塔里木盆地典型砂岩油气储层自生伊利石K-Ar同位素测年研究与成藏年代探讨

塔里木盆地共发现 8套砂岩油气储层 ,对其中的 5套典型砂岩油气储层进行了自生伊利石K Ar同位素测年分析与研究。利用该项技术对其成藏史进行初步探讨是本次研究的主要目的。中央隆起下志留统沥青砂岩的自生伊利石年龄为 383.4 5～ 2 35 .17Ma ,表明志留系古油藏形成于加里东晚期—海西晚期 ;上泥盆统东河砂岩的自生伊利石年龄为 2 6 3.82～ 2 31.34Ma ,表明东河砂岩油气藏主要形成于海西晚期 ;库车坳陷依南 2气田 (依南 2井 )下侏罗统阳霞组砂岩的自生伊利石年龄为 2 8.0 8～ 2 3.85Ma ,表明油气充注发生在中新世以来 ;喀什凹陷阿克莫木气田 (阿克 1井 )下白垩统砂岩的自生伊利石年龄为 2 2 .6 0～ 18.79Ma ,表明中新世可能有古油气运移或古油藏形成 ;库车坳陷迪那 2气藏 (迪那 2 0 1井 )古近系砂岩中的伊利石主要为碎屑成因 ,不能用于进行油气成藏史研究 ,但该气藏白垩系砂岩的自生伊利石年龄为 2 5 .4 9～ 15 .4 7Ma ,表明可能为中新世成藏。本次研究表明 ,该项技术在塔里木盆地初步显示出较好的应用效果 ,具有较为广阔的应用前景。     

中国东北地区新生代火山岩的年代学研究

用常规K-Ar、~(40)Ar-~(39)Ar、~(14)C等方法系统测定了东北地区新生代火山岩的年龄,获得近百个有效年龄数据。其精度和准确度都很高,与地质背景相当吻合。对于玄武岩中超镁铁质岩色体也进行了年龄测定尝试、发现包体中含继承氩,并可能存在~(36)Ar过剩。在阶段加热过程中,样品中氩的释放有两个高峰,一个在低温阶段(450—620℃),另一个在高温阶段(>1000℃),约50％的放射成因~(40)Ar在低温阶段释放。     

油藏成藏年代学分析

成藏年代学研究是成藏动力学研究的重要方面 ,是揭示成藏过程、成藏速率研究的有效途径。文中系统介绍了成藏年代学研究方法 ,即以储层自生伊利石年代学分析法为主 ,与其它传统地质方法相结合 ,对大庆油田的成藏年代学进行了系统研究。大庆油田北部的喇嘛甸、萨尔图、杏树岗块状背斜构造油藏成藏年龄在 65～ 4 0Ma ,南部受岩性控制的背斜构造油藏成藏年龄在 77.4～ 73Ma ,采用数值模拟方法对其进行了验证 ,揭示了石油二次运移、聚集成藏的动力学过程具有快速、高效的特征     

K-Ar Ages of Granitic Magmatism and Related Pegmatite Formation at the Umanotani-Shiroyama Mine, Shimane Prefecture, SW Japan and Their Bearings on Cooling History

Abstract. The Umanotani-Shiroyama pegmatite deposits, the largest producer of K-feldspar and quartz in Japan, are of typical granitic pegmatite. Ilmenite-series biotite granite and granite porphyry, hosting the ore deposits, and biotites separated from these rocks yielded K-Ar ages ranging from 89.0 to 81.4 Ma and 95.2 to 93.7 Ma, respectively. Muscovite and K-feldspar separated from the ore zone yielded K-Ar ages with the range of 96.2 to 93.1 Ma and 87.3 to 80.7 Ma, respectively. Muscovites from quartz-muscovite veins in the ore zone and in the granite porphyry yielded K-Ar ages of 90.4 and 76.3 Ma, respectively. K-feldspar is much younger in age than coexisting muscovite. It is noted that the K-Ar ages of biotite separates and the whole-rock ages are identical to those of muscovite and K-feldspar in the ore zone, respectively. These time relations, as well as field occurrence, indicate that the formation of the pegmatite deposits at the Umanotani-Shiroyama mine is closely related in space and time to a series of granitic magmatism of ilmenite-series nature. Using closure temperatures of the K-Ar system for biotite and K-feldspar (microcline), cooling rate of the pegmatite deposits is estimated to be about 82C/m.y. at the beginning, but slowed down to about 15C/m.y. in the later period.     

