An infrared and <Superscript>1</Superscript>H MAS NMR investigation of strong hydrogen bonding in ussingite,Na<Subscript>2</Subscript>AlSi<Subscript>3</Subscript>O<Subscript>8</Subscript>(OH)

The mineral ussingite, Na₂AlSi₃O₈(OH), an interrupted tectosilicate, has strong hydrogen bonding between OH and the other nonbridging oxygen atom in the structure. Infrared spectra contain a strongly polarized, very broad OH-stretching band with an ill-defined maximum between 1500 and 1800 cm^–1, and a possible OH librational bending mode at 1295 cm^–1. The IR spectra confirm the orientation of the OH vector within the triclinic unit cell as determined from X-ray refinement (Rossi et al. 1974). There are three distinct bands in the ¹H NMR spectrum of ussingite: a predominant band at 13.5 ppm (TMS) representing 90% of the structural hydrogen, a second band at 15.9 ppm corresponding to 8% of the protons, and a third band at 11.0 ppm accounting for the remaining 2% of structural hydrogen. From the correlation between hydrogen bond length and ¹H NMR chemical shift (Sternberg and Brunner 1994), the predominant hydrogen bond length (H...O) was calculated to be 1.49 Å, in comparison to the hydrogen bond length determined from X-ray refinement (1.54 Å). The population of protons at 15.9 ppm is consistent with 5–8% Al–Si disorder. Although the ussingite crystal structure and composition are similar to those of low albite, the bonding environment of OH in low albite and other feldspars, as characterized through IR and ¹H NMR, is fundamentally different from the strong hydrogen bonding found in ussingite.     

球坐标系下三维大地电磁正演研究

大地电磁正演理论研究热点一直以来主要集中在如何提高计算效率和精度,但在剖面足够长、探测深度足够大的情况下,传统的笛卡尔坐标系数值模拟方式难以准确拟合地球曲率形态.本文研究了基于球坐标系的三维大地电磁正演,推导了交错网格有限差分三维正演公式,与一维解析解和三维标准模型测试对比,验证了正演算法的正确性.通过理论模型计算,对比分析球坐标和笛卡尔坐标系正演结果表明：球坐标系模拟更合理,避免了传统笛卡尔坐标拉伸投影所引入的误差,可代替目前的笛卡尔坐标模拟方法.基于球坐标和笛卡尔坐标系的三维大地电磁正演响应值随着频率变低差异越明显.球坐标和笛卡尔坐标计算结果差异度与频率、模型结构和电阻率有关.本文模型计算结果在数万秒周期处已出现接近10%的差异,对于较大尺度的长周期大地电磁,地球曲率的影响不能忽略.

     

印度尼西亚西爪哇低品位金矿柱浸试验

在较佳人浸粒度（-20ram）及适宜的喷淋制度条件下,经5天浸出周期柱浸后,可获得金浸出率91．31％、NaCN耗量142．3g／t的技术经济指标,表明该金矿适合用本堆浸工艺提金。     

临汾盆地果场地裂缝成因机理分析

地裂缝是临汾盆地主要的地质灾害之一, 自20世纪70年代盆地开始出现地裂缝以来, 至2012年8月共发现86条地裂缝。本文以临汾盆地内部典型地裂缝临汾果场地裂缝为研究对象, 详细地论述了地裂缝发育的地质环境背景。利用野外调查、测量、槽探、钻探和物理勘探等地质手段, 主要研究了地裂缝的发育特征, 包括平面特征、灾害特征、浅部剖面结构特征和深部特征4个方面, 总结了地裂缝的活动规律。发现果场地裂缝平面延伸长, 宽度大, 走向稳定, 灾害严重; 浅表层上宽下窄, 呈喇叭状, 深部结构显示地裂缝下伏隐伏断层, 地裂缝活动受降雨控制。通过分析影响地裂缝形成的各个因素:盆地构造、超采地下水和强降雨, 将果场地裂缝的形成分为3个阶段:孕育阶段、出露阶段和扩展阶段; 最后概化了果场地裂缝的成因机理:构造孕缝、抽水诱缝和降雨扩缝。     

Low-pressure evolution of arc magmas in thickened crust: The San Pedro–Linzor volcanic chain,Central Andes,Northern Chile

