Using multiple archives to understand past and present climate–human–environment interactions: the lake Erhai catchment,Yunnan Province,China

A 6.48 m sediment core sequence from Erhai lake, Yunnan Province, provides a multi-proxy record of Holocene environmental evolution and human activity in southwest China. These sedimentary records provide proxy time series for catchment vegetation, flooding, soil erosion, sediment sources and metal workings. They are complemented by independent regional climate time-series from speleothems, archaeological records of human habitation, and a detailed documented environmental history. The article attempts to integrate these data sources to provide a Holocene scale record of environmental change and human–environment interactions. These interactions are analysed in order to identify the roles of climate and social drivers on environmental change, and the lessons that may be learned about the future sustainability of the landscape. The main conclusions are: lake sediment evidence for human impacts from at least 7,500 cal year BP is supported by a terrestrial record of cultural horizons that may extend back to ∼9,000 cal year BP. A major shift in the pollen assemblage, defined by detrended correspondence analysis, at ∼4,800 cal year BP marks the transition from a ‘nature-dominated’ to a ‘human-dominated’ landscape. From 4,300 cal year BP, a change in river discharge responses may signal the beginning of hydraulic modification through drainage and irrigation. Major increases in disturbed land taxa and loss of forest taxa from 2,200 cal year BP onward, also associated with the start of significant topsoil erosion, register the expansion of agriculture by Han peoples. It is also the start of silver smelting linked to trade along the SW Silk Road with Dali becoming a regional centre. Peak levels of disturbed land taxa, topsoil and gully erosion are associated with the rise and fall of the Nanzhao (CE 738–902) and Dali (CE 937–1253) Kingdoms, and the documented environmental crisis that occurred in the late Ming and Qing dynasties (CE 1644–1911). The crisis coincides with a stronger summer monsoon, but exploitation of marginal agricultural land is the main driver. These historical perspectives provide insight into the resilience and sustainability of the modern agricultural system. The largest threat comes from high magnitude-low frequency flooding of lower dry farmed terraces and irrigated valley plains. A sustainable future depends on reducing the use of high altitude and steep slopes for grazing and cultivation, maintaining engineered flood defences and terraces, and anticipating the behaviour of the summer monsoon. This article is based on a keynote address delivered by John Dearing at the 10th International Paleolimnology Symposium, June 2006, Duluth, Minnesota, USA.     

Effect of seasonality on oxidative stress responses and metal accumulation in soft tissues of Aulacomya atra,a mussel from the South Atlantic Patagonian coast

This study investigated the effects of pollution and its interaction with temperature on the oxidative status of the ribbed mussel Aulacomya atra in the southern Atlantic Patagonian coast. Animals were collected from four sites with different degree and type of human activity impact, during the summer and winter of 2011. Seawater chromium, copper, manganese, nickel and zinc concentrations were measured, as well as metal accumulation, lipid peroxidation, protein oxidation, reduced glutathione levels, and enzymatic activities of superoxide dismutase and glutathione-S-transferase in gills and digestive glands.Metal bioaccumulation and oxidative stress responses in both tissues were generally higher in mussels from harbor areas. Water temperature had a remarkable effect on gill SOD activity and protein oxidation during winter in mussels from all locations.Methodologically, we conclude that measuring both metal bioaccumulation and oxidative stress responses allowed for a more accurate assessment of the biological effects of metal present in seawater.     

Chronology of mercury enrichment factors in reef corals from western Venezuela

Mining and deforestation in the early 20th century, the development of petrochemical industries during the 1950s, and the constant weathering of natural deposits of cinabrium (HgS) have made Golfo Triste, Venezuela, a region impacted by mercury (Hg). We studied the chronology of Hg in coral skeletons of Siderastrea siderea (1 colony, 1900-1996) and Montastraea faveolata (2 colonies, 1930-1999) from Parque Nacional San Esteban. Maximum values of Hg/Ca ratios and standard deviations of Hg enrichment factors occurred in the 1940s, 1960s, and 1980s, and matched maxima of decadal rainfall. Values from the 1950s and 1970s matched periods of abundant but constantly decreasing rainfall and hence were best explained by the combination of runoff and the sudden bioavailability of Hg in the region. This sudden availability likely was associated with activities of the chlorine-caustic soda and fertilizer plants of Morón petrochemical complex, industries that started producing large amounts of Hg in 1958.     

The metabolic and fitness costs associated with metal resistance in Nereis diversicolor

The population of Nereis diversicolor inhabiting the upper reaches of Restronguet Creek, Cornwall, UK is highly resistant to acute zinc and copper toxicity. Here we employ bioenergetic accounting and fecundity counts to demonstrate the energetic costs associated with this phenomenon in terms of the worms’ allocation of metabolic resources and reproductive output [P_r]. Metal-resistant animals exhibited a scope for growth that was 46-62% less than that of animals from two non-resistant reference populations, corresponding to a mean metabolic cost of 1.31 mJ h⁻¹ mg DW⁻¹. The resistant population also contained 13% less lipid than animals from the reference populations and 73-81% less carbohydrates. Consequently, mass-specific fecundity was reduced in resistant animals by 39-45%, although material investment in individual gametes did not appear to vary. This demonstrates fitness costs associated with metal resistance in this ecologically important polychaete and adds to our understanding of phenotypic trade-offs associated with resistance.     

