to 1.30 Ga, suggesting that the parental magmas were formed from partial melting of pre-existing crustal rocks. Our zircon U–Pb geochronology and Hf isotopic data indicate the major source regions for the Wulagen metasedimentary rocks was the Kyrgyzstan North Tianshan. The zircon age population of 600–400 Ma (peak at ~460 Ma) has negative εHf(t) values (?15.0 to ?0.6) and Mesoproterozoic two-stage model ages, suggesting that the early Paleozoic magmatism resulted mainly from the melting of ancient crust, which played an important role in crustal evolution in the southern CAOB.     

华南花岗岩物源成因特征与陆壳演化

华南不同时代的花岗岩按物质来源及成因可划分为:幔源(分异)系列:幔-壳混源(同熔)系列;壳源改造(重熔)系列和幔-壳混源碱性系列等四个不同的系列,简要阐述了划分四类系列的岩石学、地球化学的依据。侧重根据Sm-Nd、Rb-Sr同位素成分,以二元混合模型计算了花岗岩源区物质组成中,上壳和亏损地幔组份各占的比例。在此基础上探讨了不同物源成因系列花岗岩形成与华南陆壳演化的内在联系:东安、雪峰旋回褶皱系阶段花岗岩物源成因类型比较多样,有幔源(分异)系列、不成熟壳源、成熟壳源改造(重熔)系列等;加里东,海西期以陆壳改造(重熔)系列为主;印支、燕山期活化区(地洼)阶段,在地幔活化激发下,中国东部陆缘形成幔—壳混源(同熔)系列花岗岩和相应的火山岩;但沿内部断裂带,在壳下地幔热传输及构造作用下引起陆壳重熔,形成属于壳源改造(重熔)系列花岗岩。同位素的研究证明了:地洼阶段的构造-岩浆活动主要动力是来自壳下地幔的活化。     

小秦岭太峪水系沉积物重金属污染生态危害评价

以金矿开发影响的黄河二级支流太峪水系沉积物为研究对象,沿河采集16个表层沉积物样品,分层采集垂向剖面10件水库沉积物样品,测定了样品中重金属元素Hg、Pb、Cd、Cr、As、Cu和Zn的含量,采用Hakanson潜在生态指数法和Tomlinson污染负荷指数法评价重金属元素污染程度和潜在生态风险。结果表明,矿业活动是太峪水系沉积物重金属元素污染的主要因素;变异系数、富集系数和最高污染系数均反映Hg、Pb、Cd是太峪水系沉积物的特征污染重金属元素,Cr和As的质量分数接近地区背景值;太峪水系表层沉积物受到重金属元素的极强污染,山区段污染较山外更严重;整个流域的Hg、Pb、Cd具有很强的潜在生态危害,Cr、As、Zn的潜在生态危害轻微;太峪水系沉积物垂向各层沉积物都受到重金属元素的极强污染,生态问题以Hg、Pb、Cd的潜在生态危害为主,其污染和生态危害程度都高于流向上的沉积物。潜在生态危害指数评价突出了不同元素的毒性和危害程度,而污染负荷指数法侧重于样本空间上的污染程度,二者互补使用有利于实际问题的全面评价。     

重庆青鹏煤矿-200m水平突水水源分析

青鹏煤矿位于重庆市沙坪坝区青木关镇及壁山县壁城镇,已开采50余年.随着开采水平的延深,矿井地下水流场发生了相应的变化,改变了地下水原有的补、径、排条件.2012年2月,青鹏煤矿-200m水平-22103运输巷施工过程中,碛头煤层(M2)顶板裂隙突水造成局部淹井事故.通过地面及井下水文地质调查以及采取地表水、泉水、矿井水样进行水质分析,指出矿井突水水源由须家河组裂隙水、采空区积水和嘉陵江组灰岩岩溶裂隙水的越流补给3部分组成.为矿井防治水提供了水文地质依据.