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71.
Geophysical investigations using 2-D DC resistivity were carried out on old parts of two similar landfills, with waste of
different ages. The data sets, which included high data density in both vertical and horizontal directions, were interpreted
with 2-D smoothness constrained inversion. The landfills were excavated after the surveying. The objective was to test the
capability of the resistivity method as a pre-characterization technique. The objectives were only partially fulfilled. First,
the moisture content was the parameter that appeared to exert the dominant control over the resistivity distribution of the
landfill. The most important potential information that can be recovered is, therefore, an indication of the waste piles hydraulics.
Second, it was neither possible to estimate the amount of recoverable soils, nor to correlate the type of waste with the resistivity
models. However, discrete anomalies were identified, and if specific materials are searched for, the resistivity models indicate
possible places to search.
Received: 23 July 1998 · Accepted: 20 October 1998 相似文献
72.
鱼饲料着色剂-甲壳类下脚料类胡萝卜素的提取技术 总被引:6,自引:0,他引:6
本文对近40年来甲壳类下脚料中类胡萝卜素的提取技术进行了综述,其提取技术流程主要包括:1.下脚料预处理。下脚料研磨后经2mm筛网去除几丁质残渣,或研磨后直接提取;2.热醋酸、盐酸的直接去钙化或酸青贮(有机酸及无机酸)去钙化;3.添加蛋白酶进行水解;4.类胡萝卜素的油提取及化学提取。三个阶段批逆流加工法及有机溶剂(丙酮、己烷、石油醚)提取类胡萝卜素5.类胡萝卜素稳定性控制。在整个处理工艺的某阶段添加 相似文献
73.
S. C. Tarantino M. Zema F. Maglia M. C. Domeneghetti M. A. Carpenter 《Physics and Chemistry of Minerals》2005,32(8-9):568-577
A suite of (Mn1-x
Fe
x
)Nb2O6 (x=0, 0.05, 0.25, 0.50, 0.75, 1) columbite samples has been prepared by solid-state reaction from oxides. X-ray diffraction
and spectroscopic investigations have been carried out in order to gain different perspectives on how the solid solution adapts
at different length scales to cation mixing. X-ray powder diffraction and powder absorption IR spectroscopy data are presented.
The powder diffraction data show that there is no significant excess volume of mixing on the Fe–Mn columbite join. All the
unit-cell parameters decrease linearly as a function of increasing Fe content. Substitution of Fe2+ for the larger Mn2+ cation causes a decrease in the volume of the A polyhedron, which also becomes more regular with respect to both bond-length
and edge-length distortion parameters. No significant variation of the B site has been observed. Wavenumber shifts of the
IR peaks nearly all vary linearly with composition, consistent with linear variations of the lattice parameters. Line broadening
has been quantified by autocorrelation analysis of the IR spectra. This is interpreted as suggesting that there is some element
of local strain or positional disorder at the length scale of second or third nearest neighbours around sites occupied by
Fe. 相似文献
74.
Lallan Prasad Gupta Hodaka Kawahata Mio Takeuchi Hidekazu Ohta Yoshiro Ono 《Resource Geology》2005,55(4):357-372
Abstract. Municipal solid waste combustion leads to concentration of various metals in the solid residue (fly ash) remaining after combustion. These metals pose serious environmental hazard and require proper handling and monitoring in order to control their harmful effects. Leachability of some metals from fly ash was examined in fly ash and Milli-Q water mixture (liquid-to-solid ratio, 100) under various temperature and pH conditions in the laboratory. The leaching experiments conducted for 24 hours showed that pH was generally more important than temperature in controlling the amount of metals leached out of the fly ash. However, at a given pH, rise in temperature led to different degree of (usually one to two fold) enhanced or reduced leaching of metals. Owing to amphoteric nature of oxides of Al, Cr, Pb and Zn, these metals often yielded typical pattern of increase and decrease in their concentrations with change in pH. The extent of leaching of Cr and Pb in our experiments suggests that decrease of pH to acidic range in the case of Pb and to neutral to acidic range for Cr over a long period of storage of fly ash at solid waste dumping site may facilitate leaching of these metals from fly ash, leading to contamination of groundwater to the level that exceeds beyond the level permitted by the environmental laws. 相似文献
75.
Environmental impact of uncontrolled waste disposal in mining and industrial areas in Central Germany 总被引:7,自引:0,他引:7
P. Schreck 《Environmental Geology》1998,35(1):66-72
The present-day landscape in Central Germany, in particular the region of Leipzig, Halle and Bitterfeld, is characterized
by the scars of former industrial activities. Vast districts have been devastated by lignite strip mining. Industrial and
domestic waste, residues from ore smelting, and highly toxic waste products from petrochemical plants and pesticide production
were deposited in abandoned pits near population centers. The chief effects of waste on the environment are the contamination
of groundwater by dissolved pollutants, the acidification of soil and water by the oxidation of pyrite-containing mining waste,
and the salinization of shallow aquifers by rising brines from adjacent confined groundwater affected by mining. The consequences
for the region are serious: mining lakes used for recreational purposes are contaminated by leachates from adjacent waste
dumps. Pyrite-containing refuse from lignite mining under oxidation gives rise to the acidification of surface and groundwater,
a basic condition for pollutant mobilization. In former metal mining districts, metalliferous and radioactive residues from
smelting jeopardize public health. These effects are described in detail using three case studies.
