四种重金属对刺参幼参的急性致毒效应

采用静水试验法,在水温18.5℃~20℃的条件下,用Cu2 ,Zn2 ,Cd2 和Cr6 四种重金属对刺参幼参进行了单一急性毒性试验。结果表明:Cu2 对刺参幼参的24h,48h,72h和96hLC50分别为0.299,0.176,0.133和0.120mg/L;Zn2 的24h,48h,72h和96hLC50分别为6.700,3.624,2.577和1.951mg/L;Cd2 的24h,48h和72hLC50分别为4.246,2.588和2.137mg/L;Cr6 的24h,48h和72hLC50分别为31.974,7.499和3.808mg/L;Cu2 ,Zn2 ,Cd2 和Cr6 对刺参幼参的安全浓度分别为0.018,0.362,0.259和0.750mg/L。四种重金属对刺参幼参的毒性大小依次为Cu2 >Cd2 >Zn2 >Cr6 。     

陕西地洞河高分辨率石笋记录的DO18季风增强事件

千年尺度事件的结构特征和区域响应是理解和认识冰期气候变化及动力机制的关键。本文基于陕西汉中宁强县地洞河一支长417 mm石笋DDH1的11个U-Th年代和417个氧同位素（δ¹⁸O）数据,重建了末次冰期（64.8~33.2 ka B.P.）亚洲季风演化历史。石笋δ¹⁸O记录在64.7±0.2 ka B.P.和59.3±0.1 ka B.P.快速负偏,分别指示了DO18事件的开始和H6事件的结束。在DO18事件结束过程,石笋δ¹⁸O记录在64.0~60.4 ka B.P.持续正偏,振幅达2.9 ‰,反应季风逐渐减弱,但未出现明显转型阶段。其总体形态与大西洋Cariaco盆地岩芯反射率、南极冰芯的记录较为一致,但是不同于格陵兰冰芯的记录。因地洞河所处青藏高原、秦岭叠加影响的区域,纬度和地形的双重影响使得其石笋δ¹⁸O记录较其他地区偏负,振荡幅度更大。因地形阻挡了高纬信号,使得低纬甚至南半球的信号突现出来,ITCZ的移动、南半球温度和水汽潜热的释放作用在这一区域尤为显著。

     

基于CMIP6的西南暴雨洪涝灾害风险未来预估

为预估全球变暖背景下中国西南地区未来暴雨洪涝灾害风险的变化特征,研究挑选5个CMIP6模式和5个极端降水指数,结合地形因子、社会经济数据和耕地面积百分比,构建暴雨洪涝灾害风险评估模型,对西南暴雨洪涝灾害风险进行基准期(1995—2014年)评估、未来两个时期(2021—2040年,2041—2060年)3种情景(SSP1-2.6,SSP2-4.5,SSP5-8.5)下的预估和对比分析。结果表明：EC-Earth3, EC-Earth3-Veg两个单模式对5个极端降水指数的模拟效果较好,不等权重集合(UEWA-5)的效果整体优于等权重集合(EWA-5)。西南地区5个极端降水指数的高值区位于云南西部、广西东北部以及四川盆地西缘,社会脆弱性和辐射强迫越高,极端降水指数平均值和最大值越大; 从基准期到未来两个时期,5个极端降水指数均呈增大趋势。未来暴雨洪涝灾害的中高风险区和高风险区主要分布在四川成都市、重庆中心和四川盆地西部、云南昆明市、广西中南部和桂林市等局部较发达地区; 未来两个时期SSP2-4.5情景下的中高风险区和高风险区面积最大; 从基准期到未来远期,中高风险区和高风险区面积将随着时间增长而增加。     

