Rates of transformation, recycling and burial of nitrogen and their temporal and spatial variability were investigated in deep-sea sediments of the Porcupine Abyssal Plain (PAP), NE Atlantic during eight cruises from 1996 to 2000. Benthic fluxes of ammonium (NH4) and nitrate (NO3) were measured in situ using a benthic lander. Fluxes of dissolved organic nitrogen (DON) and denitrification rates were calculated from pore water profiles of DON and NO3, respectively. Burial of nitrogen was calculated from down core profiles of nitrogen in the solid phase together with 14C-based sediment accumulation rates and dry bulk density. Average NH4 and NO3-effluxes were 7.4 ± 19 μmol m−2 d−1 (n = 7) and 52 ± 30 μmol m−2 d−1 (n = 14), respectively, during the period 1996–2000. During the same period, the DON-flux was 11 ± 5.6 μmol m−2 d−1 (n = 5) and the denitrification rate was 5.1 ± 3.0 μmol m−2 d−1 (n = 22). Temporal and spatial variations were only found in the benthic NO3 fluxes. The average burial rate was 4.6 ± 0.9 μmol m−2 d−1. On average over the sampling period, the recycling efficiency of the PON input to the sediment was 94% and the burial efficiency hence 6%. The DON flux constituted 14% of the nitrogen recycled, and it was of similar magnitude as the sum of burial and denitrification. By assuming the PAP is representative of all deep-sea areas, rates of denitrification, burial and DON efflux were extrapolated to the total area of the deep-sea floor (>2000 m) and integrated values of denitrification and burial of 8 ± 5 and 7 ± 1 Tg N year−1, respectively, were obtained. This value of total deep-sea sediment denitrification corresponds to 3–12% of the global ocean benthic denitrification. Burial in deep-sea sediments makes up at least 25% of the global ocean nitrogen burial. The integrated DON flux from the deep-sea floor is comparable in magnitude to a reported global riverine input of DON suggesting that deep-sea sediments constitute an important source of DON to the world ocean. 相似文献
The Eastern Anatolia Region exhibits one of the world's best exposed and most complete transects across a volcanic province related to a continental collision zone. Within this region, the Erzurum–Kars Plateau is of special importance since it contains the full record of collision-related volcanism from Middle Miocene to Pliocene. This paper presents a detailed study of the volcanic stratigraphy of the plateau, together with new K–Ar ages and several hundred new major- and trace-element analyses in order to evaluate the magmatic evolution of the plateau and its links to collision-related tectonic processes. The data show that the volcanic units of the Erzurum–Kars Plateau cover a broad compositional range from basalts to rhyolites. Correlations between six logged, volcano-stratigraphic sections suggest that the volcanic activity may be divided into three consecutive Stages, and that activity begins slightly earlier in the west of the plateau than in the east. The Early Stage (mostly from 11 to 6 Ma) is characterised by bimodal volcanism, made up of mafic-intermediate lavas and acid pyroclastic rocks. Their petrography and high-Y fractionation trend suggest that they result from crystallization of anhydrous assemblages at relatively shallow crustal levels. Their stratigraphy and geochemistry suggest that the basic rocks erupted from small transient chambers while the acid rocks erupted from large, zoned magma chambers. The Middle Stage (mostly from 6–5 Ma) is characterised by unimodal volcanism made up predominantly of andesitic–dacitic lavas. Their petrography and low-Y fractionation trend indicate that they resulted from crystallization of hydrous (amphibole-bearing) assemblages in deeper magma chambers. The Late Stage (mostly 5–2.7 Ma) is again characterised by bimodal volcanism, made up mainly of plateau basalts and basaltic andesite lavas and felsic domes. Their petrography and high-Y fractionation trend indicate that they resulted from crystallization of anhydrous assemblages at relatively shallow crustal levels. AFC modelling shows that crustal assimilation was most important in the deeper magma chambers of the Middle Stage. The geochemical data indicate that the parental magma changed little throughout the evolution of the plateau. This parental magma exhibits a distinctive subduction signature represented by selective enrichment in LILE and LREE thought to have been inherited from a lithosphere modified by pre-collision subduction events. The relationships between magmatism and tectonics support models in which delamination of thickened subcontinental lithosphere cause uplift accompanied by melting of this enriched lithosphere. Magma ascent, and possibly magma generation, is then strongly controlled by strike-slip faulting and associated pull-apart extensional tectonics. 相似文献
Northeastern (NE) China is the easternmost part of the Central Asian Orogenic Belt (CAOB), which is celebrated for its accretionary tectonics and the world's most important juvenile crust production in the Phanerozoic era. Abundant granitoids occur in the Great Xing'an, Lesser Xing'an and Zhangguangcai Ranges in NE China. This paper presents partial results of a series of studies on the granitoids from this region, aiming to understand their role in the building of new continental crust in eastern Asia. Three composite granite plutons (Xinhuatun, Lamashan and Yiershi) were chosen for geochemical and isotopic study in order to determine their emplacement ages and petrogenesis. Petrographically, they range from granodiorite (minor), monzogranite, syenogranite to alkali-feldspar granite. Quartz and perthitic feldspar are principal phases, accompanied by minor amounts of plagioclase, biotite (<5%) and other accessory minerals. In addition, many contain abundant miarolitic cavities which suggest that they were emplaced at shallow levels with extensive fractional crystallization. Geochemically, the granites are silica-rich, peraluminous and have high contents of alkalis. They invariably show enrichment in light rare earth elements (LREE) and significant negative Eu anomalies. All the granitic rocks demonstrate the characteristic negative anomalies in Ba, Nb, Sr, P, Eu, and Ti, and a positive anomaly in Pb in the spidergram.
