Optimization of the Sampling Technique for the Determination of Dissolved Hydrogen in Groundwater

In this study a field‐sampling technique for dissolved hydrogen (H₂) in groundwater will be presented which allows the transport of gaseous samples into the laboratory for further analysis. The method consists of transferring the headspace trapped in a gas‐sampling bulb which is continuously purged by groundwater into previously evacuated vials using a gas‐tight syringe. Three transfer steps with preceding evacuation of the vial led to a H₂‐recovery of 100 % in laboratory experiments. The method has been applied to determine H₂ concentrations in an aquifer contaminated with chlorinated solvents. Tests concerning the effect of different pumping techniques on H₂ concentrations revealed that most reliable values were obtained with a bladder pump, while an electrically driven submersible pump generated considerable amounts of hydrogen due to electrochemical interactions with the sampled water. Concentrations of dissolved hydrogen in field and laboratory samples were about two orders of magnitude higher when sampling was performed with the electrically driven submersible pump compared to sampling with the bladder pump and a peristaltic pump. Lab experiments with a Plexiglas reservoir to produce H₂‐enriched water were used to study the effect of two tubing materials (PVC, polyamide) on H₂ losses. PVC tubing turned out to allow transfer of H₂‐enriched water over 25 m without significant losses, while PA‐tubing was not suitable for sampling of H₂.     

非线性最小二乘参数平差迭代算法

在非线性最小二乘问题现有的3类主要算法－－高斯－牛顿法、阻尼最小二乘法和最小二乘的拟牛顿法的基础上，引入了综合性能更优的非线性规划的SQPM（序列二次规划法）算法，并且为进一步提高SQPM算法迭代的收敛性，对其步长策略进行了改进。改进的SQPM算法成为无需精确计算参数概略值的非线性最小二乘参数平差的实用和有效算法。     

地下流体地震前兆多层次跟踪法短期预测在粤闽交界和珠江三角洲地区的应用

利用粤闽交界地区、珠江三角洲地区连续10年左右的地下流体资料，研究利用多层次跟踪法进行地震短期预测的效果，结果表明，该法的粤闽交界及近海地区的应用效果较好，但在珠江三角洲及近海地区暂不宜应用。     

均质土坡的安全系数

本文用变分法的基本理论的方法，推导出了均质土坡稳定性在平面应变情况下的基本方程，将简单边坡无粘性土（Ｃ＝０）与纯粘性土ψ＝０）的情况作为特例导出了相应的计算方法与计算公式，并对传统的条分法与土坡临界高度计算方法进行了讨论。     

几种有效的测井找气方法

已建立的几种有效测井找气方法,在我国天然气勘探开发中应用,发现了许多气层.本文综述这几种有效的测井找气方法,并给出了实例.     

基于SSM的云南省产业结构水平测评

基于传统偏离-份额分析法（SSM）以及动态偏离-份额分析法,首先对中国西部地区12省（直辖市、自治区）产业结构进行横向对比,再结合云南省产业结构的历年纵向分析,旨在为云南省产业结构优化升级、经济发展方式转变提供科学参考．结果表明：1）云南省第一产业在产业结构和竞争力上均处于相对落后地位;2）云南省第二产业结构优势不明显,具备一定的竞争力优势,但同西部发达地区相比仍有一定差距;3）云南省第三产业结构优势明显,但竞争力优势不明显,产业结构优势未能很好的转化为竞争力优势;4）云南省应根据自身优势及存在问题,抓住机遇、制定对策,促进产业结构优化升级．     

用线性规划法求解瞬变电磁场反射系数

讨论了在水平层状介质中的反射系数的物理意义 ,推出时间域含有以反射系数序列为未知项的欠定方程组 ,提出用线性规划法求解瞬变电磁场反射系数序列 ,并给出求解思路和程序框图。对两个理论模型进行了处理 ,计算出了其反射系数。算例分析结果表明 ,算法可靠 ,程序可行。这一方法可用于瞬变电磁成像数值计算中。     

孔隙尺度多孔介质流体流动与溶质运移高性能模拟

深入探究孔隙尺度下的流体流动特性和溶质运移规律对石油开采、农田养分管理、地下水污染修复有着重要意义。以人工构建的多孔介质结构和同步辐射X射线显微CT扫描的土壤团聚体(分辨率3.7μm)为研究对象,在空间节点数多达64 000 000的情况下,基于格子Boltzmann模型和GPU并行技术计算得到多孔介质流体运动和溶质运移过程的关键参数,并据此探究多孔介质空间异质性对水力学特性的影响。通过对3组不同结构的多孔介质比较发现,结构复杂程度最高的土壤样品和不规则堆叠的圆球结构的渗透率在100 mD(即10^-13m^2)量级,远低于规则堆叠的圆球结构(>20 000 mD);土壤的迂曲度为1.40~1.60,明显高于规则堆叠的圆球结构。研究结果表明,渗透率大的样品具有较小的迂曲度,这与结构的空间异质性有较强的关系;土壤的渗透率和迂曲度呈现各向异性;在水力梯度一定的前提下,渗透率较大的样品,纵向弥散系数也较大;同时,结构的异质性也会影响溶质的穿透曲线。本研究提出的模拟方法可在土壤结构中进行高效的水流运动和溶质运移模拟,可用于土壤多孔介质在孔隙尺度下的水力学特性研究。     

The generation and redistribution of overland flow on a massive oxic soil in a eucalypt woodland within the semi-arid tropics of North Australia

There is a dearth of knowledge on the runoff processes of eucalypt woodland communities in the semi-arid tropics of Australia. The work was undertaken on a 100 m transect of a 0·8 degree hillslope typical of the ‘smooth plainlands’ of central-north Queensland. This paper introduces a new experimental design for measuring overland flow in such areas by way of a cascade system of unbounded runoff plots which allow the inputs and outputs between troughs to be calculated. Most storms generate overland flow. Time to overland flow ranges between 1 and 18 min where rain intensities are above 10mm hr⁻¹ and when the average detention storage of 3·6 mm is exceeded. The bare soil surfaces within the scattered grass understory control the runoff generation process through the temporal variability of field saturated hydraulic conductivity. The study demonstrated that overland flow is mainly redistributed over the freely-draining oxic soil. Some areas export more overland flow than they gain from upslope (runoff), others gain more overland flow than they export (runon). Over the study period only 2 per cent of total rain is transferred out of this 100 m transect as overland flow due to the short duration of storms, the relatively high soil permeability, and the low slope angle. The remainder adds to the large soil water store or deep drainage. The variability of runoff–runon over these ‘smooth plainlands’ highlights how results from bounded plots would be misleading in such areas.     

COMPARISON OF MEASUREMENT METHODS BASED ON A MODEL FOR THE ERROR STRUCTURE

Comparison of methods is a technique often used for investigation of systematic errors of measurementmethods.As concerns the design and analysis of such comparisons,much variety of opinion and practiceexists.In one approach a few specimens are measured several times by different operators in differentlaboratories(reproducibility conditions)and in another approach several specimens are measured on oneor a few occasions by one operator in the same laboratory(repeatability conditions).In this paper amodel for the error structure of measurements is formulated and it is emphasized that one has todistinguish between two types of systematic errors:the first type depends only on the level of themeasured quantity and the second type is specific for the separate specimens.On the basis of this modelthe information which can be obtained from the different designs of method comparisons is discussed.A new approach for the analysis of method comparisons with many specimens is also proposed.