全球流体通道网

新近取得的深反射与全球地震层析成像资料,为地球内部结构和流体通道的研究提供了一些依据．通过研究这些地震资料,可以了解地球内部物质分布状态的几何模式．综合研究表明,地球内存在流体通道网,它连通地球外核、中幔圈、软流圈和岩石圈,是固体地球系统的重要组成部分．这种通道网络象“动脉”那样把地球外核中的流体和热量向外传送,但与热羽说不同的是,不见得有对应的“静脉”存在以保持地幔质量平衡．固体地球作为多层次多要素的巨型复杂系统,其动力学过程要用浑沌理论去解释．研究地球流体活动的轨迹和吸引子,将有助于深入了解地球活动的规律性．     

倾角导向体控制的气烟囱识别技术及其在海拉尔盆地贝尔凹陷中的应用

在调研了国内外气烟囱研究成果与思路的基础上,通过全新的地震解决方案——OpendTect平台提供的基于属性多层感知器(MLP)的人工神经网络(ANN)的方法预测气烟囱的发生概率体,并利用倾角导向体对算法进行改进,提出倾角控制下的地震气烟囱识别技术,很好地补充并发展了模式识别技术在地震勘探领域的应用。通常该技术一方面可以解释运移通道和浅层气成藏的原因;另一方面,形成的气烟囱地震数据体还可以预测源岩的发育情况;此外,对于判别断层封闭性也非常适用。最后应用这一技术对海拉尔盆地贝尔凹陷一含油区块的运移通道和成藏规律进行研究,分析该研究区的断裂发育特征和运移通道类型,总结了油源、通道、储层和盖层的空间配置关系,并建立相应的成藏模式。     

Gas-Phase Formation of Water-Soluble Organic Compounds in the Atmosphere: A Retrosynthetic Analysis

Atmospheric particles contain a myriad of organiccompounds, including many multifunctional,water-soluble organic compounds. Many of thesecompounds are postulated to be secondary of origin. This work investigates the possible precursors ofseveral classes of multifunctional, water-solublesecondary organic compounds by analyzing the pathwaysleading to their formation, based on known gas-phasereactions. The analysis is termed `retrosynthetic'due to the backward direction of the analysis, fromproducts to precursors. Pathways for multi-functionalcompounds were generated combinatorially, consideringthe formation of one functional group at a time.Many multifunctional organic compounds with carboxylicacid, carbonyl, and hydroxy functional groups werefound to be first- or second-generation products ofcommon anthropogenic and biogenic volatile organiccompounds such as alkanes, alkenes, aromatics, andcyclic alkenes. The estimated yields of water-solubleorganic compounds from primary precursors ranged fromless than 1% to over 10%, based on stoichiometricconsiderations. The SOA formation index, whichcombines the concepts of yields and rates, was used tocompare the feasibility of the retrosyntheticpathways. Many of the candidate pathways involve theisomerization reaction of alkoxy radicals andoxygenated intermediate products such asmonocarboxylic acids and hydroxyaldehydes.     

柴达木盆地三湖地区第四系生物气的形成途径与运聚方式

柴达木盆地三湖(台吉乃尔湖、涩聂湖、达布逊湖)地区第四系生物气区是我国最大的生物气区。笔者系统采集了该气区21个天然气样品,测量了其组分和碳同位素组成,重点探讨了生物气形成途径和运聚方式。生物气δ~(13)C_1和δ~(13)C_(CO_2)均随深度增大而变重,显示了CO_2还原途径成气的特征。生物气δ~(13)C_1、δ~(13)C_(CO_2)和δD分布与CO_2还原方式形成的生物气的相应同位素值分布范围接近。在有关成因图解中这些数据主要位于CO_2还原途径成气范围内。生物气CO_2和CH_4之间的碳同位素分馏系数α_c>1.055,具有CO_2还原途径成气的特征。柴达木盆地第四纪干旱的古气候、较低的古温度、较高的沉积速率和水体中较高的硫酸盐含量使得甲烷菌的大量繁殖只能在较大的深度范围内才能实现,从而,有利于CO_2还原途径成气作用进行。涩北一号、涩北二号气田生物气δ~(13)C_1组成分布可能表明,生物气形成以后沿疏导层水平运移进入气藏,基本不存在垂向运移。该项研究对于进一步深入探讨生物气成因、形成条件,确定生物气模拟实验方式与条件,计算生物气资源量,建立成藏模式和选择天然气有利勘探区块均具有重要价值。     

