On the composition and differentiation of Ceres

The dwarf planet Ceres has a density of 2040-2250 kg m⁻³, and a dark non-icy surface with signs of hydrated minerals. As opposed to a differentiated internal structure with a nonporous rocky core and a water mantle, there are arguments for undifferentiated porous interior structure. Ceres’ mass and dimensions are uncertain and do not exclude undifferentiated interior even if hydrostatic equilibrium is attained. The rocky surface may be inconsistent with a large-scale water-rock differentiation. A differentiated structure with a thick water mantle below a rocky crust is gravitationally unstable and an overturn would have led to abundant surface salt deposits, which are not observed. A formation of hydrated surface minerals caused by internal heating implies a major density increase through devolatilization of the interior. A later accumulation of hydrated materials is inconsistent with anhydrous surfaces of many asteroids and with a low rate of the cosmic dust deposition in the inner Solar System. Ceres’ internal pressures (<140-200 MPa) are insufficient to significantly reduce porosity of chondritic materials and there is no need for abundant water phases to be present to account for the bulk density. Having the porosity of ordinary chondrites (∼10%), Ceres can consist of rocks with the grain density of pervasively hydrated CI carbonaceous chondrites. However, additional low-density phases (e.g., water ice) require to be present in the body with the grain density of CM chondrites. The likely low-density mineralogy of the interior implies Ceres’ accretion from pervasively aqueously altered carbonaceous planetesimals depleted in short-lived radionuclide ²⁶Al. Abundant water ice may not have accreted. Limited heat sources after accretion may not have caused major mineral dehydration leading to formation of water mantle. These inferences can be tested with the Dawn spacecraft in 2015.     

Mineralogical characterization of Mars Science Laboratory candidate landing sites from THEMIS and TES data

Data from the Mars Global Surveyor Thermal Emission Spectrometer (TES) and the Mars Odyssey Thermal Emission Imaging System (THEMIS) instruments are used to assess the mineralogic and dust cover characteristics of landing regions proposed for the Mars Science Laboratory (MSL) mission. Candidate regions examined in this study are Eberswalde crater, Gale crater, Holden crater, Mawrth Vallis, Miyamoto crater, Nili Fossae Trough, and south Meridiani Planum. Compositional units identified in each region from TES and THEMIS data are distinguished by variations in hematite, olivine, pyroxene and high-silica phase abundance, whereas no units are distinguished by elevated phyllosilicate or sulfate abundance. Though phyllosilicate minerals have been identified in all sites using near-infrared observations, these minerals are not unambiguously detected using either TES spectral index or deconvolution analysis methods. For some of the sites, small phyllosilicate outcrop sizes relative to the TES field of view likely hinder phyllosilicate mineral detection. Porous texture and/or small particle size (<∼60 μm) associated with the phyllosilicate-bearing surfaces may also contribute to non-detections in the thermal infrared data sets, in some areas. However, in Mawrth Vallis and Nili Fossae, low phyllosilicate abundance (<10-20 areal %, depending on the phyllosilicate composition) is the most likely explanation for non-detection. TES data over Mawrth Vallis indicate that phyllosilicate-bearing surfaces also contain significant concentrations (>15%, possibly up to ∼40%) of a high-silica phase such as amorphous silica or zeolite. High-silica phase abundance over phyllosilicate-bearing surfaces in Mawrth Vallis is higher than that of surrounding surfaces by 10-15%. With the exception of these high-silica surfaces in Mawrth Vallis, regions examined in this study exhibit similar bulk mineralogical compositions to that of most low-albedo regions on Mars; the MSL scientific payload will thus be able to provide important information on surface materials typical of low-albedo regions in addition to investigating the origin of phyllosilicate and/or sulfate deposits. With the exception of Gale crater, all of the landing sites have relatively low dust cover compared to classic high-albedo regions (Tharsis, Arabia and Elysium) and to previous landing sites in Gusev Crater, Utopia Planitia, and Chryse Planitia.     

