核磁共振T2谱M-P广义逆反演研究

基于广义逆和奇异值分解理论,研究核磁共振T2谱反演的截断法和阻尼法。首先给出反演问题的M-P广义逆解;然后对系数矩阵进行奇异值分解求其M-P广义逆,对奇异值进行截断或者加阻尼,保证解的稳定性兼顾其分辨率;最后利用迭代技术实现解的非负约束。数值仿真实验和岩心T2谱反演表明:对于双峰谱,在信噪比SNR≥10时,截断法和阻尼法反演T2谱的分辨率和稳定性都很高;截断法截断因子选择范围小,在SNR<10时解的分辨率和稳定性差;阻尼法阻尼因子选择范围大,在SNR<10时解的稳定性好,但短组分分辨率低,长组分分辨率高。对于三峰谱,当SNR≥20时,截断法和阻尼法反演的T2谱光滑连续,具有三峰结构;当SNR<20时两者均不能反演出与构造谱接近的三峰谱。因此,2种方法可应用于SNR≥10的双峰谱和SNR≥20的三峰谱反演;从分辨率和稳定性、平滑噪声及截断和阻尼因子的选取上,阻尼法略优于截断法。     

核磁共振地下水探测技术在水源勘察及确定地下咸淡水界面中的应用与研究

地面核磁共振找水技术是目前世界上唯一的直接找水方法.笔者通过该技术在内蒙古五原县乡镇安全饮水工程水源勘察中的应用,对如何确定地下咸淡水界面开展了研究工作.通过所获得的解译成果与钻孔资料的对比,认为在依据区域水文地质资料的基础上,用该技术确定地下咸淡水界面位置较为准确;在无区域水文地质资料的情况下,单以核磁共振解译成果能...     

不同取代位置羧甲基壳聚糖的核磁共振波谱和电位滴定分析

本文制备了O-羧甲基壳聚糖、N-羧甲基壳聚糖和N,O-羧甲基壳聚糖,并采用核磁共振波谱以及电位滴定方法对不同取代位置羧甲基壳聚糖取代度进行了分析。结果表明,核磁共振碳谱及DEPT谱可以确定羧甲基壳聚糖中羧甲基的取代位置,电位滴定法可以确定O-位羧甲基、N-位羧甲基以及总羧甲基的取代度,是一种简单易行的方法。     

Quantification of uplift in the Carnarvon Basin based on interval velocities

Sonic velocities in the Toolonga Calcilutite (Upper Cretaceous), the Gearle Siltstone and Haycock Marl (mid‐Cretaceous), and the Muderong Shale (Lower Cretaceous) were each used to independently quantify apparent uplift (height above maximum burial depth) in the Carnarvon Basin. Apparent uplift is given by the difference in depth between the present‐day velocity‐depth trend for a unit in a particular well and the reference trend (unaffected by uplift) of the unit. Apparent uplift results derived from the Toolonga Calcilutite, Gearle Siltstone and Muderong Shale are statistically similar. The consistency of results from carbonate and clastic units suggests that, at the formation and regional scale, overcompaction (i.e. anomalously high interval velocity) in these three units reflects previously greater burial depth, rather than sedimentological and/or diagenetic processes, and validates the use of lithologies other than shale in maximum burial‐depth studies. The proposed magnitudes of apparent uplift are greatest along some of the main structural highs of the Carnarvon Basin. Apparent uplift of approximately 800 m was determined along the Legendre Trend, and along the Barrow Arch. In excess of 900 m of apparent uplift was determined on the Bambra Anticline. The consistency of results from units of Early to Late Cretaceous age suggests that uplift must have post‐dated the youngest (Late Cretaceous) unit analysed.     

