油气储层自生伊利石的分离提纯及其K-Ar同位素测年技术研究

油气注入史研究对于指导油气勘探具有非常重要的意义。油气储层自生伊利石K Ar同位素测年可以为油气注入时间的研究提供科学依据。文中对油气储层自生伊利石分离提纯及其K Ar同位素测年技术进行了系统介绍。对碎屑含钾矿物杂质对自生伊利石K Ar同位素年龄的影响进行了深入研究 ,建立了一套完整的数据处理技术并提出了“校正年龄”的概念。     

Episodic accretion and metamorphism of Jurassic accretionary complex based on biostratigraphy and K-Ar geochronology in the western part of the Mino-Tanba Belt, Southwest Japan

Abstract The low grade metamorphic Jurassic accretionary complex in the western part of the Mino-Tanba Belt, Southwest Japan, is a chaotic sedimentary complex which consists of argillaceous matrices with allochthonous blocks of chert, greenstone, siliceous mudstone, terrigenous sandstone and mudstone. The complex is divided into three distinct geologic units, Units I, II and III, with a tectonic boundary (thrust) between them, forming a pile-nappe structure. They have different features for lithologies, fossil age, metamorphic condition and K-Ar age. Microfossil researches revealed that their timings of accretion were in the early Early Jurassic ( ca 195 Ma) for Unit III, in the early Middle Jurassic ( ca 175 Ma) for Unit II and in the latest Late Jurassic (ca 147 Ma) for Unit I. On the other hand, K-Ar age determinations of white mica separated from pelitic rocks of the three units clarified that the subsequent subduction-related metamorphism was 23 million years after the accretion of each unit. These results strongly suggest that the accretionary and metamorphic process had taken place episodically with an interval of 20 to 28 million years during Mesozoic time in the western part of the Mino-Tanba Belt, Southwest Japan.     

K-Ar法地质年龄国家一级标准物质ZBH-25黑云母的研制

ZBH-25黑云母采自北京房山花岗闪长岩体。它的~(40)Ar/~(39)Ar 阶段加热实验结果表明,~(40)Ar~*在矿物晶格中保存均匀稳定,年龄谱平坦,~(39)Ar 析出量高达96%,~(40)K-~(40)Ar~*同位素体系封闭良好,证明该黑云母结晶以后未受过热扰动。坪年龄为133.0±0.3Ma,总气体年龄为132.1±0.6Ma;~(36)Ar/~(40)Ar-~(39)Ar/~(40)Ar 反等时线年龄为133.1±1.3 Ma,~(40)Ar/~(36)Ar 初始值为293.5±1.6,与大气氩丰度比(295.5±0.5)处于同一范围,表明样品不含过剩氩。激光显微探针单颗粒坪年龄为132.8±0.2Ma,年龄谱和 K/Ca 谱线平坦,激光熔样总气体年龄为131.3±0.2Ma(图6)。这几个 Ar-Ar 年龄的一致性,说明样品具有良好的均匀性和稳定性,是理想的 K-Ar 和 Ar-Ar 法年龄标准物质。对均匀性检验数据进行统计学方法检验,在0.05显著性水平下,证明 K 和~(40)Ar~*的 F 分布值小于 F 临界值,说明该样品是均匀的。国内外14个实验室参加了 K 含量的定值分析,15个实验室参加了~(40)Ar~*含量的定值分析,经统计学方法检验,结果显示全部定值数据都服从正态分布并具等精度。在置信概率为0.95时,~(40)Ar~*和 K 含量的相对标准偏差都小于0.5%。两个特性量值定值分析结果的一致值和不确定度分别为:~(40)Ar~*=1.817±0.013×10~(-9)mol/g,K=7.60±0.02%,K-Ar 年龄(标准值)=132.9±1.3Ma(2σ).此标准物质纯度为98.8%,粒度为0.25-0.63mm,总重量为5800g,缩分成最小样品单元共400瓶,每瓶重量为14.5g。可供我国 K-Ar 和 Ar-Ar 法同位素年代学实验室使用120年。     

济阳坳陷桩海地区中生界同位素年代地层学研究

济阳坳陷中生界分布广泛,具有油气成藏的基本地质条件,并取得了一定的勘探发现,但其勘探程度和研究程度相对较低,包括地层划分、沉积体系、储层特征、控藏因素等。特别是地层时代、分层与分界等基本的地质问题尚存在不同的观点和认识。根据区内14口井的10个火山岩全岩样品和79个小于2μm的泥岩自生伊利石样品,开展K-Ar法同位素年代地层学测定,分别确定了中生界的坊子组、蒙阴组、三台组和西洼组的绝对年龄值,将坊子组划归下侏罗统,蒙阴组为中侏罗统,缺失上侏罗统,并明确了各组的接触关系。     

