有机酸对长石溶解度影响的热力学研究

为明确认识有机酸（草酸、醋酸）对长石溶解度及储层次生孔隙发育的影响，本文利用热力学方法，计算了不同温度、酸度下钾长石在含有醋酸根0.05mol/L、草酸0.0055mol/L的溶液中的溶解度及草酸和醋酸对溶液酸度的影响，计算的结果表明醒酸根与铝的络合作用只发生在偏酸性的溶液体系中，并且随温度升高要求酸度增加，实际的络合能力降低，醋酸根的络合作用对长石溶解度的增加作用极及有限，最高时不足一倍；但醋酸能有效地缓冲溶液酸度，从而提高长石溶解度。草酸根与铝的络合作用发生在弱碱性至酸性条件下，温度升高，络合能力增加，络合效应对长石溶解度，草酸根上铝的络合作用发生在弱碱性至酸性条件下，温度升高，络合能力增加，络合效应对长石溶出量的增加最多可达2个数量级以上，草酸的浓度太低无法通过缓冲溶液在较高的酸度下来促进长石的溶解，草酸和醒酸能否促进储层次生孔隙的发育取决于盆地流体的酸度及组成流体的缓冲体系。     

Land subsidence caused by groundwater exploitation in Suzhou City,China

Suzhou City, located at the lower reaches of the Yangtze River in southeastern Jiangsu Province, is one of the few cities in China which suffer from severe ground settlement. A research project was carried out to investigate this problem. Geological and hydrogeological studies show that there is a multi-layered aquifer system with three distinct, soft mud layers of marine and lagoonal origins. An examination of historical records of groundwater extraction, water levels, and ground settlement shows that the ground subsidence is associated with the continuously increasing groundwater extraction in the deep, confined aquifer. It is believed that the consolidation of the soft mud layers, especially the third layer which is thick and close to the main pumped aquifer, contributes to the ground settlement. A three-dimensional finite difference numerical model representing the multi-layered aquifer system was developed to study the ground settlement in response to groundwater extraction. By calibrating the model with both the measured groundwater level and ground settlement, the aquifer parameters were estimated. The model outputs fit reasonably well with the observed results, which indicates that the numerical model can reproduce the dynamic processes of both groundwater flow and soil consolidation. The hydraulic conductivity of the third mud layer near the center of the ground settlement has been reduced by over 30% in the last 14 years. The gradual deterioration in the hydraulic conductivity of the mud may have significant adverse effect on the sustainable groundwater resource of the deep confined aquifer, since the recharge from the shallow aquifers through the mud layer is the only source of water to the deep aquifer. An analysis of the spatial distributions of groundwater drawdown and ground settlement shows that the area with maximum drawdown is not necessarily the area with maximum ground settlement due to the occurrence of the soft mud layer. A simple reallocation in pumping rates on the basis of the spatial distribution of the thick mud layer could significantly reduce the ground settlement. Electronic Publication     

岩质高边坡稳定性支持向量机预测方法研究

提出一种基于支持向量机的岩质边坡稳定性预测方法。该方法地很好的表达了岩质边坡稳定性与其影响因素之间的非线性映射关系,并应用该方法建立了相应的模型。预测结果表明,利用该方法进行岩质边坡稳定性预测是可行的、有效的。     

热液中铅、锌、银共生分异的热力学探讨

通过元素基本性质的对比以及热力学计算分析，探讨了热液中银、铅、锌的共生分异机制。在酸性至近中性条件下，氯配合物是它们在热液中的存在形式，其中锌氯配合物最稳定；在近中性到碱性条件下，硫氢配合物占主导地位，此时，银硫氢配合物相对最稳定。温度下降、[Cr]降低、pH升高及f(O2)降低，引起银、铅、锌配合物溶解度减小，发生沉淀分离；对于硫氢配合物，其稳定性主要受pH及还原硫浓度的影响。因此，配合物的不同存在形式以及配合物稳定性之间的差异，使得它们对热液条件的改变做出不同的响应，从而导致了热液中银、铅、锌在成矿过程中的共生分异。     

基于CNOP方法的台风目标观测中三种敏感区 确定方案的比较研究

在目标观测中,敏感区的确定是个关键性的问题。本文详细研究了如何用条件非线性最优扰动（CNOP）方法确定敏感区。提出了三种确定敏感区的方案:水平投影方案、单点能量投影方案以及垂直积分能量方案。比较了三种方案确定的敏感区的差异,分析了它们所阐释的物理意义,讨论了它们的优缺点,并通过理想回报试验考查了不同方案确定的敏感区的有效性。对六个台风个例的应用结果显示,单点能量投影方案与垂直积分能量方案下识别的敏感区较为相似,二者与水平投影方案确定的敏感区则有较大的区别。两种能量方案确定的敏感区更多地反映了环境场对台风的影响,而水平投影方案则反映了台风自身对流不对称性结构对台风发展变化的影响。理想回报试验结果表明,由两种能量方案确定的敏感区对预报误差能量的减小程度以及路径预报的改善程度都要大于水平投影方案确定的敏感区的效果,且垂直积分能量方案确定的敏感区的有效性最高。而在强度预报方面,三种方案对预报效果的改善程度相当。因此,总的说在台风目标观测研究中,利用CNOP方法确定敏感区时,垂直积分能量方案是较佳的方案。     

非线性土层地震反应分析的一种方法

本文利用作者给出的土的剪切动力本构关系的动态骨架曲线模型,结合显式差分数值逐步积分方法,给出了一种分析非线性土层地震反应的方法。反应计算中,地震效应视为基底剪切波垂直入射,且考虑了上部土层中能量向弹性基底辐射的效应。文章最后给出了本方法应用的一个算例,并给出了相应的等效线性化方法的计算结果。     

地洼盆地砂岩铜矿床成矿作用的化学动力学和热力学研究

对我国南方中新生代地洼盆地中的砂岩铜矿床进行了化学动力学与热力学的理论与实验研究。矿源岩中以辉铜矿和黄铜矿最有利于溶解和迁移，ＮａＣｌ对Ｃｕ的溶解和含矿流体的形成起了催化作用。溶液中Ｃｕ以络合物的形式迁移，其中以一价铜氯络合物为主；温度的降低和溶液中性化导致了络合物的失稳、分解和铜矿物的沉淀。铜矿物的化学动力学和热力学制约了砂岩铜矿中以辉铜矿为主及矿床分带的形成。     

飑线的非线性重力波行波解模型

本文提出了一个飑线的非线性重力波行波解模型,并将该模型与实际飑线作了比较,结果表明,该模型可反映出飑线的主要特征.     

Quantifying Organization of Atmospheric Turbulent Eddy Motion Using Nonlinear Time Series Analysis

Using three methods from nonlinear dynamics, we contrast the level of organization inthe vertical wind velocity (w) time series collected in the atmospheric surface layer(ASL) and the canopy sublayer (CSL) for a wide range of atmospheric stability ()conditions. The nonlinear methods applied include a modified Shannon entropy, waveletthresholding, and mutual information content. Time series measurements collected overa pine forest, a hardwood forest, a grass-covered forest clearing, and a bare soil, desertsurface were used for this purpose. The results from applying all three nonlinear timeseries measures suggest that w in the CSL is more organized than that in the ASL, and that as the flows in both layers evolve from near-neutral to near-convective conditions, the level of organization increases. Furthermore, we found that the degree of organization in w associated with changes in is more significant than the transition from CSL to ASL.