固化盐渍土核磁共振微观特征

采用核磁共振技术,对不同配比的水玻璃、石灰+粉煤灰及石灰+粉煤灰+水玻璃的固化盐渍土的微观特征进行检测,结合无侧限抗压强度试验,分析了各固化方案的盐渍土固化效果,讨论了强度成因的微观特征机制。结果表明,不同固化土的孔隙特征有较大差异。石灰+粉煤灰固化盐渍土大孔隙减少;石灰+粉煤灰+水玻璃固化盐渍土孔隙总体积减少,但同时有大孔隙生成;水玻璃固化盐渍土孔隙总体增多,但随水玻璃浓度增大,孔隙体积有所减小。石灰+粉煤灰+水玻璃固化盐渍土抗压强度远大于其他固化方案,但是其孔隙结构并不是最优,说明颗粒间的胶结情况对固化效果的影响远大于孔隙特征。     

利用成像测井自动判别礁滩储层沉积相和岩性

礁滩储层是我国海相碳酸盐岩油气勘探的重要目标,也是我国油气产能的重要接替领域之一。由于礁滩储层储集空间类型多样,非均质性极强,依靠常规测井判别其沉积相和岩性非常困难。成像测井能够清晰地反映礁滩储层的结构组分和沉积构造,为沉积相和岩性的判别提供了可靠的依据。在对大量礁滩储层的成像和岩心对比观察的基础上,我们提出了9种典型的成像解释模式,建立了利用成像解释模式自动判别礁滩储层沉积相和岩性的方法并研制了相应的处理软件。该方法在塔中和川东北地区礁滩储层的实际应用中取得了良好的效果。     

Combining rate-controlled porosimetry and NMR to probe full-range pore throat structures and their evolution features in tight sands: A case study in the Songliao Basin,China

To better understand reservoir quality and to produce accurate petrophysical interpretations, it is necessary to understand complex and heterogeneous pore throat structures in tight sands and to develop a technique to reveal the full range of pore and throat distributions. In this study, in order to characterize the features and evolutions of pore throat structures, nine samples from the Lower Cretaceous tight gas sandstone in the Songliao Basin of China are measured by nuclear magnetic resonance (NMR), rate-controlled porosimetry (RCP) and scanning electron microscopy (SEM). Throats with bifractal structures are found in these tight sands and can be divided into a backbone formation (BF) region and a percolation region using RCP data. Because (i) throats in the percolation region record treelike pore structures and are predominant in small pore spaces and (ii) a good correlation exists between NMR-derived T₂ relaxation times and the RCP-derived radius of throats, the throat distribution obtained via RCP can be used to calibrate the NMR PSD and then to partition the PSD into distributions of pore bodies and throats. These data indicate that (i) throats are more common than pore bodies in pore spaces of tight sands with lower permeability, (ii) pore bodies are connected to throats from both the BF and percolation regions, in which the fluid mobility in pore bodies is mainly controlled by the pore to throat ratio (PTR), which is related to the intersection throat of these two regions, and (iii) compaction, dissolution, clay cementation and sediment properties (e.g., rock compositions) have different impacts on the evolutions of pore bodies and throats, in which larger PTR values in tight sands are mainly produced by compaction and pore-bridging clay cementation, and lower contents of pore bodies are commonly related to abundant plastic compositions and pore-bridging clay cementation.     

Identification of water-bearing fractures in hard rock terrain by electrical conductivity logs, India

For the delineation of water-bearing fractures in hard rock areas, a new hydro-chemical technique has been developed which is based on electrical conductivity (EC) logs. The EC logs were carried out in experimental shallow bore wells (≈50 m) in three different parts of India. A sharp variation in EC was observed near water-bearing fractures in hard rock areas. To access applications of this technique, different locations in India were selected and experimental bore wells (≈50 m) were drilled. These were:

Calculation of <Superscript>17</Superscript>O NMR shieldings in molecular models for crystalline MO,M=Mg,Ca, Sr,and in models for alkaline earth silicates

¹⁷O NMR shieldings are calculated for the central O in the molecular model OM₆(OH)₁₂ ^–2, for crystalline alkaline earth oxides, MO, where M=Mg, Ca, and Sr, using both Hartree–Fock and hybrid Hartree–Fock density-functional theory. Agreement of calculated and experimental NMR shifts of CaO and SrO compared to MgO is good, but only if the basis set on the M atoms has sufficient tight d polarization functions. Preliminary results are also presented for nonbridging O in the silicate Si(OH)₃O^– anion, perturbed by alkaline earth cations, giving trends which agree qualitatively with experiment.     

