Haitaite-(La), LaU4+Fe3+2(Ti13Fe2+4Fe3+)Σ18O38, a New Member of the Crichtonite Group

Haitaite-(La), (La, Ce)(U4+, U6+, Fe2+)(Fe3+, Al)2(Ti, Fe2+, Fe3+)18O38, is a new member of the crichtonite group. It is named after the Haita Village in the Miyi County of Sichuan Province, China, where the mineral was discovered. The mineral occurs as black opaque centimeter-sized aggregates in the external contact zone between the Neoproterozoic (~800 Ma) alkali feldspar granite and the Mesoproterozoic (~1700 Ma) micaschist. In the studied sample, haitaite-(La) is associated with other minerals, including ilmenite, magnetite, rutile, zircon, brannerite and uraninite. The new mineral is a black, metallic phase and has a Mohs hardness of 6, with a density of 4.99 g/cm3 (calculated) and 5.03 g/cm3 (measured). Haitaite-(La) is opaque in transmitted light and grayish-white under reflected light, with a reflectivity between 22.5% and 16.42% in the 400–700 nm band (SiC, in the air). The compositions of the mineral were measured by EPMA, the U4+/U6+ ratio was determined by X-ray photoelectron spectroscopy and the Fe2+/Fe3+ ratio was determined by M?ssbauer spectroscopy. Haitaite-(La) is trigonal, belongs to R3ˉ and has unit-cell parameters a = 10.3678(5) ?, c = 20.8390(11) ?, V = 1939.9(2) ?3, Z = 3. The crystalline structure is composed of octahedra with 9 layers of close-packed octahedra (M1, M3, M4, M5), tetrahedra (M2) and contains large 12-coordinated M0 sites.     

The impact of ecosystem functional type changes on the La Plata Basin climate

In this paper, the effects of land cover changes on the climate of the La Plata Basin in southern South America are investigated using the Weather and Research Forecasting (WRF) Model configured on a 30/10km two-way interactive nested grid. To assess the regional climate changes resulting from land surface changes, the standard land cover types are replaced by time-varying Ecosystem Functional Types (EFTs), which is a newly devised land-cover classification that characterizes the spatial and interannual variability of surface vegetation dynamics. These variations indicate that natural and anthropogenic activities have caused changes in the surface physical parameters of the basin, such as albedo and roughness length, that contributed to regional climate changes. EFTs are obtained from functional attributes of vegetation computed from properties of the Normalized Difference Vegetation Index (NDVI) to represent patches of the land surface with homogeneous energy and gas exchanges with the atmosphere. Four simulations are conducted, each experimental period ranging from September to November in two contrasting years, 1988 and 1998. The influence of an identical EFT change on the surface heat fluxes, 2-m temperature and humidity, 10-m winds, convective instabilities and large-scale moisture fluxes and precipitation are explored for 1988 (a dry year) and 1998 (a wet year). Results show that the surface and atmospheric climate has a larger response to the same EFT changes in a dry year for 2-m temperature and 10-m wind; the response is larger in a wet year for 2-m water vapor mixing ratio, convective available potential energy, vertically integrated moisture fluxes and surface precipitation. For EFTs with high productivity and a weak seasonal cycle, the nearsurface temperature during the spring of 1988 and 1998 increased by as much as 1℃ in the central and western portions of La Plata Basin. Additionally, for higher productivity EFTs, precipitation differences were generally positive in both dry and wet years, although the patterns are not uniform and exhibit certain patchiness with drier conditions.     

