Microlite transfer by disaggregation of mafic inclusions following magma mixing at Soufrière Hills volcano,Montserrat

The Soufrière Hills volcano on Montserrat has for the past 12 years been erupting andesite with basaltic to basaltic–andesite inclusions. The andesite contains a wide variety of phenocryst textures and strongly zoned microlites. Analysis of minor elements in both phenocrysts and microlites allows us to put detailed constraints on their origins. Compositions of clinopyroxene, from overgrowth rims on quartz and orthopyroxene and coarse-grained breakdown rims on hornblende, are identical to those from the mafic inclusions, indicating that these rims form during interaction with mafic magma. In contrast, resorbed quartz and reversely zoned orthopyroxenes form during heating. Microlites of plagioclase and orthopyroxene are chemically distinct from the phenocrysts, being enriched in Fe and Mg, and Al and Ca respectively. However, microlites of plagioclase, orthopyroxene and clinopyroxene are indistinguishable from the compositions of these phases in the mafic inclusions. We infer that the inclusions disaggregated under conditions of high shear stress during ascent in the conduit, transferring mafic material into the andesite groundmass. The mafic component of the system is therefore greater than previously thought. The presence of mafic-derived microlites in the andesite groundmass also means that care must be taken when using this as a starting material for phase equilibrium experiments.     

Long term exposure to respirable volcanic ash on Montserrat: a time series simulation

Frequent ash fallout from long-lived eruptions (with active phases greater than 5 years) may lead to local populations experiencing unacceptably high cumulative exposures to respirable particulate matter. Ash from Montserrat has been shown to contain significant levels of cristobalite and other reactive agents that are associated with an increased risk of developing pneumoconiosis (including silicosis) and other long-term health problems. There are a number of difficulties associated with estimating risks in populations due to uncertain and wide ranging individual exposures, change in behaviour with time and the natural variation in individual response. Present estimates of risk in workers and other population groups are simplifications based on a limited number of exposure measurements taken on Montserrat (1996–1999), and exposure−response curves from epidemiological studies of coal workers exposed to siliceous dust. In this paper we present a method for calculating the long-term cumulative exposure to cristobalite from volcanic ash by Monte Carlo simulation. Code has been written to generate synthetic time series for volcanic activity, rainfall, ash deposition and erosion to give daily ash deposit values and cristobalite fraction at a range of locations. The daily mean personal exposure for PM₁₀ and cristobalite is obtained by sampling from a probability distribution, with distribution parameters dependent on occupation, ground deposit depth and daily weather conditions. Output from multiple runs is processed to calculate the exceedance probability for cumulative exposure over a range of occupation types, locations and exposure periods. Results are interpreted in terms of current occupational standards, and epidemiological exposure−response functions for silicosis are applied to quantify the long-term health risk. Assuming continuing volcanic activity, median risk of silicosis (profusion 1/0 or higher) for an average adult after 20 years continuous exposure is estimated to be approximately 0.5% in northern Montserrat to 1.6% in Cork Hill. The occupational group with the highest exposure to ash are gardeners, with a corresponding 2% to 4% risk of silicosis. In situations where opportunities for in-depth exposure studies are limited, computer simulations provide a good indication of risk based on current expert knowledge. By running the code for a range of input scenarios, the cost-benefit of mitigation measures (such as a programme of active ash clearance) can be estimated. Results also may be used to identify situations where full exposure studies or fieldwork would be beneficial. Editorial responsibility: J Stix     

