用于多接收器等离子体质谱铜铁锌同位素测定的离子交换分离方法

采用AGMP-1阴离子交换树脂，分别以7mol／L HCl、2mol／L HCl、0．5mol／L HNO3作为淋洗剂，可有效分离Cu、Fe、Zn。介绍了方法的基本原理、化学分离过程及混合标准溶液与地质标样的分离结果。结果表明，Cu、Fe、Zn回收率均接近100％，标准溶液在离子交换分离前后同位素组成一致，可以满足多接收器等离子体质谱对Cu、Fe、Zn同位素高精度分析的要求。     

电感耦合等离子体发射光谱法测定键合用硅铝丝中硅铁铜

采用电感耦合等离子体发射光谱法测定硅铝丝（Al—1％Si）中Si及杂质元素Fe和Cu。确定了最少取样量和样品溶解方法，优化了元素分析谱线和仪器的测量条件。实验表明，方法的加标回收率为99％～1叭％，相对标准偏差（n=6）低于1．4％，Si、Fe、Cu的检出限分别为8．5、1．0和0．4μg／L。该方法应用于快速测定键合硅铝丝中的各种元素，结果满意。     

北京市老城区雨洪控制与利用示范工程运行中的水质研究

以北京市老城区雨洪控制与利用示范工程为背景．对天然降雨、不同下垫面雨水径流、示范工程处理过程雨水径流以及地下水水质进行分析研究,通过示范工程对雨洪的处理利用效果,探讨雨水回灌至地下能否对地下水环境产生负面影响。     

地下水源热泵的水文地质设计

地下水源热泵是一种国内外正在迅速推广的新型节能环保型空调技术,但如果设计和运行管理不合理,会造成水资源的耗损和地质环境的破坏,因此需要加强其水文地质设计。地下水源热泵的水文地质设计包括水力学设计、热力学设计和地质环境保护设计。水力学设计的重点是维持地下水回灌能力,热力学设计的重点是防止回灌井导致的地下水过热和过冷,地质环境保护设计重点是防止水资源浪费和地下水污染。算例分析表明,抽灌井距的确定需要把水力学设计与热力学设计结合起来进行。     

微地震监测技术在秦家屯地区的应用

详细阐述了微地震注水前缘监测的原理。应用微地震注水前缘监测系统,通过微地震信息的现场监测和解释,结合生产动态及其他监测资料综合分析,并以秦家屯地区的QK 3-5井为例,描述了秦家屯地区注水开发状态下水井水驱前缘位置,研究了地下油水运动规律,证明了方法的可靠性和实用性。结果表明,对于油田注水分析与研究微地震监测技术可以取得很好的效果。     

利用水源热泵开采浅层地热能若干问题的探讨

地下水源热泵采能技术作为一种浅层低温地热能的可持续开发方式,在我国推广应用已有近十年的时间。尽管推广时间不长,但发展速度非常之快,尤其是近3～5年。由于多方面的原因,我国部分地下水源热泵采能工程逐渐暴露出一些问题,需要给予足够的重视。本文介绍了地下水源热泵采能系统的运行模式及特点,简要地对国内外热泵采能技术的应用现状进行了综述,并对该项技术在我国推广应用过程中存在的一些问题,进行了一定的分析和讨论。     

