High-T phase transition of synthetic ANaB(LiMg)CMg5Si8O22(OH)2 amphibole: an X-ray synchrotron powder diffraction and FTIR spectroscopic study

The synthetic amphibole Na_0.95(Li_0.95Mg_1.05)Mg₅Si₈O₂₂(OH)₂ was studied in situ at high-T, using IR OH-stretching spectroscopy and synchrotron X-ray powder diffraction. At room-T the sample has P2₁ /m symmetry, as shown by the FTIR spectrum. It shows in the OH region two well-defined and intense absorptions at 3,748 and 3,712 cm⁻¹, respectively, and two minor bands at 3,667 and 3,687 cm⁻¹. The main bands are assigned to the two independent O–H groups in the primitive structure. The two minor bands evidencing the presence of small amount of vacant A-site (^A□_0.05). With increasing T, these bands shift continuously and merge into a unique absorption at high temperature. A change as a function of increasing T is revealed by the evolution of the refined unit-cell parameters, whose trend shows a transition to C2/m at about 320–330°C. The spontaneous scalar strain, fitted with a tricritical 2–6 Landau potential, gives a T _c of 325(10)°C (β parameter = 0.27). Comparison with the second-order P2₁ /m ⇔ C2/m phase transition at 255°C for synthetic amphibole ^ANa_0.8^B(Na_0.8Mg_1.2)^CMg₅Si₈O₂₂(OH)₂ indicates that the substitution of Na with Li at the B-sites strongly affects the thermodynamic character and the T _c of the phase transition. The comparison of LNMSH amphiboles with cummingtonitic ones shows that the high-T thermodynamic behaviour is affected by A-site occupancy.     

Territorializing land conflict: Space,place, and contentious politics in the Brazilian Amazon

Brazil possesses a long history of violent struggle for land, and its most recent phase is occurring predominantly in the Amazon Basin. Consequently, this paper attempts to territorialize land conflict in the Brazilian Amazon, and in so doing, to illuminate the place-specific intersection of historic social, political, and economic circumstance that created a violent landscape in the so-called “South of Pará.” The paper’s premise is that such conflict can be best viewed as resulting from a dialectic between general social processes operating across spatial scales, which create necessary conditions for conflict, and place-specific historical circumstances that transform necessary into sufficient conditions. The paper presents a framework integrating the theory of contentious politics and literatures addressing violence associated with the Amazonian frontier and with resource scarcity (and abundance). The discussion and theoretical application deconstruct the environmental, cognitive, and relational mechanisms that created violence in the South of Pará, and set the stage for the Eldorado dos Carajás massacre in April of 1996.     

The 17 March 2005 Kuzulu landslide (Sivas, Turkey) and landslide-susceptibility map of its near vicinity

Landslides are common natural hazards in the seismically active North Anatolian Fault Zone of Turkey. Although seismic activity, heavy rainfall, channel incisions, and anthropogenic effects are commonly the main triggers of landslides, on March 17, 2005, a catastrophic large landslide in Sivas, northeastern of Turkey, the Kuzulu landslide, was triggered by snowmelt without any other precursor. The initial failure of the Kuzulu landslide was rotational. Following the rotational failure, the earth material in the zone of accumulation exhibited an extremely rapid flow caused by steep gradient and high water content. The Agnus Creek valley, where Kuzulu village is located, was filled by the earth-flow material and a landslide dam was formed on the upper part of Agnus Creek. The distance from the toe of the rotational failure down to the toe of the earth flow measured more than 1800 m, with about 12.5 million m³ of displaced earth material. The velocity of the Kuzulu landslide was extremely fast, approximately 6 m/s. The main purposes of this study are to describe the mechanism and the factors conditioning the Kuzulu landslide, to present its environmental impacts, and to produce landslide-susceptibility maps of the Kuzulu landslide area and its near vicinity. For this purpose, a detailed landslide inventory map was prepared and geology, slope, aspect, elevation, topographic-wetness index and stream-power index were considered as conditioning factors. During the susceptibility analyses, the conditional probability approach was used and a landslide-susceptibility map was produced. The landslide-susceptibility map will help decision makers in site selection and the site-planning process. The map may also be accepted as a basis for landslide risk-management studies to be applied in the study area.     

兰州市2001年沙尘气溶胶质量浓度的特征分析

 分析了2001年沙尘暴期间兰州与靠近沙尘源区的武威的沙尘浓度和粒径分布特征,并运用对数正态分布规律拟合了沙尘粒径的分布。通过对比武威、皋兰和兰州沙尘暴期间沙尘浓度的变化以及武威与兰州的沙尘粒径分布特征,揭示了河西走廊沙漠对兰州市沙尘暴的影响。     

Stability analysis of seabed strata and casing structure during the natural gas hydrates exploitation by depressurization in horizontal wells in South China Sea

Natural gas hydrates(NGHs) are a new type of clean energy with great development potential. However, it is urgent to achieve safe and economical NGHs development and utilization. This study established a physical model of the study area using the FLAC^3D software based on the key parameters of the NGHs production test area in the South China Sea, including the depressurization method, and mechanical parameters of strata, NGHs occurrence characteristics, and the technological characteri...     