Gas retention in fine-grained pyroclastic flow materials at high temperatures

The ability of a dense pyroclastic flow to maintain high gas pore pressure, and hence low friction, during runout is determined by (1) the strengths and longevities of gas sources, and (2) the ability of the material to retain residual gas once those sources become ineffective. The latter is termed the gas retention capacity. Gas retention capacity in a defluidizing granular material is governed by three timescales: one for the evacuation of bubbles (t _be ; brief and not considered in this paper), one for hindered settling from the expanded state (t _sett), and one for diffusive release of residual pore pressure from the non-expanded state (t _diff). The relative magnitides of t _sett and t _diff depend on bed thickness, t _sett dominating in thin systems and t _diff in thick ones. Three pyroclastic flow materials, two ignimbrites and a block-and-ash flow sample, were studied experimentally to investigate expansion behaviour under gas flow and to determine gas retention times. Effects of particle size were evaluated by using two size cuts (<4 mm and <250 μm) from each sample. Careful drying of the materials was necessary to avoid effects of humidity-related cohesion. Two sets of experiments were carried out: (1) expansion in the non-bubbling regime at 50–200°C, (2) bed collapse tests from the initially bubbling state at 50–550°C. Provided that gas channelling was avoided by gentle stirring, all the samples exhibited a regime of uniform expansion prior to the onset of bubbling. Fine particle size (in particular high fines content), low particle density and high temperature all favoured smoother fluidization by increasing the maximum expansion possible in the non-bubbling state. An empirical equation describing the uniform expansion of the materials was determined. High temperature also favoured greater gas partitioning into the dense phase of the bubbling bed, as well (in finer-grained samples) as higher voidage in the settled bed. Large values of t _sett and t _diff were favoured by fine particle size. Temperature had less influence, suggesting that experimental results at low temperatures (50–200°C) can be extrapolated to higher temperatures. Gas retention times provide insight into the ability of pyroclastic flows in expanded (t _sett) or non-expanded (t _diff) flow states to retain gas once air ingestion or gas production have become ineffective. Finer-grained pyroclastic flows are expected to retain gas longer, and hence to have higher apparent ‘mobilities’, than coarser-grained ones of comparable volume, as has been observed on Montserrat.     

Locating pyroclastic flows on Soufriere Hills Volcano, Montserrat, West Indies, using amplitude signals from high dynamic range instruments

Pyroclastic flows are located using amplitude signals from a seven-station high dynamic range seismograph array located 1.9–6.1 km from Soufriere Hills Volcano in Montserrat, West Indies. Locations are determined by measuring the seismograph signal amplitude for an event recorded at several stations in a moving time window analysis. For a given window, the measured amplitudes are corrected to a trial source location by removing the effect of the surface wave geometric spreading, instrument gain, and the attenuation at calculated travel-times. The trial source location is then compared to other trial locations via an iterative localised grid search where the root-mean-squared amplitude residual (δA) is minimised. The process is repeated for subsequent time steps resulting in a best-fit event location and size through time. The method has been tested on four small events occurring on April 8, 1999, August 12, 1999, February 25, 2001, and July 4, 2001, when visual observations of pyroclastic flows coincided with good seismograph station coverage (number of stations 5, azimuthal gap <160°). Based on the location results the four events propagated 0.5, 1.4, 1.3 and 1.0 km from the dome, and had maximum attenuation-corrected reduced displacements (D_RQ) of 9.0, 2.8, 6.9 and 2.3 cm² and maximum pyroclastic flow velocities of 7, 30, 20 and 8 ms⁻¹, respectively. A time-lapse video of the event of August 12, 1999, shows that amplitude-based location through time closely matches the observed run-out distance and velocity. In contrast, amplitude-based locations for the events of April 8, 1999, and July 4, 2001, underestimated the actual flow run-out by 1.5 km. Underestimation of the true run-out distance is probably due to both the increased distribution of sources as coherent dome material disaggregates into many blocks, and signal contamination from other sources. Results indicate that pyroclastic flows and rockfalls can be located using amplitude signals from high dynamic range seismograph stations yielding estimates of size and trajectory, regardless of visibility conditions on the volcano. This new method is being tested as a hazard mitigation and research tool on Montserrat.     

Anatomy of a submarine pyroclastic flow and associated turbidity current: July 2003 dome collapse, Soufrière Hills volcano, Montserrat, West Indies

The 12 to 13 July 2003 andesite lava dome collapse at the Soufrière Hills volcano, Montserrat, provides the first opportunity to document comprehensively both the sub‐aerial and submarine sequence of events for an eruption. Numerous pyroclastic flows entered the ocean during the collapse, depositing approximately 90% of the total material into the submarine environment. During peak collapse conditions, as the main flow penetrated the air–ocean interface, phreatic explosions were observed and a surge cloud decoupled from the main flow body to travel 2 to 3 km over the ocean surface before settling. The bulk of the flow was submerged and rapidly mixed with sea water forming a water‐saturated mass flow. Efficient sorting and physical differentiation occurred within the flow before initial deposition at 500 m water depth. The coarsest components (～60% of the total volume) were deposited proximally from a dense granular flow, while the finer components (～40%) were efficiently elutriated into the overlying part of the flow, which evolved into a far‐reaching turbidity current.     