Neoproterozoic metamorphism and deformation at the southeastern margin of the East European Craton,Uralides, Russia

The eastern margin of the East European Craton (EEC) has a long lasting geological record of Precambrian age. Archaean and Proterozoic strata are exposed in the western fold-and-thrust belt of the Uralides and are known from drill cores and geophysical data below the Palaeozoic cover in the Uralides and its western foredeep. In the southern Uralides, sedimentary, metamorphic and magmatic rocks of Riphean and Vendian age occur in the Bashkirian Mega-anticlinorium (BMA) and the Beloretzk Terrane. In the eastern part of the BMA (Yamantau anticlinorium) and the Beloretzk Terrane, K-Ar ages of the <2-µm-size fraction of phyllites (potassic white mica) and slates (illite) give evidence for a complex pre-Uralian metamorphic and deformational history of the Precambrian basement at the southeastern margin of the EEC. Interpretation of the K-Ar ages considered the variation of secondary foliation and the diagenetic to metamorphic grade. In the Yamantau anticlinorium, the greenschist-facies metamorphism of the Mesoproterozoic siliciclastic rocks is of Early Neoproterozoic origin (about 970 Ma) and the S1 cleavage formation of Late Neoproterozoic (about 550 Ma). The second wide-spaced cleavage is of Uralian origin. In the central and western part of the BMA, the diagenetic to incipient metamorphic grade developed in Late Neoproterozoic time. In post-Uralian time, Proterozoic siliciclastic rocks with a cleavage of Uralian age have not been exhumed to the surface of the BMA. Late Neoproterozoic thrusts and faults within the eastern margin of the EEC are reactivated during the Uralian deformation.     

新疆富蕴可可托海—二台断裂带中假玄武玻璃及其围岩的年代学研究

发育在新疆富蕴可可托海—二台断裂带中的假玄武玻璃是古地震断裂快速滑移形成的构造岩。地质产状、显微构造研究表明,这些假玄武玻璃主要由发生重结晶的玻璃质熔融体形成。假玄武玻璃基质的全岩40Ar/39Ar阶段升温方法主阶段和KAr年龄分别为282.8±3.8 Ma和276.4±7.4 Ma。假玄武玻璃所在母岩（黑云母花岗岩和钾长花岗岩）的锆石U-Pb年龄分别为390.4±1.0 Ma和396.3±0.1 Ma,表明二台断裂带中的假玄武玻璃是在二叠世早期形成的,也说明二台断裂带古地震活动至少可以追溯到晚古生代（早二叠世早期）。尽管二台断裂带是现今仍然活动的地震构造带,但目前所见到的假玄武玻璃是早二叠世时期古地震活动的产物。1931年的富蕴80级地震仅仅是沿着二台断裂带发生的多次构造活动的一次活动,与假玄武玻璃之间没有成因上的联系。     

雷州半岛玛珥湖区玄武岩的年代、地球化学特征及其意义

我国南部雷州半岛是亚洲季风影响的核心区,区域内田洋、青桐洋和九斗洋这3个干玛珥湖沉积序列可为揭示低纬地区亚洲季风的轨道尺度变化提供关键证据。查明这些玛珥湖的形成年代、基底玄武岩的地球化学组成及其风化产物特征,为进一步获得沉积序列的年代控制、揭示沉积物替代指标的古气候意义提供了基础。本研究对3个干玛珥湖基底的玄武岩进行了K-Ar测年、地球化学成分和玛珥湖周围风化剖面粘土矿物的测试分析,得出了以下结论:1)田洋玛珥湖湖盆的形成年代为0.73~0.87Ma,首次报道的青桐洋和九斗洋湖盆的形成时代分别为0.82 Ma和0.81~1.08 Ma,它们均属于早更新世晚期到中更新世早期的石峁岭期火山射气喷发形成的。2)田洋、青桐洋和九斗洋玛珥湖基底玄武岩均属于石英拉斑玄武岩。同一时期喷发的石英拉斑玄武岩广泛分布在玛珥湖的周围,这些玄武岩风化的产物以高岭石、三水铝石以及赤铁矿为主,在降水较为充沛的时期,物理或化学风化的产物随地表径流汇入湖盆,是玛珥湖沉积的主要来源。本研究为正在进行的低纬地区更新世轨道尺度季风降水重建提供了基础。     