物理过程参数化方案对中国夏季降水日变化模拟的影响

国际耦合模式比较计划第六阶段(CMIP6)新增的高分辨率模式比较计划(HighResMIP)首次提供全球高分辨率(25—50 km)多模式集合的气候模拟试验结果。利用8个CMIP6 HighResMIP模式评估了高分辨率全球气候模式对青藏高原夏季小时降水与极端降水的模拟能力,结果表明：CMIP6高分辨率模式高(低)估了青藏高原地区的降水量和频率(强度),过多的降水量主要来自模式对降水频率的高估,尤其是弱降水(< 2 mm·h^-1)的发生频率。模拟偏差与地形海拔密切相关,偏差大值区主要位于高原南坡和东坡陡峭地形区。模式不能准确再现降水量与海拔之间的关系,高(低)估了高(低)海拔地区的降水量。模式低估了降水强度随海拔升高而降低的变化速率。在日变化方面,模式能够模拟出青藏高原降水傍晚至午夜的峰值特征,但明显低估了降水的日变化振幅。在小时极端降水方面,模式低估了高原区域平均极端降水第95百分位数阈值,仅为观测值的57%。

     

川南观音场-瓦市地区须家河组六段储层特征及其控制因素

通过对4条野外剖面、40口并岩心样品及84张薄片的观察和测井等资料的分析,对川南观音场-瓦市地区须六段的岩石学特征、孔隙类型、孔隙结构及孔渗特征等进行了深入研究。结果表明:川南地区须六段岩性主要为中-细粒长石岩屑砂岩和岩屑石英砂岩,孔隙度在6%~10%之间,平均孔隙度为7.3%。渗透率为0.03×10^-3μm²~0.9×10^-3μm²,平均渗透率为0.177×10^-3μm²。储层属于典型的低孔低渗储层,储集空间主要为粒间孔和粒内溶孔。在平面上,储层物性受沉积相带的控制;在垂向上,随深度的增加,压实作用和胶结作用使物性急剧变差。绿泥石的环边胶结作用、长石的溶蚀作用对储层物性起建设性作用,构造作用极大地改善了储层的物性。     

麻黄山西区延长组长4+5至长6储层成岩作用及成岩演化史研究

麻黄山西区长4＋5至长6储层为一套三角洲前缘亚相的细砂岩,研究证明砂岩目前处于中成岩A期。机械压实与胶结作用是孔隙减少的主要作用,也是本区原生孔隙少、储集物性差的直接原因;而大气淡水的淋滤作用及有机酸溶蚀作用,尤其是有机酸溶蚀作用,是产生次生孔隙的主要作用,使局部储层物性有所改善,因此次生孔隙是本区油气的主要储集空间,下一步油气勘探开发应注重对有利次生孔隙空间的预测。     

华庆地区延长组长6油层组储集砂岩特征及对储层物性的影响

长6油层组储集砂岩主要为岩屑长石砂岩,粒度较细,分选中等偏差,填隙物主要为碳酸盐矿物和粘土矿物。砂岩的物质组成影响着其储层性能,储层物性随着石英含量的增加而变好,而随着岩屑含量的增加而变差。砂岩中长石的溶蚀作用是改善储层物性的关键因素。填隙物的含量越大,则孔隙喉道堵塞和充填的程度增加,导致储层物性变差。     

应用6σ质量管理方法尝试评价多目标样品氯等项目检测质量水平

应用6σ质量管理方法评价X射线荧光光谱法测定多目标地球化学样品分析中4个日常监控土壤标准物质中Cl、S、总碳、N、Na₂O、MgO、Al₂O₃、SiO₂、P、K₂O、CaO、Ba、Ti、V、Cr、Mn、TFe₂O₃、Zn、Ga、Br、Pb、Th、Rb、Sr、Y、Zr、Nb等27个项目检测质量水平。研究结果显示,随着高精度、自动化仪器的应用,多目标样品分析多个项目的精密度、准确度都得到大幅度的提高,部分检测项目的性能已经达到6σ质量水平;但有少数项目如N、总碳、Cr 等低于3σ质量水平,其精密度准确度均需改进,分析性能有待进一步提高,建议更换检测方法。用6σ质量管理方法评价地质实验分析测试质量水平与地质实验室传统质量控制方法得出的结果具有一致性,其评价方法简便、量化、直观、具有一定的应用价值。     