Volcanic seismicity at Montserrat,a comparison between the 2005 dome growth episode and earlier dome growth

In 2005 Soufrière Hills Volcano on Montserrat started its third major episode of dome growth since the current eruption started in 1995. The style of seismicity associated with dome growth has changed, in particular the events known as ‘hybrid’ earthquakes have reduced in numbers by an order of magnitude compared to previous dome growth episodes. In the past, hybrid earthquakes have been associated with magma ascent and so it is surprising to observe prolonged periods of rapid dome growth during which very few hybrid earthquakes are recorded. In addition, the frequency of the codas of hybrid earthquakes, as well as of some of the so called ‘long-period’ events, has changed. The changes in recorded seismicity have had a marked effect on the techniques used to monitor the state of the volcano and those events that continue to be recorded in large numbers (‘rockfall events’) have been used to assess the state of activity at the volcano.     

Evidence for carbonate platform failure during rapid sea‐level rise; ca 14 000 year old bioclastic flow deposits in the Lesser Antilles

Bioclastic flow deposits offshore from the Soufrière Hills volcano on Montserrat in the Lesser Antilles were deposited by the largest volume sediment flows near this active volcano in the last 26 kyr. The volume of these deposits exceeds that of the largest historic volcanic dome collapse in the world, which occurred on Montserrat in 2003. These flows were most probably generated by a large submarine slope failure of the carbonate shelf comprising the south‐west flank of Antigua or the east flank of Redonda; adjacent islands that are not volcanically active. The bioclastic flow deposits are relatively coarse‐grained and either ungraded or poorly graded, and were deposited by non‐cohesive debris flow and high density turbidity currents. The bioclastic deposit often comprises multiple sub‐units that cannot be correlated between core sites; some located just 2 km apart. Multiple sub‐units in the bioclastic deposit result from either flow reflection, stacking of multiple debris flow lobes, and/or multi‐stage collapse of the initial landslide. This study provides unusually precise constraints on the age of this mass flow event that occurred at ca 14 ka. Few large submarine landslides have been well dated, but the slope failures that have been dated are commonly associated with periods of rapid sea‐level change.     

Gas and particle emissions from Soufrière Hills Volcano, Montserrat, West Indies: characterization and health hazard assessment

 The Soufrière Hills Volcano, Montserrat, erupting since 18 July 1995, intensified its degassing in early 1996 with the continuing growth of the lava dome inside the summit crater. During this period of increased activity, between 11 and 18 March 1996, we measured gases and particles within the visible plume to determine whether at that time it posed a health risk to the population of Plymouth, the capital town, which is 5 km southwest (downwind) and was then still occupied. Gravimetric measurements were made of total suspended particles (TSP) and particles having an aerodynamic diameter of less than 10 μm (PM₁₀). Measurements were made of sulphur dioxide (SO₂), hydrochloric acid (HCl), hydrofluoric acid (HF), nitric acid (HNO₃), acetic acid (CH₃COOH), formic acid (HCOOH), and particulate sulphate (SO₄ ^2–), chloride (Cl^–), nitrate (NO₃ ^–), fluoride (F^–), methanesulphonate (CH₃SO₃ ^–), acetate (CH₃COO^–), formate (HCOO^–), ammonium (NH₄ ⁺), sodium (Na⁺) and acidity (H⁺). Trace metals having human health implications [chromium (Cr), nickel (Ni), cobalt (Co), copper (Cu), zinc (Zn), arsenic (As), selenium (Se), cadmium (Cd), tin (Sn), mercury (Hg) and lead (Pb)] were also determined. Mean concentrations of HCl, SO₂ and HF obtained in the town of Plymouth were 14.0, 5.9 and 0.8 ppbv, respectively. Corresponding concentrations in the mixed plume on the crater edge were 533, 168 and 22 ppbv. There were no direct emissions of HNO₃, although nitrate was detected in coarse particles at the source. Higher concentrations of CH₃COOH and HCOOH were measured close to the crater. Mean TSP and PM₁₀ were 64 and 15 μg m^–3 in Plymouth, and 455 and 47 μg m^–3 on the upper volcano slope. Aerosols were highly acidic at the source but rapidly neutralised during transport. Trace metals were enriched in the aerosol relative to crater surface material. The concentrations of the acid gases, sulphur dioxide in particular, and particles were found to be too small to pose a health hazard at the time of these measurements, when relatively modest volcanic activity was occurring. Received: 9 September 1998 / Accepted: 29 August 1999