干酪根结构中碳分布特征及其与生烃潜力的关系──~（13）C NMR CP／MAS 与DD技术的应用

用常规的固体~（１３）ＣＮＭＲ谱与偶极相移谱（ＤＤ）分析研究了大庆地区不同类型低成熟干酪根的结构特征。Ｉ型干酪根ＤＤ谱的主要特征为脂碳中有明显的柔性可动的链亚甲基与次甲基峰，而Ⅲ型干酪很则以甲基信号为主。将不同结构的脂碳与干酪根的生烃潜力（由岩石评价仪测定的Ｓ值）相关联，发现亚甲基与次甲基的相关系数最高，甲基次之，ａ位亚甲基与季碳又次之，氧接脂碳对生烃的贡献不大。     

Color display of well logs

Information displayed in image form is conventionally at least two-dimensional. One-dimensional data can also be displayed as imagery by amplitude slicing a function and representing these amplitude slices as grey levels or as intensities of a particular color. An image having length and width can be formed from one-dimensional data by arranging a sequence of such color levels along the length of the image, corresponding to the independent space or time variable, and by extending these color levels arbitrarily along the width of the image. Such an image is of arbitrary width and exhibits changes, or information, only along its length. If three such images are made, one in each of the three primary colors, each image representing a different one-dimensional function over the same range of a common independent space or time variable, standard primary color composition can be used to unite these three images into a single full-color image in either computer graphic or photographic media. When three different well logs from a single borehole are combined in this manner, the resulting full-color image is equivalent to a three-axis cross-plot of the logs involved. Because primary colors appear to the human eye to be orthogonal and miscible, the color image preserves all information present in the three original data sets.Further, because this color representation of data can be arranged conveniently in depth sequence, the color composite image presents both information best visualized in cross-plot presentation (e.g., lithologic clustering and differentiation) and information lacking in cross-plots that is best seen in conventional wiggle-trace displays of well logs (e.g., stratigraphic or depth sequence). Such color presentations of well log data reduce the number of displays competing for an interpreter's attention by uniting three wiggle traces into one display and relieve the burden of mentally combining data from several separate displays. Combined interpretation is particularly essential in well log interpretation where one must analyze individually ambiguous data sets; color log presentation automatically provides combination while leaving interpretation to the scientist. Color log images also present log data to the user in a form that differs from conventional wiggle trace and so appeals to a different and richer set of human perceptions and pattern recognition skills.     

The Chemical Species Distribution of Aluminum in Composite Flocculants Prepared from Polyaluminum Chloride (PAC) and Polydimethyldiallylammonium Chloride (PDMDAAC)

In order to improve the coagulation/flocculation efficiency of polyaluminum chloride (PAC), a composite flocculant of PAC and polydimethyldiallylammonium chloride (PDMDAAC), or PAC‐PDMDAAC, was prepared. The chemical species distribution of aluminum in PAC and PAC‐PDMDAAC, which has a close relationship with their coagulation/flocculation performance, was investigated by Al‐Ferron complexation timed spectrophotometry and ²⁷Al‐NMR. The factors affecting the chemical species of aluminum in PAC‐PDMDAAC, such as the weight concentration of PDMDAAC (Wp), basicity (B) of PAC, and viscosity (η) of PDMDAAC, were studied. The flocculation efficiencies of PAC‐PDMDAAC, PAC and PDMDAAC were studied on a six‐spindle multiple stirrer unit. The results showed that the aluminum species distribution in PAC‐PDMDAAC depends on the Wp, B and η value. When the B value is 1.5 and η value is 1.22 dL/g, the composite flocculant with Wp = 15 % gives highest Al_b and Al₁₃ contents, and its flocculation efficiency is highest in the test flocculations.     

核磁共振地下水勘查的模拟退火反演

简要地介绍了NMR找水的理论方法,分析了核磁共振找水对于不同含水层的正演计算方法,并用模拟退火反演方法对一维含水模型进行反演,给出了三个不同含水层模型的模拟退火反演效果图。经对比验证,该方法在技术上是可行的,在理论上给出了对NMR反演进行改进的可行性方法。     

Phosphorus features in FT-IR spectra of natural organic matter

Fourier-Transform Infrared （FT-IR） spectroscopy has been used extensively to characterize natural organic matter （NOM）. Absorption bands at 1100-1000 cm^-1 in the FT-IR spectra of NOM have been frequently assigned to alcoholic and polysaccharide C-O stretching or to vibrations of SiO2-related impurities. However, these interpretations do not consider that a strong band associated with P-O bonds of phosphate also appears in the same region. We evaluated the correlation between absorbance in this region and P content of 19 NOM samples from terrestrial, aquatic and plant shoot sources. In the spectra of 10 humic and fulvic acid samples, shoulder to minor bands appeared around 1050 cm^-1. Absorbance intensity at 1050 cm^-1 （Y） was linearly related to P content （X） by the following： Y=4.38X＋0.3 l, with R2=0.90. We did not observe such a close correlation between absorbance and P content in two aquatic NOM samples. Apparently, this is because the aquatic NOM samples were concentrated by reverse osmosis, which would have concentrated not only humic and fulvic acids but also other soluble organic solutes present in natural waters. In the FT-IR spectra of seven dissolved organic matter （DOM） samples obtained from dried plant shoots, broad and/or multiple bands around 1075 cm^-1 were observed with a shoulder at 977 cm^-1. These characteristics were more like those of organic phosphate compounds （such as inositol hexaphosphate）. However, solution 31P nuclear magnetic resonance spectroscopic analysis showed no significant amount of organic phosphate present in these samples.