Vegetation history of the penultimate glacial period (Marine isotope stage 6) at Ioannina,north‐west Greece

The vegetational history of the penultimate glacial period, Marine Isotope Stage (MIS) 6 (c. 185–135 ka), has remained relatively unexplored. Here we present a new record from the Ioannina basin, north‐west Greece, which constitutes the highest‐resolution terrestrial pollen record for this interval produced to date. It shows that the vegetation history of MIS 6 in this region can be divided into two parts: an early period (185–155 ka) with pronounced oscillations in tree population extent, and a later period (155–135 ka) with much smaller tree populations and subdued oscillations. This pattern is analogous to the MIS 3/MIS 2 division during the last glacial in the same sequence, although the early part of MIS 6 had larger Pinus populations and fewer temperate trees relative to the equivalent interval in MIS 3. This implies cooler and wetter conditions, which is somewhat counterintuitive given the high summer insolation during MIS 6e, but is in line with other palaeoclimatic evidence from the Mediterranean. Comparison with North Atlantic records suggests that despite the absence of pronounced iceberg discharges during MIS 6, North Atlantic millennial‐scale variability had a significant downstream impact on tree populations in north‐west Greece. Copyright © 2011 John Wiley & Sons, Ltd.     

Iron isotopic systematics of UHP eclogites respond to oxidizing fluid during exhumation

The iron stable isotope compositions (δ⁵⁶Fe) and iron valence states of ultrahigh‐pressure eclogites from Bixiling in the Dabie orogen belt, China, were measured to trace the changes of geochemical conditions during vertical transportation of earth materials, for example, oxygen fugacity. The bulk Fe³⁺/ΣFe ratios of retrograde eclogites, determined by Mössbauer spectroscopy, are consistently higher than those of fresh eclogites, suggesting oxidation during retrograde metamorphism and fluid infiltration. The studied eclogites (five samples) display limited mid‐ocean ridge basalts (MORB)‐like (~0.10‰) δ⁵⁶Fe values, which are indistinguishable from their protoliths, that is, gabbro cumulates formed through differentiation of mantle‐derived basaltic magma. This suggests that Fe isotope fractionation during continental subduction is limited. Garnet separates display limited δ⁵⁶Fe variation ranging from ?0.08 ± 0.07 ‰ to 0.02 ± 0.07‰, whereas coexisting omphacite displays a large variation of δ⁵⁶Fe values from 0.15 ± 0.07‰ to 0.47 ± 0.07‰. Omphacite also has highly variable Fe³⁺/ΣFe ratios from 0.367 ± 0.025 to 0.598 ± 0.024, indicating modification after peak metamorphism. Omphacite from retrograde eclogites has elevated Fe³⁺/ΣFe ratios (0.54–0.60) compared to that from fresh eclogites (~0.37), whereas garnet displays a narrow range of ferric iron content with Fe³⁺/ΣFe ratios from 0.039 ± 0.013 to 0.065 ± 0.022. The homogenous δ⁵⁶Fe values and Fe³⁺/ΣFe ratios of garnet suggest that it survived the retrograde metamorphism and preserved its Fe‐isotopic features and ferric contents of peak metamorphism. Because of similar diffusion rates of Fe and Mg in garnet and omphacite, and constant Δ²⁶Mg_{omphacite‐garnet} values (1.14 ± 0.04‰), equilibrium iron isotope fractionation between garnet and omphacite was probably achieved during peak metamorphism. Elevated Fe³⁺/ΣFe ratios of omphacite from retrograde eclogites and variant Δ⁵⁶Fe_{omphacite‐garnet} values of the studied eclogites (0.13 ± 0.10‰ to 0.48 ± 0.10‰) indicate that oxidized geofluid infiltration resulted in the elevation of δ⁵⁶Fe values of omphacite during retrograde metamorphism.