Spectral unmixing for mineral identification in pancam images of soils in Gusev crater, Mars

The objective of this work is to propose an automated unmixing technique for the analysis of 11-channel Mars Exploration Rover Panoramic Camera (MER/Pancam) spectra. Our approach is to provide a screening tool for identifying unique/distinct reflectance spectra. We demonstrate the utility of this unmixing technique in a study of the mineralogy of the bright salty soils exposed by the rover wheels in images of Gusev crater regions known as Paso Robles (Sols 400,426), Arad (Sol 721), and Tyrone (Sol 790). The unmixing algorithm is based on a novel derivation of the Nonnegative Matrix Factorization technique and includes added features that preclude the adverse effects of low abundance materials that would otherwise skew the unmixing. In order to create a full 11-channel spectrum out of the left and right eye stereo pairs, we also developed a new registration procedure that includes rectification and disparity calculation of the images. We identified two classes of endmember spectra for the bright soils imaged on Sols 426 and 790. One of these endmember classes is also observed for soils imaged on Sols 400 and 721 and has a unique spectral shape that is distinct from most iron oxide, sulfate and silicate spectra and differs from typical martian surface spectra. Instead, its unique spectral character resembles the spectral shape of the ferric sulfate minerals fibroferrite (Fe³⁺(SO₄)(OH) · 5H₂O) and ferricopiapite and the phosphate mineral ferristrunzite . The other endmember class is less consistent with specific minerals and is likely a mixture of altered volcanic material and some bright salts. Further analyses of data from Sols 400 and 790 using an anomaly detection algorithm as a tool for detecting low abundance materials additionally suggests the identification of the sulfate mineral paracoquimbite (Fe₂(SO₄)₃ · 9H₂O). This spectral study of Pancam images of the bright S- and P-enriched soils of Gusev crater identifies specific ferric sulfate and ferric phosphate minerals that are consistent with the unique spectral properties observed here in the 0.4-1 μm range.     

Mapping of water frost and ice at low latitudes on Mars

This paper reports on mapping of water frost and ice on Mars, in the range of latitudes between 30°S and 30°N. The study has been carried out by analysing 2485 orbits acquired during almost one martian year by the Mars Express/OMEGA imaging spectrometer. Water frost/ice is identified by the presence of ∼1.5 μm, ∼2 μm and ∼3.0 μm absorptions. Although the orbits analysed in this study cover all seasons, water frost/ice is observed only near the aphelion seasons, at Ls = 19° and at Ls = 98-150°. Water frost/ice is detected mainly on the southern hemisphere between 15°S and 30°S latitude while it has not been identified within 15°S-15°N. In the northern hemisphere, the water frost/ice detection is complicated by the presence of clouds. Usually, water frost/ice is found in shadowed areas, while in few cases it is exposed to the sunlight. This indicates a clear relationship with the local illumination conditions on the slopes which favour the water frost/ice deposition on the surface when the temperatures are very low. OMEGA observations span from 10 to 17 LT and the frost/ice is detected mainly between 15 and 16 LT, with practically no detection before 13 LT. We think this is due to the fact that the 10-12 LT observations occur at large distances and it is not a local time effect. A thermal model is used to determine the deposition conditions on the sloped surfaces where water frost/ice has been found. There, daily atmospheric saturation does not occur on pole facing 10-25° slopes with current water vapour abundances but only by assuming values greater than 40 pr μm. Moreover, the water frost/ice is not detected during the northern winter, even if the thermal model foresees daily saturation on 25° slopes.     

Mid-infrared spectral variability for compositionally similar asteroids: Implications for asteroid particle size distributions

We report an unexpected variability among mid-infrared spectra (IRTF and Spitzer data) of eight S-type asteroids for which all other remote sensing interpretations (e.g. VNIR spectroscopy, albedo) yield similar compositions. Compositional fitting making use of their mid-IR spectra only yields surprising alternative conclusions: (1) these objects are not “compositionally similar” as the inferred abundances of their main surface minerals (olivine and pyroxene) differ from one another by 35% and (2) carbonaceous chondrite and ordinary chondrite meteorites provide an equally good match to each asteroid spectrum.Following the laboratory work of Ramsey and Christensen (Ramsey, M.S., Christensen, P.R. [1998]. J. Geophys. Res. 103, 577-596), we interpret this variability to be physically caused by differences in surface particle size and/or the effect of space weathering processes. Our results suggest that the observed asteroids must be covered with very fine (<5 μm) dust that masks some major and most minor spectral features. We speculate that the compositional analysis may be improved with a spectral library containing a wide variety of well characterized spectra (e.g., olivine, orthopyroxene, feldspar, iron, etc.) obtained from very fine powders. In addition to the grain size effect, space weathering processes may contribute as well to the reduction of the spectral contrast. This can be directly tested via new laboratory irradiation experiments.     

