高表面活性矿物对Zn~(2+)的吸附机理及其环境意义

本文利用高表面活性矿物蒙脱石、蛭石、沸石在一定的介质条件下对Zn2 +进行吸附实验研究。蒙脱石和蛭石对Zn2 +的等温吸附线呈双“S”型 ,而沸石对Zn2 +的等温吸附线则呈“Langmuir”型。三种矿物对Zn2 +的吸附容量大小顺序为 :蒙脱石 >蛭石 >沸石。运用粉晶X射线衍射、红外光谱、差热及热重分析等技术对矿物及矿物吸附Zn2 +后的结构特征进行了研究。结果表明 ,蒙脱石吸附锌后其层间域中吸附锌大量水解形成新的物相 ,而蛭石与沸石吸附锌后水解很少。这为利用高表面活性矿物控制和治理环境污染及其可循环利用提供了理论依据。     

东天山戈壁荒漠景观区地球化学勘查中某些工作方法的研究

通过东天山地区地球化学勘查中某些方法的试验,研究了一套适宜于戈壁荒漠景观中地球化学勘查的工作方法.（1）查明了盛行风对岩屑异常特征的影响程度;（2）推荐消除风成沙影响的合理采样粒级;（3）利用水溶态铜、金异常指示被运积物掩盖的铜、金矿体;（4）明确了荒漠区盐磐层不会阻碍在残积物覆盖区发现矿致岩屑异常和在运积物覆盖区发现后生晕.     

吉林六批叶沟金矿石及金矿物特征研究

六批叶沟金矿石属少硫化物类型,金属矿物主要是黄铁矿,脉石矿物以石英、绿泥石、长石、绢云母为主;矿石常具晶质结构、压碎结构、交代结构以及浸染状、角砾状、细脉网脉状等构造.金矿物以银金矿、含银自然金为主,其形态以不规则状、尖角粒状、角粒状等居多,以中-细粒者常见;嵌布状态以粒间金为主,其次是包裹金和裂隙金.自然金中除Ag含量较高外,尚含有少量的Fe、Ni、Co、Cu、S等杂质,其成色为769.4‰,属自然元素类金-银系列矿物.     

河南西峡-内乡琥珀矿床的初步研究

河南西峡-内乡琥珀矿床是我国琥珀市场上原料的重要产地。通过对该矿床的地层、岩相、古地理以及水动力条件等因素的分析研究，以及对琥珀矿体地质特征、琥珀物理性质及化学组成特征的研究，认为该琥珀矿床属于晚白垩世河流冲、洪积沉积矿床。     

金在地幔矿物中的赋存形式及其赋存介质转化的可能模式:以中国北方一些地幔橄榄岩包体为例

采集中国北方玄武岩中橄榄岩包体样品21件。测定了其中的主元素、微量元素、稀土元素(REE)和Au等的含量。橄榄岩包体中的Au含量与CaO含量的相关性表明,其中的Au可能主要赋存于单斜辉石中,反映Au含量可能与地幔演化及熔融程度有关;橄榄岩包体后期受地幔流体交代作用的影响,Au转而以硫化物形式存在,这一过程是在橄榄岩包体原有Au的物质基础上进行的。     

腾格里地区盐湖的盐类沉积特征

腾格里沙漠122个盐湖分为石盐、石盐-芒硝、石盐-白钠镁矾及芒硝(石膏)4种类型。盐湖含盐系厚度一般4～9m,总体呈现下部为含盐碎屑沉积,上部以盐类沉积为主,构成储卤层,卤水赋存其中,由湖岸至湖心储卤层厚度增长。含卤层理渐小,卤水含KCl渐高。盐湖中矿物主要为碳酸盐矿物,以芒硝、石膏为主的硫酸盐矿物、石盐以及粘土矿物。盐湖卤水以晶间卤水为主。许多卤水含K+大于2g/L。K+含量最高的红盐池,平均含量达19.14g/L。对钾矿而言,在盐湖分布相对集中地区,有一定的综合开发利用前景。     

X-ray diffraction investigation of native Si-Fe alloy minerals from Luobusha, Tibet

The origin of native Si-Fe alloy mineral is thought to be related with mantle and aerolite. The native Si-Fe alloy minerals from podiform chromites of the Luobusha ophiolite in the Yarlong Zangbo suture zone were examined by a new method for powder-like diffractograms of small single crystals, using an SMART APEX-CCD area-detector X-ray diffractometer. The powder diffraction pattern shows that the minerals are composed of FeSi, FeSi₂, β-FeSi₂ and native silicon. The association of these minerals suggests that the crystallization order of the mineral may be from early to late FeSi→FeSi₂→native silicon, accompanied by gradually increasing deoxidization. Translated from Acta Petrologica et Mineralogica, 2005, 24(5): 453–456 [译自: 岩石矿物学杂志]     

Fast approximate EM induction modeling of metallic and UXO targets using a permeable prism

The time-domain EM induction response of non-magnetic and magnetic targets can be approximated using a conductive permeable prism composed of six faces of conductive plates, each face being composed of a set of conductive ribbons. The effect of magnetic permeability is included by the use of two “apparent flux gathering” coefficients, and two “effective magnetic permeability” coefficients, in the axial and transverse directions. These four magnetic property coefficients are a function of physical properties and geometry of the target, but are independent of prism orientation relative to a transmitter. The approximation algorithm is computationally fast, allowing inversions for target parameters to be achieved in seconds. The model is tested on profiles acquired with a Geonics EM63 time-domain EM metal detector over a non-magnetic copper pipe target, and a steel artillery shell in horizontal and vertical orientations. Results show that this approximation to a permeable prism has a capability of fitting geometric, conductivity and magnetic parameters at both early and late sample times. The magnetic parameters show strong change from early to late times on the EMI decay curve, indicating that the magnetic properties of the target have non-linear characteristics. It is proposed that these magnetic parameters and the nature of their non-linearity may carry additional discrimination information for distinguishing between intact munitions and scrap in UXO studies.     

2D magnetic resonance tomography applied to karstic conduit imaging

Karstic conduits play a crucial role for water supply in many parts of the world. However, the imaging of such targets is generally a difficult task for most geophysical methods. Magnetic Resonance Sounding (MRS) is a geophysical method designed for imaging of water bearing structures. Initially, MRS was developed for characterizing horizontally stratified aquifers. However, when applying a 1D MRS measuring setup to the imaging of 2D–3D targets, the size of which may be much smaller than the loop, the accuracy and the lateral resolution may not be sufficient. We have studied the possibility of simultaneously processing several MRS aligned along a profile to perform a Magnetic Resonance Tomography (MRT). This work emphasizes the gain of resolution for 2D–3D imagery of MRT versus the interpolation of 1D inversion results of MRS along the same profile. Numerical modelling results show that the MRT response is sensitive to the size and location of the 2D target in the subsurface. Sensitivity studies reveal that by using the coincident transmitting/receiving (TX/RX) setup and shifting the loop around the anomaly area, the depth, section and position of a single karstic conduit with a size smaller than the MRS loop size can be resolved. The accuracy of the results depends on the noise level and signal level, the latter parameter being linked to the depth and volume of the karstic conduit and the water content in the limestone matrix. It was shown that when applying MRT to the localization of 2D anomalies such as karstic conduits, the inclination of the geomagnetic field, the orientation of the MRT profile and the angle of crossover of the conduit by the MRT profile must be taken into account. Otherwise additional errors in interpretation should be expected. A 2D inversion scheme was developed and tested. Both numerical and experimental results confirm the efficiency of the developed approach.