Analytical perspective on trace element species of interest in exploration

Analysis of soil and sediment samples, using selective extraction methods to distinguish different phases, is of particular interest in exploration geochemistry to locate deeply buried mineral deposits. There are various mechanisms of binding labile elements in the secondary environment, including physical and chemical sorption, precipitation, chelation and complexation. Phases present in soils and sediments which are likely to scavenge ‘free' elements include amorphous Mn and Fe oxides, the humic and fulvic components of humus, and clays. This paper reviews these forms of trace elements and the methods in current use to quantify them. Examples of precision data, both for control and survey samples, are given with respect to trace elements dissolved from the ‘soluble organic' component of humus, Mn oxides and amorphous Fe oxides. The high sensitivity of inductively coupled plasma mass spectrometry (ICP–MS) is required to measure accurately and precisely a large suite of trace elements, especially where only small fractions of elements are dissolved by such leaches as the commercially available Enzyme and MMI (Mobile Metal Ion) extractions. The relative standard deviations (RSD) obtained for 33 elements (e.g. Ag, Cd, In, I) in the standard reference sample (SRM), TILL-2, are in the range 0.5–8% for the hydroxylamine hydrochloride (NH₂OH·HCl) leach designed to extract hydrous Fe and Mn oxides. The corresponding RSDs for elements in the reactive Mn oxide phase extracted by the Enzyme leach are in the range 3–19% except for some trace elements at levels close to detection limit (e.g. Cd, Bi). The RSDs obtained for field duplicates are inferior to those for analytical replicates (i.e. sample splits), probably a reflection of different concentrations of the host phase. In one soil survey, the Fe extracted by a 0.25 M NH₂OH·HCl leach ranged conservatively from 0.2 to 1.7% whereas the Mn extracted by the Enzyme leach varied extensively, from 0.3 to >999 ppm. In contrast, precision, at 1–7% RSD, for field duplicates was found to be comparable with that for both analytical duplicates and the SRM, LKSD-4, for elements associated with the humic and fulvic component of humus samples sieved to <177 μm.     

Observations of the upper frequency cutoffs of the auroral kilometric radiation

Intense auroral kilometric radiation (AKR) is being frequently observed with POLRAD from the Auroral Probe (Interball-2). Observations of the abrupt upper frequency cutoffs (UFCs) in the spectra of AKR are reported. The UFCs can be observed at a frequency range from 300 to 700 kHz, corresponding to AKR generation altitudes from approximately 4800 to 2100 km, and are distributed in magnetic local time (MLT) hours similarly to the AKR events, with a maximum at 1 h MLT. The observed frequency extent of the UFCs is 12 kHz, and is often determined by the instrumental resolution (4 kHz). It is suggested that the UFC may be associated with an abrupt switching on of the generation mechanism, when the electron density becomes sufficiently low inside a plasma depletion at an altitude where the ratio of f_pe/f_ce crosses some threshold value. The steepness of the UFCs can imply a non-linear process of generation. The estimated distance of the e-folding field aligned wave amplification is between 3 and 8 km. The UFCs are sometimes, though very seldom (10%), accompanied by narrow band (less than 4 kHz) ridges of radiation observed at the cutoff frequency. They are smoothly drifting in frequncy for several minutes. The power density of radiation in the ridge can be up to 2 orders of magnitude stronger than in the accompanying wide band emission of AKR. The ridge at UFC can imply either energy concentration at the source bottom, or focusing, if specific conditions for the escape of the radiation are assumed.     

Measurements of the direction of the solar wind using interplanetary scintillation

EISCAT observations of the interplanetary scintillation of a single source were made over an extended period of time, during which the orientation of the baselines between the two observing sites changed significantly. Assuming that maximum correlation between the scintillations observed at the two sites occurs when the projected baseline is parallel to the direction of plasma flow, this technique can be used to make a unique determination of the direction of the solar wind. In the past it has usually been assumed that the plasma flow is radial, but measurements of eleven sources using this technique have indicated conclusively that in at least six cases observed at mid or high heliocentric latitude there is a significant non-radial component directed in four cases towards the heliocentric equator and in two cases towards the pole.     

Velocity of auroral arcs drifting equatorward from the polar cap

The drift velocity of an auroral arc is compared with the component of F-region plasma velocity in the same direction for ten cases where the arc is seen to move steadily equatorward for several minutes without any major change in appearance or orientation. In most cases the two velocities are close, but on two occasions the drift velocity of the arc is much higher than the plasma velocity. From the cases studied it appears that during the growth and recovery phase of the substorm cycle the arc moves with a velocity close to the convection velocity, but during the expansion phase this is not the case.