全文获取类型
收费全文 | 3214篇 |
免费 | 427篇 |
国内免费 | 1021篇 |
专业分类
测绘学 | 18篇 |
大气科学 | 62篇 |
地球物理 | 758篇 |
地质学 | 3203篇 |
海洋学 | 359篇 |
天文学 | 19篇 |
综合类 | 35篇 |
自然地理 | 208篇 |
出版年
2024年 | 27篇 |
2023年 | 62篇 |
2022年 | 99篇 |
2021年 | 155篇 |
2020年 | 170篇 |
2019年 | 205篇 |
2018年 | 172篇 |
2017年 | 191篇 |
2016年 | 177篇 |
2015年 | 164篇 |
2014年 | 193篇 |
2013年 | 233篇 |
2012年 | 204篇 |
2011年 | 174篇 |
2010年 | 133篇 |
2009年 | 217篇 |
2008年 | 318篇 |
2007年 | 255篇 |
2006年 | 215篇 |
2005年 | 186篇 |
2004年 | 189篇 |
2003年 | 120篇 |
2002年 | 116篇 |
2001年 | 101篇 |
2000年 | 110篇 |
1999年 | 80篇 |
1998年 | 80篇 |
1997年 | 69篇 |
1996年 | 42篇 |
1995年 | 29篇 |
1994年 | 62篇 |
1993年 | 30篇 |
1992年 | 18篇 |
1991年 | 7篇 |
1990年 | 13篇 |
1989年 | 6篇 |
1988年 | 10篇 |
1987年 | 4篇 |
1986年 | 7篇 |
1985年 | 5篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有4662条查询结果,搜索用时 15 毫秒
41.
The objective of this study was to examine the redox reactions and other transformations of mercury (Hg) species in surface waters, and the factors determining the rates of these reactions. For the redox studies completed at the Chesapeake Biological Laboratory (CBL), two isotopes (199HgII and 202Hg0) were added into different types of filtered water (fresh to seawater) to examine the oxidation and reduction reactions. Further studies of both the redox reactions and methylation/demethylation reactions of Hg were conducted with unfiltered water on board research vessels during cruises in May and July 2005 on the Chesapeake Bay and shelf. While CH3199HgII was added to allow the examination of demethylation, 201HgII was used to examine both reduction and methylation, and 202Hg0 was used to examine oxidation. Overall, the results showed that both Hg oxidation and reduction were simultaneously occurring and were photochemically mediated in the waters investigated. In contrast to the previously assumed “unreactive” nature of Hg0, the studies found that the magnitude of the rate constant for Hg0 oxidation was greater than that for reduction, indicating its importance in estuarine and coastal waters. In addition, both experiments at CBL and on board ship showed that HgII reduction was similar in magnitude, suggesting that biotic processes were relatively unimportant. While no measurable methylation occurred during the incubation period during the on board studies, concentration of CH3199HgII decreased over the time during the experiments. It appeared that the demethylation processes were not dominantly photochemically driven, but could be microbially mediated. Further studies are needed in order to help better understand Hg redox and transformations in natural water systems. 相似文献
42.
本文采取K_2 S_2O_8氧化法,研究了氧化条件、紫外分光光度法测定总氮的最佳条件以及可能产生的干扰及消除方法。利用本法测定天然水中总氮回收率100±2%,检出限为0.010mg·dm~(-3)。方法快速准确,与Kjedahl法相比可提高工效27倍。 相似文献
43.
ENSO对天目山柳杉树轮同位素的影响 总被引:8,自引:0,他引:8
在Nin↑~o3,4区SST序列和Jones等的SOI序列基础上,通过主分量分析方法建立了一个ENSO指数序列。并与根据天目山柳杉树轮碳,氢同位素组成比所建立的树轮指数序列进行相关分析。结果表明,天目山树轮指数与ENSO指数有很好的相关性,尤其与前2年的ENSO指数相关显著。说明ENSO对该地区树木的生长和同位素的分馏有影响,也说明天目山地区的树木年轮对于ENSO事件具有一定的记录能力。 相似文献
44.