The 506 nm absorption feature in pyroxene spectra: Nature and implications for spectroscopy-based studies of pyroxene-bearing targets

High-resolution (0.34 nm) reflectance spectra of a suite of terrestrial ortho- and clinopyroxenes were characterized in the 506-nm region. This region exhibits absorption bands attributed to spin-forbidden transitions in Fe²⁺ located in the M2, and possibly M1, crystallographic site(s). The most intense absorption bands (up to 3.8% deep in <45 μm fractions) are present in low Ca-content orthopyroxene spectra. This region exhibits two (spectral Group I) or more (spectral Group II) absorption bands in the 500-515 nm interval. Group I spectra are associated with the lowest Ca-content samples. For orthopyroxenes, the number of constituent absorption bands and band depths vary as a function of Ca content; increasing Ca content results the appearance of more than two absorption bands and a general reduction in band depths, offsetting an expected increase in band depth with increasing Fe²⁺ content; band depths may also be reduced due to the long wavelength wing of ultraviolet region Fe-O charge transfer absorptions. Band depths and shapes in this region are also a function of grain size, with the strongest bands appearing for larger grain sizes - in the 90-250 μm range. The number and position of constituent absorption bands can be used to constrain factors such as cooling rates, as expressed in the formation of Guinier-Preston zones versus coarser-grained augite exsolution lamellae. Band depths in the spectra of fine-grained (<45 μm) clinopyroxenes do not exceed 1% and are generally lowest for spectral type A clinopyroxenes, where most of the Fe²⁺ is present in the M1 crystallographic site. The appearance of the 506 nm band in the spectra of pyroxene-bearing asteroids can be used to constrain pyroxene composition and structure. The results of this study suggest that detailed analysis of absorption features in the 506 nm region is a powerful tool for determining the composition and structure of pyroxenes. The spectral resolution of the VIR-MS spectrometer aboard the Dawn spacecraft - which will examine Asteroid 4 Vesta, a body possessing surficial pyroxenes - will be sufficient to provide some constraints on pyroxene composition.     

Diagenetic haematite and sulfate assemblages in Valles Marineris

Previous orbital mapping of crystalline gray haematite, ferric oxides, and sulfates has shown an association of this mineralogy with light-toned, layered deposits on the floor of Valles Marineris, in chaos terrains in the canyon’s outflow channels, and in Meridiani Planum. The exact nature of the relationship between ferric oxides and sulfates within Valles Marineris is uncertain. The Observatoire pour la Mineralogie, l’Eau, les Glaces et l’Activite (OMEGA) spectrometer initially identified sulfate and ferric oxides in the layered deposits of Valles Marineris. The Thermal Emission Spectrometer (TES) has also mapped coarse (gray) haematite in or at the base of these deposits. We use Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) spectra and Context Camera (CTX) and High Resolution Imaging Science Experiment (HiRISE) imagery from the Mars Reconnaissance Orbiter (MRO) to explore the mineralogy and morphology of the large layered deposit in central Capri Chasma, part of the Valles Marineris canyon system that has large, clear exposures of sulfate and haematite. We find kieserite (MgSO₄·H₂O) and ferric oxide (often crystalline red haematite) in the lower bedrock exposures and a polyhydrated sulfate without ferric oxides in the upper bedrock. This stratigraphy is duplicated in many other basinal chasmata, suggesting a common genesis. We propose the haematite and monohydrated sulfate formed by diagenetic alteration of a sulfate-rich sedimentary deposit, where the upper polyhydrated sulfate-rich, haematite-poor layers either were not buried sufficiently to convert to a monohydrated sulfate or were part of a later depositional phase. Based on the similarities between the Valles Marineris assemblages and the sulfate and haematite-rich deposits of Meridiani Planum, we hypothesize a common evaporite and diagenetic formation process for the Meridiani Planum sediments and the sulfate-bearing basinal Interior Layered Deposits.     