The sandhopper Talitrus saltator (Crustacea: Amphipoda) as a biomonitor of trace metal bioavailabilities in European coastal waters

The amphipod crustacean Talitrus saltator is an established, easily accessible, biomonitor of trace metal bioavailabilities in coastal waters. We have carried out a geographically widespread collection of T. saltator from European shores, stretching from the north-west Atlantic through the Baltic to the Mediterranean. A primary aim of the work was to establish a database of accumulated trace metal concentrations (Cd, Cr, Cu, Fe, Mn and Zn) in this biomonitor. Statistical analysis has shown significant geographical differences in the bioavailabilities of all the metals, the most distinct being copper, iron and manganese. It has proved possible to identify unusually high accumulated concentrations of Cd, Cr, Cu, Fe, Mn and Zn in this biomonitor, indicative of high metal bioavailability at a particular site. These may serve as reference points for future biomonitoring programmes seeking to identify metal contamination in coastal waters.     

柱状成层地层中仪器偏心对阵列感应测井响应的影响

采用柱状成层介质的并矢Green函数高效计算井眼中偏心发射源产生的电磁波,并利用该算法模拟了阵列感应测井仪器在井眼中偏心时的响应.在模拟时既考虑到了金属心轴的存在也考虑到了线圈系所处绝缘层的存在,并重点分析了绝缘层的影响.数值模拟结果表明,对相对低泥浆电导率情况而言,无论线圈距长短,线圈系所处绝缘层对仪器响应的影响均较小,可忽略不计.而对于相对高泥浆电导率情况,线圈系所处绝缘层对仪器响应的影响明显,不可忽略,且线圈距越短影响越大,仪器偏心距越大影响越大.另由数值模拟结果可以看出,在相同泥浆电导率情况下,仪器线圈距越短偏心对线圈系响应的影响越大.     

Changes in metal contamination levels in estuarine sediments around India – An assessment

This review is the first attempt to comprehend the changes in metal contamination levels in surface estuarine sediments with changing time around India. Contamination factor, geoaccumulation index, pollution load index, effects range low and effects range median analysis were used to evaluate the quality of the estuarine sediments (by using the available literature data). This study suggests that estuarine sediments from the east coast of India were comparatively less contaminated by metals than the west coast. Sediments from those estuaries were found to be more contaminated by metals on which major cities are located. An improvement in estuarine sediment quality (in terms of metal contamination) over time around India was noticed. This study provides managers and decision-makers of environmental protection agency with a better scientific understanding for decision-making in controlling metal pollution in estuarine sediments around India.     

Comparison of metal accumulation in the azooxanthellate scleractinian coral (Tubastraea coccinea) from different polluted environments

The response of metal accumulation in coral Tubastraea coccinea to various degrees of metal enrichment was investigated from the Yin-Yang Sea (YYS) receiving abandoned mining effluents, the Kueishan Islet (KI) hydrothermal vent field, and the nearshore area of remoted Green Island (GI). The concentrations of most dissolved metals were highest in seawater at YYS, followed by KI, and then GI, showing the effects of anthropogenic and venting inputs on metal levels. Five metals (Co, Fe, Mn, Ni, and Zn) yielded significant differences (p < 0.05) among the skeleton samples. We identified similar patterns in the metal–Ca ratios, indicating that the elevated metals in skeletons was a consequence of external inputs. The coral tissues were relatively sensitive in monitoring metal accumulation, showing significant differences among three locations for Cd, Co, Cu, Fe, Pb, Ni, and Zn. Specific bioconcentration factors provided strong support for the differential metal accumulation in skeletons and tissues.     

Reactive-transport modeling of fly ash–water–brines interactions from laboratory-scale column studies

Dynamic leaching tests are important studies that provide more insights into time-dependent leaching mechanisms of any given solid waste. Hydrogeochemical modeling using PHREEQC was applied for column modeling of two ash recipes and brines generated from South African coal utility plants, Sasol and Eskom. The modeling results were part of a larger ash–brine study aimed at acquiring knowledge on (i) quantification and characterization of the products formed when ash is in contact with water–brines in different scenarios, (ii) the mineralogical changes associated with water–brine–ash interactions over time, (iii) species concentration, and (iv) leaching and transport controlling factors. The column modeling was successfully identified and quantified as important reactive mineralogical phases controlling major, minor and trace elements’ release. The pH of the solution was found to be a very important controlling factor in leaching chemistry. The highest mineralogical transformation took place in the first 10 days of ash contact with either water or brines, and within 0.1 m from the column inflow. Many of the major and trace elements Ca, Mg, Na, K, Sr, S(VI), Fe, are leached easily into water systems and their concentration fronts were high at the beginning (within 0.1 m from the column inflow and within the first 10 days) upon contact with the liquid phase. However, their concentration decreased with time until a steady state was reached. Modeling results also revealed that geochemical reactions taking place during ash–water–brine interactions does affect the porosity of the ash, whereas the leaching processes lead to increased porosity. Besides supporting experimental data, modeling results gave predictive insights on leaching of elements which may directly impact on the environment, particularly ground water. These predictions will help develop scenarios and offer potential guide for future sustainable waste management practices as a way of addressing the co-disposal of brines within inland ash dams and heaps.