The emplacement of the Xinhuatun pluton took place at 184±4 Ma as revealed by zircon SHRIMP U–Pb data. This is also supported by the slightly younger Rb–Sr whole-rock (WR) isochron age of 173±3 Ma. A whole-rock (WR) Rb–Sr isochron age of 154±3 Ma was obtained for the Lamashan pluton, which is interpreted as close to the time of emplacement. The Yiershi pluton was intruded at about 140 Ma as evidenced by a zircon U–Pb age of 137±2 Ma and WR Rb–Sr isochron age of 143±5 Ma. Biotite-WR Rb–Sr isochrons and 40Ar/39Ar ages of feldspars allow us to estimate the cooling rate of each pluton.
Geochemical data suggest that the rocks are highly fractionated I-type granites. Fractionation of biotite and feldspars was the principal process of magmatic differentiation and responsible for major element variation. Rb, Sr and Ba concentrations were controlled by feldspar separation, whereas REE elements were fractionated by accessory minerals, such as apatite, allanite and monazite. 相似文献
Central Anatolia exhibits good examples of calc-alkaline and alkaline magmatism of similar age in a collision-related tectonic setting (continent–island arc collision). In the Central Anatolia region, late Cretaceous post-collisional plutonic rocks intrude Palaeozoic–Mesozoic metamorphic rocks overthrust by Upper Cretaceous ophiolitic units to make up the Central Anatolian Crystalline Complex.
In the complex, three different intrusive rock types may be recognised based on their geochemical characteristics: (i) calc-alkaline (Behrekdag, Cefalikdag, and Celebi); (ii) subalkaline-transitional (Baranadag); and (ii) alkaline (Hamit). The calc-alkaline and subalkaline plutonic rocks are metaluminous I-type plutons ranging from monzodiorite to granite. The alkaline plutonic rocks are metaluminous to peralkaline plutons, predominantly A-type, ranging from nepheline monzosyenite to quartz syenite.
All intrusive rocks show enrichment in LILE and LREE relative to HFSE, and have high 87Sr/86Sr and low 143Nd/144Nd ratios. These characteristics indicate an enriched mantle source region(s) carrying a subduction component inherited from pre-collision subduction events. The tectonic discrimination diagram of Rb vs. (Y+Nb) suggests that the calc-alkaline, subalkaline, and alkaline plutonic rocks have been affected by crustal assimilation combined with fractional crystallisation processes.
The coexistence of calc-alkaline and alkaline magmatism in the Central Anatolian Crystalline Complex may be attributed to mantle source heterogeneity before collision. The former carries a smaller intraplate component and pre-subduction enrichment compared to the latter. Either thermal perturbation of the metasomatised lithosphere by delamination of the thermal boundary layer (TBL), or removal of a subducted plate (slab breakoff) is the likely mechanism for the initiation of the post-collisional magmatism in the Complex. 相似文献
The Manyas fault zone (MFZ) is a splay fault of the Yenice Gönen Fault, which is located on the southern branch of the North Anatolian Fault System. The MFZ is a 38 km long, WNW–ESE-trending and normal fault zone comprised of three en-echelon segments. On 6 October 1964, an earthquake (Ms = 6.9) occurred on the Salur segment. In this study, paleoseismic trench studies were performed along the Salur segment. Based on these paleoseismic trench studies, at least three earthquakes resulting in a surface rupture within the last 4000 years, including the 1964 earthquake have been identified and dated. The penultimate event can be correlated with the AD 1323 earthquake. There is no archaeological and/or historical record that can be associated with the oldest earthquake dated between BP 3800 ± 600 and BP 2300 ± 200 years. Additionally, the trench study performed to the north of the Salur segment demonstrates paleoliquefaction structures crossing each other. The surface deformation that occurred during the 1964 earthquake is determined primarily to be the consequence of liquefaction. According to the fault plane slip data, the MFZ is a purely normal fault demonstrating a listric geometry with a dip of 64°–74° to the NNE. 相似文献