Constraints on the timing and regional conditions at the start of the present phase of crustal extension in western Turkey,from observations in and around the Denizli region

The chronology of extension of the continental crust in western Turkey has been the subject of major controversies. We suggest that these difficulties have arisen in part because of past misuse of dating evidence; and in part because the assumption often made, that deposition of major terrestrial sedimentary sequences implies crustal extension to create the necessary accommodation space, is incorrect. We report evidence that the present phase of extension began in the Denizli region at ~ 7 Ma, around the start of the Messinian stage of the Late Miocene. This timing matches the estimated start of right-lateral slip on the North Anatolian Fault Zone, and corresponds to a substantial increase in the dimensions of the Aegean extensional province to roughly its present size: beforehand, between ~ 12 Ma and ~ 7 Ma, extension seems to have only occurred in the central part of this modern province. In some localities, terrestrial sedimentation that began before this start of extension continued into this extensional phase, both within and outside normal fault zones. However, in other localities within the hanging-walls of normal faults, the start of extension marked the end of sedimentation. Relationships between sedimentation and crustal extension in this region are thus not straightforward, and a simple correlation should therefore not be assumed in structural interpretations. During the time-scale of this phase of extension, the Denizli region has also experienced major vertical crustal motions that are unrelated to this extension. The northern part of this region, in the relatively arid interior of western Turkey, has uplifted by ~ 400 m since the Middle Pliocene, whereas its southern part, closer to the Mediterranean Sea and with a much wetter climate, has uplifted by ~ 1,200 m since the Early Miocene, by up to ~ 900 m since the Middle Pliocene, and by an estimated ~ 300 m since the Early Pleistocene. This regional uplift, superimposed on the local effects of active normal faulting, is interpreted as a consequence of lateral variations in rates of erosion. A reliable chronology for this phase of extension in western Turkey, in relation to changes in the geometry of motions of adjoining plates and Late Cenozoic environmental change, is now in place.     

油藏成藏年代学分析

成藏年代学研究是成藏动力学研究的重要方面 ,是揭示成藏过程、成藏速率研究的有效途径。文中系统介绍了成藏年代学研究方法 ,即以储层自生伊利石年代学分析法为主 ,与其它传统地质方法相结合 ,对大庆油田的成藏年代学进行了系统研究。大庆油田北部的喇嘛甸、萨尔图、杏树岗块状背斜构造油藏成藏年龄在 65～ 4 0Ma ,南部受岩性控制的背斜构造油藏成藏年龄在 77.4～ 73Ma ,采用数值模拟方法对其进行了验证 ,揭示了石油二次运移、聚集成藏的动力学过程具有快速、高效的特征     

塔里木盆地典型砂岩油气储层自生伊利石K-Ar同位素测年研究与成藏年代探讨

塔里木盆地共发现 8套砂岩油气储层 ,对其中的 5套典型砂岩油气储层进行了自生伊利石K Ar同位素测年分析与研究。利用该项技术对其成藏史进行初步探讨是本次研究的主要目的。中央隆起下志留统沥青砂岩的自生伊利石年龄为 383.4 5～ 2 35 .17Ma ,表明志留系古油藏形成于加里东晚期—海西晚期 ;上泥盆统东河砂岩的自生伊利石年龄为 2 6 3.82～ 2 31.34Ma ,表明东河砂岩油气藏主要形成于海西晚期 ;库车坳陷依南 2气田 (依南 2井 )下侏罗统阳霞组砂岩的自生伊利石年龄为 2 8.0 8～ 2 3.85Ma ,表明油气充注发生在中新世以来 ;喀什凹陷阿克莫木气田 (阿克 1井 )下白垩统砂岩的自生伊利石年龄为 2 2 .6 0～ 18.79Ma ,表明中新世可能有古油气运移或古油藏形成 ;库车坳陷迪那 2气藏 (迪那 2 0 1井 )古近系砂岩中的伊利石主要为碎屑成因 ,不能用于进行油气成藏史研究 ,但该气藏白垩系砂岩的自生伊利石年龄为 2 5 .4 9～ 15 .4 7Ma ,表明可能为中新世成藏。本次研究表明 ,该项技术在塔里木盆地初步显示出较好的应用效果 ,具有较为广阔的应用前景。