Minerals mapping of the lunar surface with Clementine UVVIS/NIR data based on spectra unmixing method and Hapke model

The distribution of minerals on the lunar surface is information which could contribute to studying lunar origin and evolution. In this paper, the distribution of clinopyroxene, orthopyroxene, olivine, ilmenite, and plagioclase on the lunar surface has been mapped based on Hapke radiative transfer model and linear unmixing of spectra with Clementine UVVIS/NIR data. The results have been validated on the basis of minerals modal abundance data of the Apollo samples, and problems in the minerals abundance mapping have been analyzed. The validation based on analysis data of Apollo samples indicates that plagioclase mapped in this paper represents the total abundance of plagioclase and agglutinitic glass. The minerals mapping results show that the lunar surface is mainly composed of pyroxene, plagioclase, agglutinitic glass, and ilmenite. Basalt in the lunar mare is mainly composed of clinopyroxene and ilmenite, and lunar highland is mainly composed of plagioclase and agglutinitic glass. Orthopyroxene is mainly distributed on the north of Mare Imbrium, on the south of Maria and Aitken Basin. According to our results, there is probably no large area of olivine distribution on the lunar surface which is different from earlier published results. Therefore, emphasis should be put on the olivine distribution in the minerals mapping using hyperspectral data such as M³ of Chandrayaan-1 and IIM of ChangE-1.     

Constraints on Mercury’s surface composition from MESSENGER and ground-based spectroscopy

The composition and chemistry of Mercury’s regolith has been calculated from MESSENGER MASCS 0.3-1.3 μm spectra from the first flyby, using an implementation of Hapke’s radiative transfer-based photometric model for light scattering in semi-transparent porous media, and a linear spectral mixing algorithm. We combine this investigation with linear spectral fitting results from mid-infrared spectra and compare derived oxide abundances with mercurian formation models and lunar samples. Hapke modeling results indicate a regolith that is optically dominated by finely comminuted particles with average area weighted grain size near 20 μm. Mercury shows lunar-style space weathering, with maturation-produced microphase iron present at ∼0.065 wt.% abundance, with only small variations between mature and immature sites, the amount of which is unable to explain Mercury’s low brightness relative to the Moon. The average modal mineralogies for the flyby 1 spectra derived from Hapke modeling are 35-70% Na-rich plagioclase or orthoclase, up to 30% Mg-rich clinopyroxene, <5% Mg-rich orthopyroxene, minute olivine, ∼20-45% low-Fe, low-Ti agglutinitic glass, and <10% of one or more lunar-like opaque minerals. Mercurian average oxide abundances derived from Hapke models and mid-infrared linear fitting include 40-50 wt.% SiO₂, 10-35 wt.% Al₂O₃, 1-8 wt.% FeO, and <25 wt.% TiO₂; the inferred rock type is basalt. Lunar-like opaques or glasses with high Fe and/or Ti abundances cannot on their own, or in combination, explain Mercury’s low brightness. The linear mixing results indicate the presence of clinopyroxenes that contain up to 21 wt.% MnO and the presence of a Mn-rich hedenbergite. Mn in M1 crystalline lattice sites of hedenbergite suppresses the strong 1 and 2 μm crystal field absorption bands and may thus act as a strong darkening agent on Mercury. Also, one or more of thermally darkened silicates, Fe-poor opaques and matured glasses, or Mercury-unique Ostwald-ripened microphase iron nickel may lower the albedo. A major part of the total microphase iron present in Mercury’s regolith is likely derived from FeO that is not intrinsic to the crust but has been subsequently delivered by exogenic sources.     

Mineralogy of Asteroid 1459 Magnya and implications for its origin

Detailed near-infrared spectral observations of Asteroid 1459 Magnya reveal an asteroid that is primarily composed of pyroxene and plagioclase feldspar, confirming earlier suggestions that Magnya has a basaltic composition. The average Magnya spectrum for March 23, 2002 has a Band I center of 0.926 μm and a Band II center of 1.938 μm. Observations over  hours show little variation in band center positions. The feldspar-to-pyroxene ratio is ∼0.6 on Magnya's surface. Comparing Magnya with the spectral parameters from 4 Vesta shows discordant pyroxene chemistries; Magnya's pyroxenes contain ∼10 mol% less Fs than Vesta's pyroxenes. This suggests that Magnya originated from a parent body other than 4 Vesta and that its progenitor formed in a more chemically reduced region of the solar nebula within the asteroid belt.