Solutions of the linearized geodetic boundary value problem for an ellipsoidal boundary to order e 3

The geodetic boundary value problem (GBVP) was originally formulated for the topographic surface of the Earth. It degenerates to an ellipsoidal problem, for example when topographic and downward continuation reductions have been applied. Although these ellipsoidal GBVPs possess a simpler structure than the original ones, they cannot be solved analytically, since the boundary condition still contains disturbing terms due to anisotropy, ellipticity and centrifugal components in the reference potential. Solutions of the so-called scalar-free version of the GBVP, upon which most recent practical calculations of geoidal and quasigeoidal heights are based, are considered. Starting at the linearized boundary condition and presupposing a normal field of Somigliana–Pizzetti type, the boundary condition described in spherical coordinates is expanded into a series with respect to the flattening f of the Earth. This series is truncated after the linear terms in f, and first-order solutions of the corresponding GBVP are developed in closed form on the basis of spherical integral formulae, modified by suitable reduction terms. Three alternative representations of the solution are discussed, implying corrections by adding a first-order non-spherical term to the solution, by reducing the boundary data, or by modifying the integration kernel. A numerically efficient procedure for the evaluation of ellipsoidal effects, in the case of the linearized scalar-free version of the GBVP, involving first-order ellipsoidal terms in the boundary condition, is derived, utilizing geopotential models such as EGM96.     

三溴偶氮胂—锇—溴酸钾催化光度法测定微量锇

在酸性介质中Ｏｓ（Ⅳ）对ＫＢｒＯ３氧化三溴偶氮胂的褪色反应有明显的催化作用，借此反应可在水相中直接测定微量锇。方法灵敏度高，锇的质量浓度为１０～２００μｇ／Ｌ时符合比尔定律，表观摩尔吸光系数为９１８×１０５Ｌ·ｍｏｌ－１·ｃｍ－１。方法已用于贵金属精矿中锇的测定     

我国首次发现的Cu6SnWS8矿

Ｃｕ６ＳｎＷＳ８矿是一种罕见矿物，在我国属首次发现，该矿物平均化学成分为：Ｃｕ４０．１９％，Ｓ ２６．２３％，Ｗ ２０．０２％，Ｓｎ １３．４９。本文就目前所获得的成果，介绍一下它的地质产状，伴生矿物及矿物的物理、化学特征。     

2,4-二溴-6-羧基苯基重氮氨基偶氮苯与银显色反应的研究

作者合成的新显色剂2,4-二溴-6-羧基苯基重氮氨基偶氮苯,在pH 11.0的Na_2B_4O_7-NaOH缓冲介质中,有非离子表面活性剂Triton X-100存在下,可与Ag(Ⅰ)生成稳定的2:1红色配合物,配合物的λ_(max)=552nm,表观摩尔吸光系数ε_(552)=1.05×10~5 L·mol~(-1)·cm~(-1)。Ag量在0～400ng/ml范围内符合比尔定律。方法用于测定废水及矿石中的痕量Ag,结果满意。     

东海盆地长江凹陷美人峰组的时代归属及其地质意义

东海盆地长江凹陷美人峰组是古近系重要的地层单元之一，但因其缺少精确的古生物化石记录，时代归属和区域地层对比关系长期悬而未决，尚无定论。本文应用LA- ICP- MS定年方法，对长江凹陷CJ- 2井所揭露的美人峰组顶部两套凝灰岩夹层进行了锆石U- Pb同位素测年。结果表明，来自美人峰组顶部两件凝灰岩样品分别形成于61. 0±0. 87 Ma和62. 25±0. 92 Ma，证明该组沉积时代归属于早古新世，区域上对应于丽水- 椒江凹陷下古新统月桂峰组。烃源岩评价结果显示，美人峰组发育较好的烃源岩，有机质丰度达到中等至好，有机质类型为Ⅲ型。基于地震剖面构造精细解析，长江凹陷的美人峰组可以连续追踪到浙东坳陷，该坳陷大规模发育古新统，残余厚度达800~2000 m，指示古新世，浙东坳陷发生大规模伸展裂陷，形成NNE向展布大型裂陷带，美人峰组将是一套潜在的烃源岩层系。首次在东海盆地长江凹陷美人峰组获得高精度年龄，不仅确定了美人峰组沉积时代归属，也为东海盆地古新世区域地层的划分与对比、盆地古地理重建、构造演化、油气勘探与资源评价等提供了新的地质依据。     

宁波ZK03井水温异常与昆仑山口西8.1级地震的关系

通过分析宁波台ZK03井的基本观测条件、所使用的仪器设备以及对其日均值、整点值的探讨，认为该井水温异常很可能与昆仑山口西8．1级地震有关系。从日均值图上看，异常出现在震前10天左右，最大异常量为正常速率的负20倍；从整点值图上看，震前10天开始在34个小时内测值下降了0．001℃，是正常速率的负18倍。异常出现原因可能是由于地震前的长周期波通过上地幔或软流层传播，间接地导致了地下流体温度发生了微小的变化。     

新疆巴楚-伽师6.8级地震序列及震情分析

2003年2月24日新疆巴楚—伽师发生6．8级地震，震中位于1997—1998年伽师9次6级地震分布区域的东南端。这次6．8级地震的余震呈北西向分布，与极震区长轴走向一致，截止2003年4月15日最大余震为5．8级。震源机制解初步分析结果为：震源断错属逆倾滑性质，近南北向的节面可能为主破裂面，主压应力P轴方位为北西西。6．8级地震发生在2003年度全国划定的6—7级地震危险区内。震前根据新疆震情的发展，新疆地震局预报中心在对2月份的震情判定中明确提出“2月或稍长时间新疆两个地震重点危险区有发生中强震的可能”，预测意见对应较好。     

Structure-configurational entropy and its effect on the thermodynamic stability of uranyl phases: With special application for geological disposal of nuclear waste

Uranyl phases are found as the alteration products of uraninite under oxidizing condi- tions[1—3]. They are also expected to be the dominant alteration products of spent UO2 fuel in an oxidizing environment, such as at nuclear waste repositories[4—8]. …     

Effects of the Herbicide Metazachlor on Phytoplankton and Periphyton Communities in Outdoor Mesocosms

The effects of the chloroacetanilide herbicide metazachlor have been investigated in outdoor artificial mesocosms. Decreasing phytoplankton densities were caused by the application, however, the communities recovered after 30 to 35 days. Periphyton growth was found to be affected not only by the herbicide application but by the presence of species with different ability to grow on artificial substrates. Zooplankton diversity was small due to low density of ingestible algae species. Oxygen saturation was found to be correlated with the dosage levels of the herbicide in the second half of the study.     

Different Behavior of Iron(III) and Aluminum(III) Salts To Coagulate Silica Particle Suspension

The different coagulation‐flocculation behavior of iron(III) and aluminum(III) to coagulate silica particle suspension with four coagulants — FeCl₃, Fe₂(SO₄)₃, AlCl₃, and in our laboratory produced polyaluminum chloride PACl‐2.0 — was investigated through studying particle property changes and coagulation efficiency, for example, variations in zeta potential of particles, particle number, average particle diameter, particle size distribution, and residual turbidity of the supernatant water. Influences of flocculation intensity and pH value on the coagulation‐flocculation process were also studied. The results suggest that, under the test conditions, among these four coagulants FeCl₃ possesses an obviously stronger ability to form larger flocs and to remove turbidity, on the other hand, PACl‐2.0 obviously showed a better charge neutralization ability.