Spectroscopic Characterization of Compost at Different Maturity Stages

We studied the physicochemical and molecular changes of compost during its maturation within 60, 90, and 150 days after the composting process. Moreover, the changes were also studied in compost residues after sequential removal of lipidic compounds. Infrared DRIFT spectrometry and ¹³C‐CPMAS‐NMR spectroscopy indicate that the molecular composition of compost changes dramatically during the stabilization period. The most decomposable components, mainly represented by bioavailable lipidic and peptidic structures, were progressively mineralized passing from 60 days to longer periods of compost stabilization. At increasing maturity stages, the composition of organic matter underwent a progressive enrichment in stable hydrophobic and ligno‐cellulosic material. The sequential extraction of lipidic compounds allowed an improved characterization of substrates and confirmed the outlined progressive transformation of compost. Compost may well be chosen on the basis of selected characteristics for environmental applications.     

低电阻率油气层的测井系列研究

根据低电阻率油气层的成因,将低电阻率油气层分为四种主要不同的类型,这四种类型的低电阻率油气层除了需要进行常规测井系列外,不同成因的低电阻率油气层应采用不同的新技术测井项目,对于高不动水含量型低阻油气层,将核磁共振测井作为解决这种类型的针对对性测井项目,而MDT测井作为选择性项目;对于粘土附加导电型低阻油气层,将极化率测井作为解决该类低阻问题的针对性测井项目,核磁共振、双频介电、MDT测井作为选择性测井项目;对于砂泥岩间互型低阻油气层,高分辨率感应测井或者阵列侧向测井是解决此类低阻油气层的关键技术;对于盐水泥浆侵入型低阻油气层,可以有针对性的进行过套管电阻率测井,同时在储层物性条件较好时还可以选测C／O或PND测井替代过套管电阻率测井项目,或者根据地面及地下地质情况,选取随钻测井系列.     

库水位下降条件下斜坡稳定性研究

采用核磁共振（NMR）技术反演水文地质参数,在此基础上,基于非饱和土强度理论,对现有滑坡剩余推力法进行改进。以三峡工程库区赵树岭滑坡为例,对库水位以不同速度下降时不同时刻的滑坡稳定性进行了研究,结果表明：在库水位下降过程中会出现稳定性系数达到极小值的现象。下降速度越大,稳定性极小值越小,出现极小值的时刻也相对早。     

多尺度孔隙岩石的核磁共振扩散耦合现象及其探测方法

油藏岩石的孔隙连通性是反映流体渗流难易程度的重要参数,对渗透率、有效孔隙度等岩石物理参数的评价具有重要作用.连通的孔隙中,核磁共振(NMR)弛豫的交换会产生扩散耦合现象,可作为孔隙连通性的表征和探测方法.本文提出利用横向弛豫T2-T 2脉冲序列测量岩石的扩散耦合现象.运用随机游走方法模拟多孔岩石的核磁共振响应特征,分析...     

测井数据滑动窗关联维计算和沉积学分析

应用滑动窗关联维计算方法对鲁北济阳坳陷某钻井剖面石炭系—二叠系陆表海沉积层段GR测井响应数据进行了分形维数计算,结果表明海侵体系域关联维数一般较小,且维数曲线振荡变化较弱,而高水位体系域则相反。这与海侵体系域形成时海平面上升的主控因素压制或掩盖了其他因素的显现有关,同时也证明测井序列分形分析能从另一个新的视角观察识别测井序列中所包含的地质信息。随着分形方法应用研究的不断开展,必将从测井数据中挖掘出更多的有用信息,指导油气等资源勘探与开发,丰富及完善测井地质学理论。相信将来分形会成为地质数据分析的标准工具。     

提高测井曲线纵向分辨率的方法

常规处理方法往往漏掉一些有价值的薄油气储层。利用频率域反槽积方法、贝叶斯反褶积方法、反褶积与光滑滤波组合（ＤＦＳＮ）方法和分辨率匹配与非线性拟合方法对测井曲线进行了提高纵向分辨率处理，测井曲线的纵向分辨率可提高１～４倍，一些结果得到了证实，为准确地定量评价薄储居提供了较可靠的参数