Reversed mining and reversed-reversed mining: the irrational context of geological disposal of nuclear waste

Man does not only extract material from the Earth but increasingly uses the underground for storage and disposal purposes. One of the materials that might be disposed of this way is high-level nuclear waste. The development of safe disposal procedures, the choice of suitable host rocks, and the design of underground facilities have taken much time and money, but commissions in several countries have presented reports showing that — and how — safe geological disposal will be possible in such a way that definite isolation from the biosphere is achieved. Political views have changed in the past few years, however, and there is a strong tendency now to require that the high-level waste disposed of will be retrievable. Considering the underlying arguments for isolation from the biosphere, and also considering waste policy in general, this provides an irrational context. The development of new procedures and the design of new disposal facilities that allow retrieval will take much time again. A consequence may be that the high-active, heat-generating nuclear waste will be stored temporarily for a much longer time than objectively desirable. The delay in disposal and the counterproductive requirement of retrievability are partly due to the fact that earth-science organisations have failed to communicate in the way they should, possibly fearing public (and financial) reactions if taking a position that is (was?) considered as politically incorrect. Such an attitude should not be maintained in modern society, which has the right to be informed reliably by the scientific community.     

Organic complexation and its control of the dissolved concentrations of copper and zinc in the Scheldt estuary

Cathodic stripping voltammetry (CSV) is used to determine total (after UV-irradiation) and labile dissolved metal concentrations as well as complexing ligand concentrations in samples from the river Scheldt estuary. It was found that even at high added concentrations of catechol (1 m for copper and 0·4 m for iron) and of APDC (1 m for zinc) only part of the dissolved metal was labile (5–58% for copper, 34–69% for zinc, 10–38% for iron); this discrepancy could be explained by the low solubility of iron which is largely present as colloidal material, and by competition for dissolved copper and zinc by organic complexing ligands. Ligand concentrations varied between 28 and 206 n for copper and between 22 and 220 n for zinc; part of the copper complexing ligands could be sub-divided into strong complexing sites with concentrations between 23 and 121 n and weaker sites with concentrations between 44 and 131 n . Values for conditional stability constants varied between (logK′ values) 13·0 and 14·8 for strong and between 11·5 and 12·1 for weaker copper complexing ligands, whereas for zinc the values were between 8·6 and 10·6. The average products of ligand concentrations and conditional stability constants (a-coefficients) were 6 × 10² for zinc and 6 × 10⁶ for copper.The dissolved zinc concentration was found to co-vary with the zinc complexing ligand concentration throughout the estuary. It is argued that the zinc concentration is regulated, in this estuary at least, by interactions with dissolved organic complexing ligands. A similar relationship was apparent between the dissolved copper and the strong copper complexing ligand concentration. The total copper complexing ligand concentrations were much greater than the dissolved copper concentrations, suggesting that only strongly complexed copper is kept in solution.These results provide evidence for the first time that interactions of copper and zinc with dissolved organic complexing ligands determine the geochemical pathway of these metals.     

数据库在荷兰海洋区测中的作用与地位

荷兰海洋区测中十分重视数据库建设和信息化方法的应用，荷兰海洋区测数据库包括3类不同的层次，如项目级数据库Archive management system、部门级数据库IMKMG和企业级数据库DINO。数据库技术的使用保证了区调成果的重复利用（Re-use）和可持续使用（Sustainability），是荷兰区调顺利完成以及成果得以广泛应用的重要技术基础。     

Place-based social exclusion: redlining in the Netherlands

'Redlining' is a form of place-based exclusion. It is widely documented in the US, but not in Europe. This paper focuses on a comparative analysis of redlining practices in the two largest cities of the Netherlands: Amsterdam and Rotterdam. It shows that redlining was common practice in Rotterdam in 1999. In 2001, no signs of redlining were found in Rotterdam. However, 'yellowlining' (lower loan-to-value ratios) was still common in some parts of Rotterdam. In Amsterdam, no neighbourhoods were faced with redlining in either 1999 or 2001. However, in 1999 some neighbourhoods were yellowlined. This paper aims to get a better understanding of the nature and the institutional context of redlining in the Netherlands by explaining how the differences in redlining practices between Amsterdam and Rotterdam, and between 1999 and 2001, can be explained. The National Mortgage Guarantee as well as socio-historical, and housing and mortgage market differences and changes, are instrumental in explaining these differences in redlining practices.     

