沉积有机质激光热裂解色谱质谱探针分析技术的尝试及其前景探讨

激光热裂解－色谱－质谱分析方法具有从技术层面上融合分子地球化学方法和有机岩石学方法的潜能。通过抚顺煤镜质组分和树脂体的研究实例，介绍了激光热裂解－色谱－质谱探针分析的基本原理及测试方法。抚顺煤显微组分的微区热裂解产物特征中，镜质组和树脂体热解产物的正烷烃、烷基萘和四氢化萘的总体面貌相似，但树脂体中正烷烃含量较低，而烷基四氢化萘明显较高，这可能反映显微组分形成过程中发生过低分子烃类在各显微组分之间的混合作用。除此之外，还把激光热裂解－色谱－质谱探针技术与传统的分子地球化学方法、有机岩石学方法进行比较。探讨了激光热裂解－色谱－质谱探针技术的应用前景以及尚待解决的技术问题。落射到样品表面的激光束能量（温度）和控制和激光辐射时间的，激光束斑大小、热解产物量、色谱－质谱检验灵敏度极限三者关系等，都是限制新技术应用的技术问题。     

地幔流体及其成矿作用

高灵敏度、高精密度、低检出限、多元素同时检测并可提供同位素组成比值信息的等离子体质谱与高空间分辨率的紫外激光采样技术结合 ,可定量地测定单个流体包裹体中常、微量元素含量 ,为成矿流体的研究提供了一个新的研究手段。文中简要地介绍了激光剥蚀电感耦合等离子体质谱 (LA ICP MS)分析仪器的发展 ,结合实验室的研究工作 ,就激光剥蚀池的设计、单个流体包裹体的剥蚀方法、元素的分馏效率、定量校正技术及其在成矿成因物理化学机制研究中的应用等进行评述 ,并阐述单个流体包裹体元素组成的LA ICP MS分析技术存在的局限和发展趋势。     

Self‐purification in Upland and Lowland Streams

Ecological investigations at four streams in Saxony‐Anhalt have shown that there are considerable differences between the self‐purification power of upland and lowland streams. This result is reflected in chemistry and in microbiology. The structure of the bottom substrate mainly influences the degree of self‐purification in connection with rate of flow and flow velocity. The results and differences are demonstrated using the example of Katzsohlbach in the landscape unit “Mittel‐ and Unterharz” and the stream Olbe in the landscape unit “Magdeburger Börde”.     

Oxidation Experiment of Natural Megacrystal Clinopyroxene: Implications for Assignment of Mössbauer Spectra

The Mössbauer spectra of natural megacrystal clinopyroxene are usually fitted by 4 sets of symmetric doublets, A‐A', B‐B', C‐C' and D‐D', respectively, in terms of increasing Qs value in literature. But the assignments of those doublets are quite different, except the D‐D' doublet assigned to Fe³⁺at the lattice site M***1 in previous papers. Particularly, the assignment and interpretation of the C‐C' doublet are diverse. The oxidation experiments of natural megacrystal clinopyroxene collected from the Hannuoba basalt, North China, were performed under controlled conditions of temperature at 1000°C and oxygen fugacity of FMQ buffer in 1, 2, ***3 and 5 days respectively. The oxidized samples were then measured by X‐ray diffraction spectrometry and Mössbauer spectrometry. The oxidation of clinopyroxene is characterized by Fe²⁺ → Fe³⁺at M1 under the subsolidus conditions, which is consistent with the increase of the area of the D‐D' doublet when the heating time increases. Accordingly, the area of the A‐A' and B‐B' doublets decreases with the increasing heating time. However, the area of C‐C' keeps almost constant. Therefore, the 4 sets of doublets can be assigned correctly as follows: A‐A' doublet to Fe⁺²at M1, B‐B' Fe²⁺at M1, C‐C' Fe²⁺at M2, and D‐D' Fe³⁺at M1. The M1 site splitting is due to the NNN (Next Nearest Neighbour) effect of the M2 site. The amount of Fe³⁺at the tetrohedral site of megacrystal clinopyroxene is negligible according to this study.     

The use of sintered diamond anvils in the MA8 type high-pressure apparatus

A new multi-anvil type high-presure apparatus has been developed using sintered diamond anvils to generate pressures over 30 GPa and temperatures up to about 2000°C. A maximum sample volume of about 1 mm³ is available in this system. The pressure was confirmed by dissociation of forsterite into Mg-perovskite and periclase. The basic techniques and problems in utilizing sintered diamond in the MA8 type high-pressure apparatus are discussed with an emphasis on the future prospect of incorporating simultancous X-ray diffraction observation.     

2005年11月26日九江--瑞昌5.7级地震浅析

2005年11月26日,在江西省九江县与瑞昌市交界处发生5.7级地震,震源深度10km。宏观震中在九江县港口乡。震中烈度Ⅶ度,极震区为北东向的椭圆,烈度分布受瑞昌盆地内地形地貌条件的控制;5.7级地震的最大余震为ML5.3级,序列类型为主震—余震型,余震较丰富,余震区长轴为北西向。此次地震经历了较长期的应力应变积累过程,发生在江西分宜—黄海北部北东向ML≥4.0级地震活动带和湖北西部—江西南昌ML≥3.0级地震活动带的交汇部位,与大区域地震活动性中长期异常相关。     

利用IRS-P6卫星数据制作遥感影像地图

本文介绍了以IRS-P6卫星数据作为信息源完成大兴安岭林区的遥感影像地图制作的方法, 通过试验初步认识到:利用IRS-P6卫星数据制作遥感影像地图,可以满足1:50000、 1:25000比例尺的平面制图精度要求,在一些专业和专题应用中可以放大到1:15000比例尺使用。     

2005年10月8日巴基斯坦7.8级地震热红外异常

收集了2005年巴基斯坦7.8级地震区Noaa17/AVHRR的2004-2005年的热红外遥感资料,并进行地表温度反演,得到了以震中为中心7°×7°范围的地表温度值。经热红外图像解译与构造关系对比分析,表明热红外解译图像与构造分布具有一致性。震源区地表温度时间序列显示:震前大约3个月内震源区存在明显的热红外异常。     

Characteristics of the Variation of Cross Fault Short-Baseline and Short-Range Leveling in Western Yunnan Earthquake Test Site Before Lijiang M_S7.0 Earthquake

Results of analysis of variation of cross fault short-baseline and short-range leveling in Western Yunnan Earthquake Test Site (WYETS), results show that among five observation stations of cross fault short-baseline and short-range leveling in WYETS before the Lijiang MS7.0 Earthquake occurred in February 1996 only Yongsheng observation station (epicentral distance 82 km) located at Chenghai fault shows great variation about one year before the earthquake. And the nearest observation station, Lijiang (epicentral distance 42 km); presents great coseismic variation, but does not show obvious anomalous variation before the earthquake. There are no significant variations related to the earthquake at the other three observation stations. Two methods are used in analysis of the observed data and some valuable results have been obtained.