全球气候变暖背景下索马里急流变化的预估研究

索马里急流的变化对亚洲季风和气候变动具有重要的影响,未来索马里急流到底会如何演变？如何受全球变暖的影响？针对这个问题,文中利用IPCC第四次评估报告（IPCC AR4）的多个海气耦合模式的模拟结果,评估了多个模式在当前气候（20C3M）条件下对夏季低空索马里急流的模拟能力;预估模式在SRESA2排放情景下对21世纪（2010—2099）的索马里急流变化。研究结果表明,18个模式在现代气候条件下对索马里急流有较好的模拟能力;18个模式的集合平均结果预测夏季索马里低空急流在21世纪的变化过程是：初期（2010—2040）增强至减弱,中期（2050—2060）增加至最强,末期（2070—2090）减至最弱。与现代气候条件模拟结果相比,夏季索马里低空急流在未来气候变暖背景条件下是趋于减弱的过程,在21世纪末期最弱。研究还表明了夏季低空索马里急流的变化幅度与全球平均气温的变化幅度是一个非线性的关系,各模式对二者关系的描述存在不确定性,鉴于索马里急流对印度季风和东亚季风及中国气候的重要性,索马里急流的变化规律和未来演变是科学界特别需要深入研究的问题。     

Assessment of global meteorological,hydrological and agricultural drought under future warming based on CMIP6

在全球变暖背景下,分析和预测干旱的变化趋势和传播规律对于区域生态环境安全和灾害管理具有重要意义.本文基于第六次国际耦合模式比较计划(CMIP6),分析了SSP2-4.5和SSP5-8.5两种变暖情景下的气象(标准化降水指数SPI和标准化降水蒸发指数SPED,水文(标准化径流指数SRI)和农业(标准化土壤水分指数SSI)...     

全球增暖1.5/2℃下中国区域极端降水的风险变化及其影响因子

利用24个CMIP6全球气候模式的逐日降水模拟资料,基于广义极值分布(GEV)模型,研究了全球增暖1.5/2℃下我国20、50和100 a重现期极端降水的未来风险变化。可以发现,相对于历史时期(1995—2014年),全球升温1.5和2℃下极端降水发生概率风险空间分布相近,总体上呈现增加趋势,但额外增暖0.5℃将导致更高的风险。如50 a重现期极端降水,在增暖1.5/2℃下其重现期将分别变为17/14 a,极端降水将变得更加频繁。不同区域对气候变暖的响应存在区域差异,其中中国西部长江黄河中上游和青藏高原地区、中国东部长江黄河中下游及其以南地区,极端降水发生概率比达到3以上,局部更是达到5以上,为我国极端降水气候变化响应高敏感区域。进一步,基于概率分布函数从理论角度探讨了位置和尺度参数对发生概率风险的影响与贡献度量,并用于探讨极端降水气候平均态和变率变化对极端降水发生风险的影响,结果显示：位置和尺度参数的增量变化、风险变化率存在着显著的东西部差异,从而导致极端降水发生风险的影响因素存在差异。如中国西部尽管极端降水气候平均态和变率变化幅度不大,但因风险变化率较高,从而导致该区域的发生风险大...     

钛-氨三乙酸-对氯苯基荧光酮-CTMAB四元配合物的分光光度法研究

本文研究Ti(Ⅳ)-氨三乙酸(NTA)-对氯苯基荧光酮(p-ClPF)-CTMAB四元配合物的显色条件。结果表明,在pH5.8—6.6形成了摩尔比为Ti(Ⅳ):NTA:p-ClPF:CTMAB=1:1:3:3的四元配合物,借此反应测定钛,灵敏度高,其ε_(573nm)=2.1×10~5L·mol~(-1)·cm~(-1)。Ti(Ⅳ)浓度在0—1.4μg/10ml范围服从比耳定律。已用本法直接测定了岩矿和铝合金中的Ti,结果满意。     

6-硝基-2-苯并噻唑重氮氨基偶氮苯与铜的显色反应及其应用

在pH10～12的Na2B4O7-NaOH缓冲溶液中,TritonX-100表面活性剂存在下,6-硝基-2-苯并噻唑重氮氨基偶氮苯与铜发生显色反应,生成2∶1的深红色配合物。配合物的最大吸收峰位于535nm处,表观摩尔吸光系数1.42×105L·mol-1·cm-1。Cu2+的浓度在0～400μg/L符合比尔定律。用拟定方法测定铝合金及铜矿石样品中的微量铜,结果与原子吸收法结果相符,6次测定的RSD<3%。     

Silicate‐oxide mineral chemistry of mafic–ultramafic rocks as an indicator of the roots of an island arc: The Chilas Complex,Kohistan (Pakistan)