荷兰地籍测量的发展

荷兰地籍测量有着很长的历史,形成了自己独特的风格。在科技飞速发展的今天,它也正经历着从传统手工作业向现代化测量的变更。荷兰地籍测量在土地信息系统建设、大比例尺基本地形图以及地籍图的测量、更新方面已取得了很大成就。相信对我们有借鉴作用。     

Dunefoot dynamics along the Dutch coast

The dynamics of the dunefoot along a 160 km portion of the Dutch coast has been investigated based on a data set of annual surveys dating back to as early as 1850. The linearly detrended (or residual) dunefoot positions comprise an alongshore uniform and an alongshore non‐uniform component. The former is expressed as 10 to 15 m of landward retreat along extensive (>10 km) stretches of coast during years with severe storm surges and as up to 5 m of seaward advance during years without significant storm activity. The latter, alongshore non‐uniform component is organized in sandwave‐like patterns, which may have a longevity of decades to up to the duration of the entire data set (150 years). Their wavelengths vary along the coast, from 3·5 to 10 km; migration rates are 0–200 m a^?1. Dunefoot sandwaves are shown to be the shoreward extensions of similar sandwave patterns in the beach position. The non‐uniform dunefoot behaviour constitutes at least 80 per cent of the total residual dunefoot dynamics, implying that along the Dutch coast residual dunefoot variability is controlled by temporal and spatial variability in beach characteristics, and not by storm‐induced uniform erosion. Various potential mechanisms causing beach sandwaves are discussed. Copyright © 2002 John Wiley & Sons, Ltd.     

Manganese and Iron Oxidation During Benthic Oxygenic Photosynthesis

The effect of benthic oxygenic photosynthesis on sediment-water fluxes of manganese and iron was studied for an intertidal sediment. Undisturbed sediments were incubated at an incident surface irradiance of 250 μE m⁻² s⁻¹at 26 °C. Oxygenic photosynthesis was selectively inhibited by adding [3-(3,4-dichloro)-1,1-dimethyl-urea] (DCMU). Benthic fluxes were determined experimentally from the change in manganese and iron concentrations in the overlying water, and were predicted from the pore water concentration gradients at the sediment-water interface assuming molecular diffusion as the transport mechanism. The experimental fluxes of manganese and iron in DCMU-treated cores amounted to −0·84 and −0·59 mmol m⁻²day⁻¹, respectively, and were directed from the sediment towards the overlying water. In the control cores, showing high rates of benthic oxygenic photosynthesis, the fluxes of manganese and iron were directed towards the sediment, 0·06 and 0·01 mmol m⁻²day⁻¹, respectively. Mass balances for the 0·1–0·14 cm thick oxic zone, calculated from the experimental fluxes and the predicted fluxes, suggest a minimum areal reoxidation of 0·6 mmol m⁻²day⁻¹for manganese and of 0·48 mmol m⁻²day⁻¹for iron in cores showing benthic photosynthesis. The estimated turnover times for dissolved Mn²⁺and dissolved Fe²⁺in the oxic surface layer during benthic photosynthesis were 0·8 and 0·25 h, respectively. Sediment oxygen microprofiles and the sediment pH profiles suggest that chemical precipitation and reoxidation dominates the retention of manganese and iron during benthic oxygenic photosynthesis in shallow intertidal sediments.     