Magmatism at Andean Central Volcanic Zone (CVZ), or Central Andes, is strongly influenced by differentiation and assimilation at high pressures that occurred at lower levels of the thick continental crust. This is typically shown by high light to heavy rare earth element ratios (LREE/HREE) of the erupted lavas at this volcanic zone. Increase of these ratios with time is interpreted as a change to magma evolution in the presence of garnet during evolution of Central Andes. Such geochemical signals could be introduced into the magmas be high-pressure fractionation with garnet on the liquidus and/or assimilation from crustal rocks with a garnet-bearing residue. However, lavas erupted at San Pedro–Linzor volcanic chain show no evidence of garnet fractionation in their trace element patterns. This volcanic chain is located in the active volcanic arc, between 22°00^′S and 22°30^′S, over a continental crust ∼70 km thick. Sampled lavas show Sr/Y and Sm/Yb ratios <40 and <4.0, respectively, which is significantly lower than for most other lavas of recent volcanoes in the Central Andes. In addition, ⁸⁷Sr/⁸⁶Sr ratios from San Pedro–Linzor lava flows vary between 0.7063 and 0.7094. This is at the upper range, and even higher than those observed at other recent Central Andean volcanic rocks (<0.708). The area in which the San Pedro–Linzor volcanic chain is located is constituted by a felsic, Proterozoic upper crust, and a thin mafic lower crustal section (<25 km). Also, the NW–SE orientation of the volcanic chain is distinctive with respect to the N–S orientation of Central Andean volcanic front in northern Chile. We relate our geochemical observations to shallow crustal evolution of primitive magmas involving a high degree of assimilation of upper continental crust. We emphasize that low pressure AFC- (Assimilation Fractional Crystallization) type evolution of the San Pedro–Linzor volcanic chain reflects storage, fractionation, and contamination of mantle-derived magmas at the upper felsic crust (<40 km depth). The ascent of mantle-derived magmas to mid-crustal levels is related with the extensional regime that has existed in this zone of arc-front offset since Late-Miocene age, and the relatively thin portion of mafic lower crust observed below the volcanic chain.     

湖相沉积物与全球变化的研究

为预测未来全球的气候变化，必须了解在过去水圈、气圈与生物圈的各自作用以及它们是如何相互影响的。为此，ＩＧＢＰ（国际地圈－生物圈计划）组织了过去全球变化项目（ＰＡＧＥＳ）。湖相沉积物保存着与ＰＡＧＥＳ有关的不同时空尺度的丰富的地球系统历史信息，特别是湖相沉积物包含着可以说明全球气候变化的水圈与生物圈的陆源组分的反应。这种信息对了解影响气候变化的流域是如何发展的至关重要。笔者应用西伯利亚贝加尔湖与中国西北部青海湖作为两个实例，叙述了多学科研究湖相沉积物物理与化学参数，并利用这些参数测定了晚更新世湖区及其流域对过去气圈的变化以及日幅射分布的影响     

Precessional forcing of tropical vegetation carbon storage

Since the Mid Pleistocene Revolution, which occurred about one million years ago, global temperatures have fluctuated with a quasi‐periodicity of ca. 100 ka. The pattern of past change in the extent of woodlands, and therefore by inference vegetation carbon storage, has been demonstrated to have a strong positive link with this global temperature change at high and mid latitudes. However, understanding of climate systems and ecosystem function indicates that the pattern of woodland change at low latitudes may follow a fundamentally different pattern. We present output from the intermediate complexity model GENIE‐1, comprising a single transient simulation over the last 800 ka and a 174‐member ensemble of 130 ka transient simulations over the last glacial cycle. These simulations suggest that while vegetation carbon storage in mid–high northern latitudes robustly follows the characteristic ca. 100 ka cycle, this signal is not a robust feature of tropical vegetation, which is subject to stronger direct forcing by the precessional (21 ka) orbital cycle (albeit with a highly uncertain response). We conclude that the correlation of palaeoenvironmental records from low latitudes with global temperature change must be done with caution. Copyright © 2011 John Wiley & Sons, Ltd.     

富宁阳文冲-广南菜子垣热液淋滤卡林型金矿区

金矿区构造活动具有多期性：加里东期及海西期在矿区形成的薄弱角度不整合面、近南北向平行的滑脱断层,是含矿热液的运移、沉淀的通道和空间。金矿床应属地下热液淋滤卡林型金矿床。     

Volatile element chemistry during accretion of the earth

We review some issues relevant to volatile element chemistry during accretion of the Earth with an emphasis on historical development of ideas during the past century and on issues we think are important. These ideas and issues include the following: (1) whether or not the Earth accreted hot and the geochemical evidence for high temperatures during its formation, (2) some chemical consequences of the Earth’s formation before dissipation of solar nebular gas, (3) the building blocks of the Earth, (4) the composition of the Earth and its lithophile volatility trend, (5) chemistry of silicate vapor and steam atmospheres during Earth’s formation, (6) vapor - melt partitioning and possible loss of volatile elements, (7) insights from hot rocky extrasolar planets. We include tabulated chemical kinetic data for high-temperature elementary reactions in silicate vapor and steam atmospheres. We finish with a summary of the known and unknown issues along with suggestions for future work.     

地幔氧逸度的研究进展

通过对目前国际上诸多有关地幔氧逸度的研究结果的系统分析和总结 ,提出了地幔中自由氧对地幔物质的性质、状态及运动过程产生影响的基本作用方式 ;介绍了目前地幔氧逸度研究的主要研究手段 ,包括本征氧逸度的实验室测量、模拟氧逸度的实验室测量、地幔氧逸度计及理论计算等及其优缺点 ;定性探讨了地幔氧逸度的时空分布规律 ,获得了地幔随时间的推移变得愈来愈氧化 ,随深度的增加变得愈来愈还原 ,以及在横向上不同大地构造部位的地幔区域具有不同的氧逸度等诸多结论。结合目前人们对地幔物质组成、性质、状态、运动过程及地球的起源与演化历史等的认识 ,初步提出了地幔不同圈层氧逸度的约束机制。最后 ,针对目前地幔氧逸度的研究现状 ,为今后提出了一些参考性的研究方向。