安徽黄梅尖地区基性岩脉K-Ar年代学、地球化学特征及地质意义

在野外地质调查和室内综合研究的基础上,通过对黄梅尖地区辉绿玢岩K-Ar年代学、地球化学和Sr-Nd同位素特征进行研究,探讨辉绿玢岩的形成时代、岩石成因及构造背景。K-Ar年代学研究表明,辉绿玢岩形成于~107 Ma,是早白垩世岩浆活动的产物,形成时代晚于该地区火山岩和侵入岩,与该地区铀成矿年龄基本一致;辉绿玢岩的侵入可能是该地区岩浆作用的最后一幕,铀成矿可能与辉绿玢岩具有成因联系。地球化学特征表明,辉绿玢岩富集大离子亲石元素K、Rb、U、Pb和轻稀土元素,亏损高场强元素Nb、Ta、P、Ti,具有较高的Isr值和负εNd(t)值,具有富集地幔源区特征;辉绿玢岩是在地壳伸展和岩石圈减薄的构造背景下,由俯冲交代作用形成的富集地幔部分熔融形成的,表明~107 Ma时该地区仍处于伸展构造环境下。     

新疆北部晚古生代以来中基性岩脉的年代学、岩石学、地球化学研究

新疆北部中基性岩脉K-Ar表观年龄为187～271Ma,岩性以辉长、辉绿岩以及闪长、闪长玢岩为主,属于亚碱性系列.主量元素、稀土元素以及微量元素分析表明,中基性岩脉经历了源区地壳物质的混合以及侵位过程中的分离结晶作用,并在区域分布特点上受部分熔融程度的影响,而且由于结晶分异和部分熔融的不同,还出现了中基性岩脉系列的成分变异.排除上述岩浆作用的干扰,有证据显示岩脉起源于亏损地幔,由于Nd同位素模式年龄tDM集中在363～769Ma,反映源区是一个古生代时期的新生岩石圈地幔,该地幔源区属于大洋岩石圈地幔.新疆北部广泛出露的中基性岩脉在时间和空间上具有多样性,但是在产状、岩性组合和同位素特征上具有相似的特点,指示研究区在古生代以来具有一个相对统一和完整的源区,推测这个源区与北疆地区古生代以来长期存在的残余洋盆及其相关岩石圈有关.     

腾冲火山活动的时代和岩浆来源问题

47个腾冲火山岩样品的K-Ar年龄值域在0.09和17.84Ma之间。4条火山岩的⁴⁰Ar/³⁶Ar-⁴⁰K/³⁶Ar等时线年龄分别为2.93、0.81、0.31和0.13Ma。火山喷发的时代从中新世到更新世,喷发的高潮在晚更新世。腾冲火山目前还不是死火山,而腾冲及其邻区的热事件（侵入-热变质-喷发）又是连续发生的。20个样品的Rb和Sr含量、稳定Sr同位素初始比（0.70578-0.71437）以及其它地球化学资料还表明,这些火山岩是属于板块碰撞带生成的高钾钙碱性岩浆系列。火山岩的母岩浆来源于地幔的玄武岩浆,但在上升过程中受到过富含放射性成因Sr的地壳物质的强烈渐进混染。     

Mössbauer characteristics,mineralogy and isotopic age (Rb-Sr,K-Ar) of Upper Riphean glauconites from the UK Formation,the southern Urals

Comprehensive mineralogical analysis, Mössbauer spectroscopy and isotopic-geochronological study have been carried out for globular phyllosilicates (GPS) of glauconite group from the Uk Formation, the second one below the top of the Upper Riphean stratotype in the southern Urals. Glauconites have been sampled in the Kurtaza and Kulmas sections remote from each other in the Alatau anticlinorium that corresponds to western facies zone of the Bashkirian meganticlinorium. As is shown, size and density monomineral fractions of globules are represented by Al-glauconite according to established structural formula. The isotopic (Rb-Sr and K-Ar) dating of glauconites from the Uk Formation is performed for the first time along with computer simulation of cation arrangements in their crystal lattice and comparison of the results obtained with data of Mössbauer spectroscopy. It has been assumed by simulation that origin and transformation of the Rb-Sr and K-Ar systems in glauconite are concurrent to stages in structural evolution of this mineral, which have been controlled by geological and geochemical events in the history of sedimentary successions. The approach has been aimed at recognition of stratigraphically meaningful isotopic dates corresponding to the glauconite formation at the stage of the early diagenesis close to sedimentation time and the “rejuvenated” dates characterizing ages of subsequent geological events. The comparison of simulated cation arrangements with data of Mössbauer spectroscopy shows that the Rb-Sr (663 ± 9 Ma) and K-Ar (669 ± 16 Ma) dates established for glauconites correspond to the time of early diagenesis in their host sediments, being suitable for age assessment of the Uk Formation. The dates obtained are of interregional and wider significance, as they must be taken into consideration when constructing the general curve of Sr isotope variations in the Late Riphean oceans.     