Rates of salinization by free convection in high-permeability sediments: insights from numerical modeling and application to the Dutch coastal area

Numerical modeling and dimensional analysis is used to study the salinization of thick, high-permeability aquifers by free convection from a salt source at the surface. Current understanding of this process mainly concerns the initial stages of salinization only (boundary-layer development, break-up into fingers and initial phase of finger descent). In the modeling, special attention is paid to the role of two processes in the long-term salinization rate: (1) the progressive loss of salt from fingers by lateral diffusion, and (2) the coalescence of fingers during their descent. From the numerical simulations a relationship is derived that describes the development of the horizontally averaged salinity with depth and time as a function of permeability and initial-density contrast for aquifer Rayleigh numbers up to Ra =6,000. This relationship is consistent with and provides an extension to previous generalized relationships of the rate of finger descent. Its applicability to real-world aquifers (Ra >10⁵) that include complexities due to anisotropy, heterogeneity, and mechanical dispersion is discussed. Application to the Pleistocene coastal aquifer of the Netherlands (thickness 200 m, permeability 10^-11 m²) suggests that salinization of the aquifer during historic episodes of inundation by seawater occurred within decades.

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Resumen Se utiliza modelos numéricos y un análisis dimensional para estudiar la salinización de acuíferos potentes de alta permeabilidad por convección libre a partir de una fuente salina superficial. El conocimiento acutal de este proceso se limita a las fases iniciales de la salinización (desarrollo de la capa de contorno, creación de digitaciones y fase inicial de la progresión de éstas). En la modelación, se presta atención especial al papel desempeñado por dos procesos de salinización a largo plazo: (1) la pérdida progresiva de sal por difusión lateral desde las digitaciones, y (2) la coalescencia de las digitaciones durante su avance. A partir de las simulaciones numéricas, se obtiene una relación que describe el desarrollo de la salinidad con la profundidad y el tiempo, promediada horizontalmente, el cual depende de la permeabilidad y del contraste inicial de densidad para números de Rayleigh inferiores a 6.000. Esta relación es coherente con índices previos generalizados del avance de las digitaciones, y representa una extensión a estos. Se discute su aplicabilidad a acuíferos reales (con números de Rayleigh superiores a 105), que tienen complejidades asociadas a la anisotropía, la heterogeneidad y la dispersión mecánica. La aplicación al acuífero costero Pleistoceno de los Países Bajos (20 m de potencia y 10-11 m2 de permeabilidad) sugiere que la salinización tuvo lugar en décadas, debido a episodios históricos de inundación por aguas marinas.

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Résumé Une modélisation numérique et une analyse dimensionnelle ont été mises en oeuvre pour étudier la salinisation d'aquifères épais et à forte perméabilité par convection libre d'une source de sel en surface. La compréhension habituelle de ce processus concerne principalement les étapes initiales de la salinisation seule (développement d'une couche limite, partition en digitations et phase initiale de développement des digitation). Dans la modélisation, une attention particulière a été portée au rôle de deux processus du taux de salinisation à long terme: (1) la perte progressive de sel dans les digitations par diffusion latérale et (2) la coalescence des digitations au cours de leur développement. À partir de simulations numériques, une relation a été obtenue qui permet de décrire l'extension de la salinité horizontalement en profondeur et au cours du temps en fonction de la perméabilité et du contraste initial de densité pour des nombres de Rayleigh de l'aquifère jusqu'à Ra =6,000. Cette relation est compatible avec ces résultats et fournit une extension des relations précédemment généralisées du taux de développement des digitations. On discute son applicabilité à des aquifères réels (Ra >105) incluant des complexités liées à l'anisotropie, l'hétérogénéité et la dispersion mécanique. L'application à l'aquifère côtier du Pléistocène des Pays-Bas (épaisseur environ 200 m, perméabilité environ10–11 m²) laisse penser que la salinisation de cet aquifère au cours d'épisodes historiques d'inondation par la mer s'est produit durant des décennies.

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