鄱阳湖周边地区土壤垂向剖面 地球化学特征及第Ⅰ环境深度

通过对鄱阳湖周边厚覆盖区土壤垂深剖面的构成特点、土壤酸碱度、元素分布分配规律的分析研究,探讨了区内元素的相关组合特点及元素在深度方向上"含量稳定性拐折点"的位置,揭示了区域内土壤垂深剖面的地球化学特征与环境意义。根据数理统计原理,结合区域内土壤垂深剖面的地球化学特征和大规模生产的条件,指出区域内土壤第Ⅰ环境的合理采样深度为-150～-180 cm。     

Anthropogenic iodine-129 in seawater along a transect from the Norwegian coastal current to the North Pole

Variation in the concentrations of iodine-129 (129I, T1/2=15.7 Myr), a low-level radioactive component of nuclear fuel waste, is documented in surface waters and depth profiles collected during 2001 along a transect from the Norwegian Coastal Current to the North Pole. The surface waters near the Norwegian coast are found to have 20 times higher 129I concentration than the surface waters of the Arctic Ocean. The depth profiles of 129I taken in the Arctic Ocean reveal a sharp decline in the concentration to a depth of about 300-500 m followed by a weaker gradient extending down to the bottom. A twofold increase in the 129I concentration is observed in the upper 1000 m since 1996. Based on known estimates of marine transient time from the release sources (the nuclear reprocessing facilities at La Hague, France, and Sellafield, UK), a doubling in the 129I inventory of the top 1000 m of the Arctic Ocean is expected to occur between the years 2001 and 2006. As 129I of polar mixed layer and Atlantic layer of the Arctic Ocean is ventilated by the East Greenland Current into the Nordic Seas and North Atlantic Ocean, further dispersal and increase of the isotope concentration in these regions will be encountered in the near future.     

镧掺杂的二氧化钛纳米颗粒的合成、结构表征及光催化性能

以无水乙醇为溶剂、1-丁基-3-甲基咪唑四氟硼酸盐([Bmim]BF4)离子液体为表面活性剂,以钛酸四丁酯、六水合硝酸镧为原料,采用共沉淀法制备了不同掺镧量的La-TiO2光催化材料。采用X-射线衍射仪(XRD)、傅里叶变换红外光谱仪(FTIR)、场发射扫描电镜(FESEM)、差热-热重分析仪(TG-DSC)、紫外-可见吸收光谱仪(UV-vis)、比表面及孔隙度分析仪(BET)对其结构、形貌、热稳定性、光学性能及比表面积进行表征。所制备产品的光催化性能在紫外光下进行了光催化降解甲基橙实验,实验结果表明在离子液体的量为0.5mL,掺杂镧量为5%的TiO2纳米材料对甲基橙的降解效果相对较好,降解率最高达到98.73%。     

Constructing regional advantage in non-metropolitan regions: A comparison between La Pocatière (Canada) and Tromsø (Norway)

The construction of regional advantage has recently been emphasized by scholars as a new way of increasing firms’ competitiveness in a globalizing and learning economy. This article compares the construction of regional advantage and the development paths of specific industries in two different types of non-metropolitan regions, La Pocatière in Canada and Tromsø in Norway. The authors observe a higher level of industrial dynamism in La Pocatière than in Tromsø. They find four explanations for this variation: (1) a narrower regional innovation system (RIS) in Tromsø; (2) the fact that the target industry in Tromsø (marine biotechnology) is, in general, more difficult to develop outside metropolitan regions than the diverse mechanical engineering industry found in La Pocatière; (3) a biased focus on the development of research-based knowledge and academic spin-offs in Tromsø compared with a more varied set of strategies used in La Pocatière; and (4) La Pocatière's location in proximity to the Quebec metropolitan region.     

2011年全球重大天气气候事件及其成因

2011年,全球气温偏高,为有观测记录以来的第十个暖年,是近60年来出现拉尼娜事件的年份中全球气温最高的一年。2011年,全球热带气旋活动较常年偏少。4月,一次拉尼娜事件结束,9月又一次拉尼娜事件生成。年初,低温、寒流席卷亚洲大部,暴风雪频繁袭击北美地区。西欧和中国东部出现严重春旱。夏季,非洲东部经历了20世纪80年代以来最严重的干旱,而东南亚、巴基斯坦和中南美洲洪涝灾害严重。全球极端偏暖事件主要出现在欧洲西部和西北部、南亚南部、东亚中西部、北美东南部等地;极端偏冷事件主要出现在东亚、澳大利亚、非洲南部和美国东北部和西部等地。而南美中东部、东南亚及中国东南部、日本、澳大利亚北部、非洲西部等地出现了极端强降水事件。研究发现,2010／2011年拉尼娜事件和台风活动是导致东南亚洪涝出现的重要原因,而巴基斯坦洪涝主要与印度洋正位相偶极型海温分布有关。     