Geochronology of Pliocene volcanism in the Dzhavakheti Highland (the Lesser Caucasus). Part 2: Eastern part of the Dzhavakheti Highland. Regional geological correlation

The results of isotopic-geochronological study of the Pliocene volcanic rocks in reference sections and volcanic edifices of eastern part of the Dzhavakheti Highland (the northwestern Lesser Caucasus) are considered. The isotopic-geochronological data obtained here are correlated with data on western part of the Dzhavakheti Highland, which have been considered in previous part of this work. Based on correlation, time spans of principal volcanic events of the Pliocene in the study region as a whole are determined, and general trends of the young magmatism evolution within the region are established. In sum, the isotopic-geochronological dates evidence that the Pliocene magmatism of the Dzhavakheti Highland developed practically without essential breaks during the period of about 2 Ma long, from 3.75 to 1.75–1.55 Ma ago. The areal basic volcanism that was most widespread at that time is divisible into five discrete phases according to the isotopic dates obtained. Comparatively short pauses, which separated these phases of magmatic activity, were a few hundreds thousand years long, not more. Chemical composition of moderately acidic to silicic volcanics, which are of a limited distribution in the Dzhavakheti Highland, and their age relations with basic lavas of the region suggest that they are most likely the differentiation products of parental basic mantle-derived magmas. The analyzed distribution of volcanic centers, which erupted basic lavas of the Dzhavakheti Highland, evidence that first two phases of basic magmatism were connected here with volcanic activity in southwestern part of the region (northern termination of the Egnakhag Ridge), whereas activity of volcanoes situated on the east, predominantly in water-shed part and on slopes of the submeridional Dzhavakheti Ridge, controlled development of the third and fourth phases. Consequently, magmatic activity of the Pliocene stage in history of the Neogene-Quaternary magmatism of the Dzhavakheti Highland laterally migrated from the west to the east, being controlled by development of regional submeridional extension zones. Volcanic ridges marking the latter are formed by volcanic edifices, which are amalgamated at their bases and have erupted lavas of close age and composition. The migration of volcanic activity can be described in terms of the “domino effect,” when cessation of volcanism in one zone led to formation of the other submeridional zone of extension and magmatic activity displaced from the west eastward in sublatitudinal direction. In general, evolution of the Pliocene magmatism of the Dzhavakheti Highland, was similar, despite the essential regional peculiarities, to the generalized trend of magmatism evolution in the continental rifts and intraplate zones of the “hot-spot” type.     

望天鹅火山岩石地球化学特征及其成因

东北吉林望天鹅新生代火山岩（7．04—1．86Ma）主要由玄武粗安岩和碱性流纹岩组成。玄武粗安岩的SiO2介于49．38％-53．31％之间;K2O＋Na2O为4．27％-7．72％;∑REE为163．69×10^-6-258．55×10^-6,Eu异常不明显,δEu为0．72～1．17;碱性流纹岩具高SiO2（70．39％～71．49％）含量,高碱（K2O＋Na2O为9．28％～9．49％）,高稀土总量（∑REE介于309．30×10^-6～465．03×10^-6之间）,明显的Eu负异常,3Eu为0．52～0．71。碱性流纹岩的微量元素含量较玄武粗安岩高,且具有明显的Sr、P、Ti负异常。望天鹅火山岩的^87Sr／^86Sr比值在0．705156-0．709029之间,而^144Nd／^143Nd比值变化较小,介于0．512295～0．512602之间;放射性成因Pb同位素变化范围也较小,^206Ph／^204Pb为17．254～18．090,^207Ph／^204Pb为15．460～15．507,^208Pb／^204Ph为37．278—38．048。综合分析火山岩的主量元素、微量元素和Sr-Nd—Pb同位素特点,初步认为望天鹅火山的玄武粗安岩和碱性流纹岩具有相同的地幔源区。玄武粗安岩起源于微弱富集上地幔,在上升过程中结晶分异形成了碱性流纹岩。