Received: 30 July 1996 · Accepted: 24 February 1997 相似文献
76.
Even carbon numbered n-alk-1-enes, trapped inside organic geomacromolecules such as kerogen, asphaltene and solid bitumen, can survive geologic time because of the effective protection provided by the complex matrix structures of geomacromolecules. These alkenes are presumed to be derived from esters which are commonly present in various organisms. Subjected to either normal maturation increase or the impact of drastic thermal events, these trapped n-alk-1-enes gradually decrease in concentration and eventually disappear. 相似文献
77.
In order to improve understanding of the fate of septic tank or individual sewage disposal system (ISDS) effluent in regolith overlying fractured-rock aquifers, effluent from an ISDS in such a setting was tracked via geophysical, hydrological, and geochemical methods. Under typical precipitation conditions, the effluent entered the fractured bedrock within 5 m of the boundary of the constructed infiltration area. During a period of unusually high spring recharge, the plume migrated between 50 and 100 m within the regolith before infiltrating the fractured bedrock. The chemical signature of the effluent is similar to that required to account for the decline in water quality, suggesting a causative relationship (as estimated from mass-balance models of the surface-water chemistry near the mouth of the basin). The elevated salt content of the effluent during periods of high natural recharge to the infiltration area correlates with elevated salt concentrations in surface and groundwater at the basin scale, suggesting that some of the effluent salt load may be stored in the unsaturated zone during dry periods and flushed during periods of elevated natural recharge. 相似文献
78.
A series of synthetic Ca-Tschermak–diopside (CaAlAlSiO6–CaMgSi2O6) clinopyroxenes were investigated by powder infrared spectroscopy at room temperature in the wavenumber range 80–2,000 cm−1. Measurable local structural heterogeneities in the crystals are suggested by the line broadening parameter, Δcorr that are
observed for intermediate solid-solution compositions. The broadening is most pronounced in the high wavenumber region of
the IR spectra that contains stretching modes involving the TO4 polyhedra. The effective line widths for three selected wavenumber regions deviate positively from linear behavior. This
is also observed for the enthalpy of mixing of this solid solution. The relationship between “excess Δcorr”, δΔcorr, and heat
of mixing, ΔH
mix, behavior was investigated for this clinopyroxene series and for several other binary silicate solid solutions. The ΔH
mix versus δΔcorr slope values show a linear relationship with respect to the integrated excess volume of the various solid solutions. 相似文献
79.
A Double Solid Reactant Method was elaborated from a suggestion of Marini (Geological sequestration of carbon dioxide: Thermodynamics,
kinetics, and reaction path modeling. Developments in Geochemistry, Elsevier, Amsterdam, 2007) to simulate the release of
trace elements during the progressive dissolution of solid phases. The method is based on the definition, for each dissolving
solid, of both an entity whose thermodynamic and kinetic properties are known (either a pure mineral or a solid mixture) and
a special reactant, that is, a material of known stoichiometry and unknown thermodynamic and kinetic properties. The special
reactant is utilised to take into account the concentrations of trace elements in the dissolving solid phase. In this communication,
the influence of several trace elements on the ΔG
f
o, ΔG
r
o and log K of the minerals considered by Lelli et al. (Environ Geol, 2007) and Accornero and Marini (Geobasi, 2007a; Proceedings of
IMWA symposium, Cagliari, 27–31 May 2007b) was evaluated assuming ideal mixing in the solid state. These effects were found
to be negligible for albite and the leucite–latitic glass, limited for muscovites and chlorites, and slightly more important
for apatites. These influences become progressively higher with increasing concentration of trace elements in these minerals.
Based on these deviations in thermodynamic parameters, special reactants should not include oxide components with molar fractions
higher than 0.003.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.
相似文献
Luigi MariniEmail: |
80.
Michael O. Schwartz 《Environmental Geology》2008,54(7):1485-1488
Moral philosophy applied to nuclear waste disposal can be linked to paradigmatic science. Simple thermodynamic principles
tell us something about rightness or wrongness of our action. Ethical judgement can be orientated towards the chemical compatibility
between waste container and geological repository. A container-repository system as close as possible to thermodynamic equilibrium
is ethically acceptable. It aims at unlimited stability, similar to the stability of natural metal deposits within the Earth’s
crust. The practicability of the guideline can be demonstrated. 相似文献