与广东持续性干旱事件有关的两类海温异常型

利用1961\_2005年广东省86个常规地面观测站降水资料、 ERSST全球月平均海温资料以及NCEP/NCAR 大气多要素再分析资料, 分析了广东跨季节持续性干旱事件(下称广东干旱)与海温外强迫之间的关系及其物理过程。结果表明, 与广东干旱相关的海温异常有赤道东太平洋海温负异常型（即La Nia型）、 赤道中太平洋海温正异常型两种类型。约在1975年之前, 广东干旱基本上属于La Nia型; 在1975年之后, 除了La Nia型外, 赤道中太平洋海温正异常型干旱出现概率明显增加。可见, 在全球气候变暖的背景下, 广东干旱成因更复杂。近几年来广东干旱频繁发生, 与赤道中太平洋海温正异常型出现概率增加有关。La Nia型、 赤道中太平洋海温正异常型与广东干旱之间都存在物理上的联系, 不同的海温异常型对广东干旱影响的物理过程有所不同, 即使同一种海温异常型对不同季节的影响过程也有所不同, 然而所有物理过程最终都是通过改变和削弱降水所需的动力条件或水汽条件, 从而造成局地干旱的发生。     

一个观察北极涛动与北大西洋涛动关系的典型个例

北极涛动与大西洋涛动是否属同一气候变率模态一直是北极涛动动力学研究方面的一个颇具争议的话题。文中通过对"0801南方雪灾"期间及其前后北极涛动与北大西洋涛动异常及产生原因进行个例分析,对两者之间的关系进行了讨论。首先使用交叉子波变换与子波相关方法分析了两者的相位关系。发现在30—60天时间尺度上北极涛动与北大西洋涛动相位相差90°或-90°。而在10 20天这一尺度上北极涛动与北大西洋涛动具有大致相同的相位。对北极涛动及北大西洋涛动形成的动力过程及其在拉尼娜背景下各自特点的分析表明,这种不同尺度上位相关系的差异来自于波-流相互作用动力学的局域性。众所周知,北极涛动的3个活动中心的形成与分别位于北大西洋、北太平洋和北极平流层的3个波流相互作用中心有关。而北大西洋涛动则主要与位于北大西洋的波-流相互作用中心有关。拉尼娜事件的出现通过影响太平洋急流及行星尺度的准定常波从而进一步强化了30-60天时间尺度上北极涛动与北大西洋涛动的这种差异。这主要是因为太平洋急流或准定常行星波在对流层中直接影响了位于该区域的北极涛动的活动中心。同时准定常行星波冬季向上传播至平流层并与平流层极涡相互作用从而也影响了北极涛动在北极的活动中心。而在10—20天时间尺度上的北极涛动与北大西洋涛动同步关系则说明它们都是北极涛动的另一活动中心即大西洋上同一波-流相互作用现象——天气波破碎的反映。基于上述分析.文中倾向于认同将北极涛动和北大西洋涛动区别考虑的观点。     

CAM3模式模拟厄尔尼诺事件对大气环流异常的影响

采用CAM3（Community Atmosphere Model Version3）模式中海气湍流通量参数化原方案和改进方案,利用观测海温驱动CAM3模式进行气候模拟,以分析模式对厄尔尼诺事件影响气候变化的模拟能力。结果表明,采用CAM3模式海气湍流通量参数化改进方案,模式能够更好地模拟出由厄尔尼诺事件引起的北太平洋和北美地区大气环流的变化,尤其是对厄尔尼诺年冬季阿留申低压强度和与PNA遥相关型有关的500hPa位势高度异常的模拟。