库车褶皱冲断带天然气成藏体系及有效运移优势通道

库车褶皱冲断带天然气成藏体系由侏罗系煤系烃源岩、侧断坡断层输导体系和侧断坡相关背斜构造圈闭构成.相对于走滑断层而言, 侧断坡断层是有效的天然气运移优势通道.研究表明, 侏罗系煤系生成的天然气通过侧断坡断层向上运移到白垩系巴什基奇克组侧断坡相关背斜的砂岩储集层聚集成藏, 异常压力的幕式泄压可能是油气运移的主要方式.克拉2、迪那2、迪那1和吐孜1等气田的发现是库车褶皱冲断带天然气成藏体系的有效体现.侧断坡相关背斜是库车褶皱冲断带天然气勘探的新领域.      

Origin of Oils in “Subtle pools” in the Dongying Depression, Bohai Bay Basin, China

Subtle traps or oil pools have become an important exploration play in the Dongying Depression, Bohai Bay Basin, east China. Despite recent successes in exploration, the formation mechanisms of subtle traps are still not well understood. The majority of subtle oil pools in the Dongying Depression are developed in the middle interval of the Es3 Member of the Paleogene Shahejie Formation with the subtle traps being primarily of lenticular basin-floor turbidite sands encompassed in mudstones. Oil in the subtle traps was previously thought to have migrated directly from the surrounding source rocks of the same formation （Es3）. Detailed geochemical investigation of 41 oils and 41 rock samples from the depression now indicates that the oils from the subtle traps cannot be correlated well with the surrounding Es3 source rocks, which are characterized by high Pr/ Ph （〉1）, low Gammacerane/C30hopane, representing a freshwater lacustrine setting. In contrast the oils features low Pr/Ph （〈1） and relatively high Gammacerane content, showing a genetic affinity with the underlying Es4 source rocks, which also have the same qualities, indicating a brackish lacustrine setting. Oils in the Es3 subtle traps are probably derived from mixed sources with the contribution from the upper Es4 source rocks predominating. Therefore unconventional oil migration and accumulation mechanisms need to be invoked to explain the pooling of oils from the ES4 source rocks, which probably came through a thick low interval of the Es3 source rocks with no apparent structural or stratigraphic pathways. We suggest that the subtle oil migration pathway probably plays an important role here. This finding may have significant implications for future exploration and the remaining resource evaluation in the Dongying Depression.     

油气成藏机理研究进展和前沿研究领域

随着地质工作者刻划和认识地下地质体构成、结构的能力及研究和预测沉积盆地能量场（温度场、压力场和应力场）及其演化能力的不断提高，以流体流动和油气运移为核心的油气成藏机理研究取得了重要进展：（1）证实了油气的优势通道运移并妆步提示了优势运移通道的微观和宏观控制机制，从而使基于油气运移路径三维预测的油气藏定位预测成为可能；（2）证实了幕式快速成藏过程并初步揭示了幕式成藏的驱动机制、有利场所和地球化学识别标志，突破了油气成藏是一个缓慢渗流过程的传统模式；（3）深盆气勘探和成藏机理研究取得了进展，从而突破了背斜成藏的传统观念，使“向斜”（盆地凹陷区）成为一些盆地寻找大型天然气藏的重要场所。沉积盆地深层油气成藏过程和保存条件、活动构造背景下油气晚期快速成藏过程是油气成藏机理研究的重要前沿研究领域。     