螺旋藻多糖对肿瘤细胞生长及Hela细胞早期凋亡作用的实验研究

采用MTT法(四甲基偶氮唑盐比色法)研究了钝顶螺旋藻多糖(PSP)对Hela细胞及HepG2细胞生长的抑制作用。结果表明,随PSP浓度及培养时间的增加,肿瘤细胞存活率逐渐降低,抑制率逐渐增加,以PSP40 mg/L作用72 h最为显著。应用Annexin V/PI双染色流式细胞仪检测了早期Hela细胞凋亡,未经PSP处理的正常Hela细胞凋亡细胞极少,经PSP处理的细胞,凋亡细胞的百分比明显高于正常对照组,其作用随着剂量的增加和时间的延长而增强,具有量效关系和时效关系。结果说明PSP的抗肿瘤机制,除了诱导肿瘤细胞凋亡,还存在细胞毒性等其他机制,是多种机制共同作用的结果。     

莱州湾南岸第三陆相层年龄的铀系等时线法(TSD)测定

于莱州湾南岸ZK32-1钻孔第三陆相层上下边界处选取自生钙质结核,采用样品全溶铀系等时线法(TSD法)测定钙质结核的年龄。测试结果表明,所有等时线上的数据都有很好的线性关系,表明所获得的年龄数据是合理的。通过对样品代表性的讨论,说明所选取的钙质结核的年龄确可代表其所在地层的年龄,从而得出莱州湾南岸第三陆相层的沉积起止时间为72.16ka B.P.±7.41ka B.P.到45.34ka B.P.±5.35ka B.P.的结论。本研究首次获得莱州湾南岸地层的铀系TSD年龄,为全面认识该地区晚更新世地层年代学提供了一个新视角。     

Low-temperature alteration of oceanic island basalts and their contribution to transition metal circulation of the ocean

The major elements, rare earth elements （REE） and trace elements of four basalt samples from central and western Pacific ferro- manganese crust provinces have been analyzed using chemical methods and ICP - MS, respectively. The results indicate that the samples have been extensively altered and that the contents of their major elements have changed significantly. However, the similarity of REE partition patterns and trace element contents of basalt samples to those of fresh oceanic island basalts （OIB） indicate that the basalt samples originated as OIB. Because of low-temperature alteration, the contents of A1203 , Fe203 , MnO, K20 and P205 increased, while MgO and FeO decreased. Active components, such as magnesium and iron, were leached from OIB resulting in the relative enrichment of SiO2. The leaching of active components can cause the relative enrichment of REE, while the precipitation of LREE-rich ferromanganese oxides in vesicles and fissures not only causes an increase of REE contents, but also induces ＂fractionation＂ of LREE and HREE. Based on the enrichment mechanism of REE contents, the theoretical quantities of precipitated ferromanganese oxides and the depleted quantities of active components are calculated ： the depleted quantities of active components for the unit mass of fresh basalts vary in the range of 0.15 ～ 0. 657, and the precipitated quantities of ferromanganese oxides for the unit mass of fresh basahs vary in the range of 0. 006 ～ 0. 042. Of the major elements, the two most depleted are iron, and magnesium, with 18.28% ～ 70.95% of iron and 44.50% ～ 93.94% of magnesium in the fresh basalts was leached out. Theoretical calculation and geochemistry results both indicate that low-temperature alteration of basalts can supply abundant amount of metals to seawater, and may play an important role in ocean metal circulation.     

农机投入对农业GTFP影响及门槛效应的区域差异分析

按照粮食的产销情况,将全国划分为3类粮食功能区域,利用固定效应模型和门槛效应模型分析了农机投入对农业绿色全要素生产率(GTFP)的影响及门槛效应的区域差异。结果表明:农机投入对农业GTFP的影响程度存在区域异质性,农机投入对粮食主销区农业GTFP提升的促进作用最大,粮食产销平衡区次之,粮食主产区最小;农机投入对农业GTFP的影响路径亦存在区域差异,粮食主产区和产销平衡区的农机投入通过促进农业技术效率和农业技术进步进而推动农业GTFP提升,粮食主销区的农机投入通过促进农业技术进步推动农业GTFP提升;农机投入对粮食主产区农业GTFP的影响存在双门槛效应,对粮食主销区和产销平衡区农业GTFP的影响存在单门槛效应。     

青海南部熔积岩的发现:对寻找VMS型矿床的重要启示

熔积岩指的是侵入、混合到未固结或弱固结的湿沉积物中的熔浆分解、原位形成的一类特殊岩石。正确地认识该类岩石,有利于增进人们对岩浆-水(沉积物)相互作用过程的理解,恢复古环境。在青海南部沱沱河地区发现了一套角砾为撕片状、锯齿状及浑圆状的安山岩,胶结物为铁硅质组合的特殊熔积岩。研究表明,该熔积岩的角砾为岩浆遇水后快速淬火、裂解的产物,铁硅质组合为海底喷气沉积形成的含铁建造;且安山岩与含铁建造发生混合时,含铁建造尚未固结。该套熔积岩的发现,改变了长期以来对开心岭铁矿为火山热液交代安山岩而形成的认识,对于在矿区寻找VMS型矿床、区域内寻找海底热水喷流沉积型矿床具有重要的启示意义。