Rapid economic developments in East Asian countries have inevitably resulted in environmental degradation in the surrounding seas, and concern for both the environment and protection from pollutants is increasing. Identification of sources of contaminants is essential to environmental pollution management. In this study, the provenance of anthropogenic lead (Pb), a major pollutant of Yellow Sea sediments, was determined for river mouth sediments, including those of the Changjiang, Huanghe, Han, and Geum Rivers, and for age-determined shelf core sediments through the measurement of Pb isotope ratios in the HCl-leached fraction using multi-collector inductively coupled plasma-mass spectrometry (MC ICP/MS). Anthropogenic Pb has accumulated in shelf core sediments since 1910, and its isotope ratios were estimated as 0.863–0.866 and 2.119–2.125 for 207Pb/206Pb and 208Pb/206Pb, respectively, from the mixing relationships of the two endmembers. River mouth sediments exhibited enough distinction in anthropogenic Pb isotope ratios to be discriminated: 0.874 (2.144) in the Huanghe, 0.856 (2.129) in the Han, 0.857 (2.122) in the Geum, and 0.854 (2.101) in the Changjiang for 207Pb/206Pb (208Pb/206Pb), respectively. Although isotope ratios of geogenic Pb in sediments dating before 1910 showed narrow ranges (0.842–0.845 and 2.088–2.100 for 207Pb/206Pb and 208Pb/206Pb, respectively), distinct isotope ratios in each core permitted source identification of sediments in the Yellow Sea based on geographic locations and the geogenic Pb of each river. By comparing the isotope ratios of the estimated anthropogenic Pb to source-related materials, the provenances of anthropogenic Pb in Chinese river sediments were presumed to be Chinese coal or ore, which is also a major source of atmospheric particulate Pb. The anthropogenic Pb in the shelf core sediments in the northern Yellow Sea originated from northern Chinese cities such as Beijing and Tianjin through atmospheric pathways. Pb isotope ratios indicated that Pb in Korean river sediments was characteristic of local Korean ores. 相似文献
45.
渐新世/中新世分界的地层学事件 总被引:5,自引:1,他引:5
介绍渐新世/中新世分界面(即古近纪/新近纪分界面)附近的浮游有孔虫和钙质超微化石事件及其新年龄。2004年国际地层年代表确定该分界面位于第58长偏心率周期弱振幅处,古地磁事件C6Cn.2n底面,经天文调谐后的年龄为23.03 Ma。发生在该界面附近的生物地层学事件主要是浮游有孔虫Paragloborotalia kugleri的始现面(22.96 Ma)和钙质超微化石Sphenolithus delphix的末现面(23.11 Ma)。在南海北部东沙群岛附近的大洋钻探ODP1148站,渐新世/中新世界面以崩塌沉积物为特征,有明显沉积间断,标志南海当时有较大范围的构造运动。 相似文献
46.
本文据珠江口周年(1987年2月至1988年2月)调查资料,分析了珠江口桂山岛附近海域的三氮变化规律,讨论了三氮之间的相互关系,通量和停留时间以及各种因素对三氮的影响。结果表明:珠江河口水中三氮的时空分布具有夏、冬季含量高,春、秋季含量低,并随向外海方向递减的特点;三氮之间的关系可分别用倒指数方程Y=exp(A+B/X)的数学模式描述;NH_4-N,NO_3-N,NO_2-N的通量和停留时间分别为33.9,401.0,15.8g·atN/s和3.84,3.96,4.41d。 相似文献
47.
48.
49.
气象要素与蒸发密切相关,通过室内外不同气象条件下的器皿水蒸发实验,获得了水面蒸发氢氧稳定同位素分馏因子与气象要素的关系。实验结果表明,随着蒸发的进行,剩余水体中逐渐富集重同位素;自由水体蒸发同位素分馏在垂线上有分层现象,表层水体同位素值比垂线平均的同位素值略富集;不同温度条件下的室内蒸发实验中,温度越高,液-气间分馏系数越小,相应于同一剩余水体体积比,剩余水体稳定同位素值则越低。室外器皿水自由蒸发实验中得出的蒸发线方程斜率较大地偏离了当地降水线,表明实验期间水体蒸发分馏作用较明显。该研究为进一步揭示水体蒸发分馏规律提供了可靠的实验依据。 相似文献
50.
通过对塔东地区古城4井上寒武统和中、上奥陶统碳酸盐岩围岩及充填物的碳、氧、锶同位素地球化学和流体包裹体成分的对比研究表明,充填于中、上奥陶统和上寒武统的流体分属于2个不同来源的流体体系。充填于中、上奥陶统灰岩裂缝中方解石脉的w(87Sr)/w(86Sr)介于0.7084~0.7088,它与早奥陶世海水的w(87Sr)/w(86Sr)相近;流体体系为CH4-H2O体系;充填物与围岩间具有明显的碳、氧同位素差异,表明上部流体体系中的流体来自于奥陶系地层本身。上寒武统白云岩裂缝中方解石脉的w(87Sr)/w(86Sr)为0.7138,明显地高于同时代海水的锶同位素值;流体体系为CO2-H2O体系;下部流体体系中的流体为外来富锶流体。上、下流体体系间互不连通暗示着上寒武统地层具有相对较好的保存条件。 相似文献