夏季亚洲季风区对流层向平流层输送的源区、路径及其时间尺度的模拟研究

基于NCEP/NCAR分析资料和拉格朗日轨迹输送模式FLEXPART, 通过气块轨迹计算, 对2005年夏季亚洲季风区对流层向平流层输送 (Troposphere to Stratosphere Transport, 简称TST) 的近地层源区、 输送路径及其时间尺度问题进行了一些初步探讨。结果表明: (1) 夏季亚洲季风区TST两个主要的边界层源区, 一个是热带西太平洋地区; 另一个是青藏高原南部、 孟加拉湾以及印度半岛中北部等地区, 上述两个区域与夏季强对流的分布相一致。在对流层顶高度附近 (约16 km高度), 两个近地层源区的垂直输送贡献相当。但进一步分析发现, 穿越对流层顶高度的质量输送只有约10％能够进入20～22 km高度的平流层中, 且主要源于以青藏高原南侧为代表的南亚季风区 (约贡献75%), 这进一步强调了青藏高原及其周边区域在全球TST过程中的重要地位。 (2) 轨迹分析显示, 夏季亚洲季风区对流层进入平流层的 “入口区” 主要在 (25°N～35°N, 90°E～110°E) 区域的青藏高原及其周边区域。TST路径受对流层上层南亚高压闭合环流、 北半球副热带西风急流和赤道东风急流的共同控制。 (3) 亚洲季风区TST两个主要的过程, 一个是和夏季湿对流抬升直接联系的快速输送过程, 它可以使近地层大气在1～2天内输送到平流层中, 贡献了整个TST的10%～30%; 另一个是大气辐射加热所致的大尺度垂直输送, 该输送是一个相对的慢过程, 时间尺度一般为5～30天。此结果意味着, 源于地表的短生命周期的大气污染物可通过光化学反应过程对该区域平流层臭氧及其他大气痕量成分平衡产生重要影响。     

Remote effects of tropical cyclone wind forcing over the western Pacific on the eastern equatorial ocean

An ocean general circulation model （OGCM） is used to demonstrate remote effects of tropical cyclone wind （TCW） forcing in the tropical Pacific. The signature of TCW forcing is explicitly extracted using a locally weighted quadratic least=squares regression （called as LOESS） method from six-hour satellite surface wind data; the extracted TCW component can then be additionally taken into account or not in ocean modeling, allowing isolation of its effects on the ocean in a clean and clear way. In this paper, seasonally varying TCW fields in year 2008 are extracted from satellite data which are prescribed as a repeated annual cycle over the western Pacific regions off the equator （poleward of 10°N/S）; two long-term OGCM experiments are performed and compared, one with the TCW forcing part included additionally and the other not. Large, persistent thermal perturbations （cooling in the mixed layer （ML） and warming in the thermocline） are induced locally in the western tropical Pacific, which are seen to spread with the mean ocean circulation pathways around the tropical basin. In particular, a remote ocean response emerges in the eastern equatorial Pacific to the prescribed off-equatorial TCW forcing, characterized by a cooling in the mixed layer and a warming in the thermocline. Heat budget analyses indicate that the vertical mixing is a dominant process responsible for the SST cooling in the eastern equatorial Pacific. Further studies are clearly needed to demonstrate the significance of these results in a coupled ocean-atmosphere modeling context.     

Study on Ozone Change over the Tibetan Plateau

This paper reviewed the main results with respect to the discovery of low center of total column ozone (TCO) over the Tibetan Plateau (TP) in summer, and its formation mechanism. Some important advances are summarized as follows: The fact is discovered that there is a TCO low center over the TP in summer, and the features of the background circulation over the TP are analyzed; it is confirmed that the TP is a pathway of mass exchange between the troposphere and stratosphere, and it influences the TCO low center over the TP in summer; models reproduce the TCO low center over the TP in summer, and the formation mechanism is explored; in addition, the analyses and diagnoses of the observation data indicate that not only there is the TCO low center over the TP in summer, but also TCO decrease trend over the TP is one of the strong centers of TCO decrease trend in the same latitude; finally, the model predicts the future TCO change over the TP.