The Chilas Complex is a major lower crustal component of the Cretaceous Kohistan island arc and one of the largest exposed slices of arc magma chamber in the world. Covering more than 8000 km², it reaches a current tectonic width of around 40 km. It was emplaced at 85 Ma during rifting of the arc soon after the collision of the arc with the Karakoram plate. Over 85% of the Complex comprises homogeneous, olivine‐free gabbronorite and subordinate orthopyroxene–quartz diorite association (MGNA), which contains bodies of up to 30 km² of ultramafic–mafic–anorthositic association (UMAA) rocks. Primary cumulate textures, igneous layering, and sedimentary structures are well preserved in layered parts of the UMAA in spite of pervasive granulite facies metamorphism. Mineral analyses show that the UMAA is characterized by more magnesian and more aluminous pyroxene and more calcic plagioclase than those in the MGNA. High modal abundances of orthopyroxene, magnetite and ilmenite (in MGNA), general Mg–Fe–Al spatial variations, and an MFA plot of whole‐rock analyses suggest a calc‐alkaline origin for the Complex. Projection of the pyroxene compositions on the Wo–En–Fs face is akin to those of pyroxenes from island arcs gabbros. The presence of highly calcic plagioclase and hornblende in UMAA is indicative of hydrous parental arc magma. The complex may be a product of two‐stage partial melting of a rising mantle diaper. The MGNA rocks represent the earlier phase melting, whereas the UMAA magma resulted from the melting of the same source depleted by the extraction of the earlier melt phase. Some of the massive peridotites in the UMAA may either be cumulates or represent metasomatized and remobilized upper mantle. The Chilas Complex shows similarities with many other (supra)subduction‐related mafic–ultramafic complexes worldwide.     

High-resolution climate variability of southwest China during 57-70 ka reflected in a stalagmite δ18O record from Xinya Cave

A 26-cm-long stalagmite (XY2) from Xinya Cave in northeastern Chongqing of China has been ICP-MS ²³⁰Th/U dated, showing a depositional hiatus at 2.3 cm depth from the top. The growth of the 2.3–26 cm interval determined by four dates was between 57 ka and 70 ka, with a linear growth rate of 0.023 mm/a. We have analyzed 190 samples for δ ¹⁸O and δ ¹³C, mostly in the 2.3–26 cm part. The δ ¹⁸O and δ ¹³C values between 57 ka and 70 ka reveal decadal-to-centennial climatic variability during the glacial interval of Marine Isotope Stage 4 (MIS4), exhibiting much higher resolution than that of the published Hulu and Dongge records during this interval. Speleothem δ ¹⁸O in eastern China, including our study area can be used as a proxy of summer monsoon strength, with lighter values pointing to stronger summer monsoon and higher precipitation, and vice versa. Two decreases in the δ ¹⁸O signature of XY2 record around 59.5 and 64.5 Ka are argued to correspond to the Dansgaard-Oeschger (D-O) events 17 and 18 respectively. The Heinrich event 6 (H6) can be identified in the record as a heavy δ ¹⁸O peak around 60 ka, indicating significant weakening of the monsoon in Chongqing during the cold period. The XY2 δ ¹⁸O record shows very rapid change toward to the interstadial condition of the D-O event, but more gradual change toward to the cold stadial condition. This phenomenon found in the Greenland ice core records is rarely observed so clearly in previously published speleothem records. According to SPECMAP δ ¹⁸O record, the glacial maximum of MIS 4 was around 64.5 ka with the boundary of MIS 3/4 around 60 ka. Unlike the marine record, the speleothem record of XY2, China, exhibits much high frequency variations without an apparent glacial maximum during MIS 4. However, the timing of MIS 3/4 boundary seems to be around 60 ka when the H6 terminated, in agreement with the marine chronology. The growth period of sample XY2 during glacial times probably reflects a local karstic routing of water, rather than having climatic significance. Supported by the National Natural Science Foundation of China (Grant Nos. 40672165, 90511004, 40672202) and the Academician Special Project of Chongqing Science Committee (Grant No. 2003-7835)     

地震信号内插与噪音剔除（一）

信号内插与噪音剔除是相互有着有机联系的两个方面。首先讨论地震信号的内插方法,提出了一种“最佳内插算子”,从而导出了另一种“检噪算子”,它可以有效地把干扰波从记录中识别出来,并将其“剔除”出去。进而讨论空间域数据的内插问题--道内插问题。在一定的条件下,空间域数据内插与时间域内插是完全等效的,因此道内插也可以采用与时间域相同的“最佳内插算子”。地震记录上的干扰波其绝大部分表现为空间域的脉冲式干扰,所以用“检噪算子”在空间域作褶积,便能识别干扰,从而对干扰加以剔除。本文解决了一种迭代的剔除方法,取得了好的效果。     

Seismicity anomalies before the great earthquake of M_S=8.1 in the Kunlun Pass and its significance to earthquake prediction

Introduction The MS=8.1 earthquake occurred in west of the Kunlun Pass on November 14, 2001. It is the greatest earthquake occurred in China since the last half of the century and is an important event in recent seismic history of China. Some specialists consider that the earthquake occurred in the area where the earthquake monitoring capability is lowest in Chinese mainland; no striking precursory seismicity was found. The study on the precursory seismicity before the earthquake has not b…     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.