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11.
12.
YousifK. Kharaka Evangelos G. Kakouros James J. Thordsen David L. Naftz 《中国地球化学学报》2006,25(B08):100-101
Selenium (Se) is an essential micronutrient to biota, but can become a potent toxicant at elevated concentrations. The natural sources and chemical properties of Se species make the boundary between deficiency and toxicity narrow for some biota, with both phenomena common around the globe. Large areas of farmland in the Colorado River Basin (CRB) generate salinized drainage water with Se concentrations much higher than 5 μg/L, the U.S. Environmental Protection Agency chronic water-quality criterion for the protection of aquatic life. We have carried out detailed field and laboratory studies to investigate Se geochemistry and remediation in two of these areas: the Middle Green River Basin, Utah and the Salton Sea Basin, California, located respectively in the Upper and Lower CRB. Results from these and other studies show that approximately 90% of the dissolved Se in the Colorado River and its tributaries originally is derived from the Upper Cretaceous Mancos Shale and equivalent pyritic marine units that outcrop in the Upper CRB. Selenium is mobilized commonly by biogeochemical oxidation of this pyritic shale and is concentrated mainly as selenate (SeO4^2-) in soils and agricultural drainage water of dry climates by evaporation. Minor (0%-5%) amounts of Se are present as the selenite species (HSeO3^-) and (SEO3^2-), but these species and the more reduced species, elemental Se (SeO) and selenide (Se^2-), have much lower solubility and/or have high sorptive affinity towards organic matter, clay minerals and iron oxyhydroxides. The concentration of dissolved Se (-2.5 μg/L) and salinity in the Lower Colorado River water are among the highest of the world major rivers. Because of low precipitation (7 cm/a) and extreme evapotranspiration (-1.8 m/a) rates in the Salton Sea Basin, California, Se values in irrigation water imported from the Colorado River increase to 〉300 μg/L in drainage wastewater. Removal of Se from contaminated wastewater by nanofiltration membranes was demonstrated in laboratory and pilot-scale field experiments. 相似文献
13.
Chunye LIN Mengchang HE Baixing YAN Xiangchun QUAN Yuxiang ZHOU Wei GUO Zhifeng YANG 《中国地球化学学报》2006,25(B08):118-119
The Second Songhua River was subjected to a large amount of untreated effluent from petrochemical industries in Jilin City in the 1960s to the 1970s. The objectives of this study were to investigate the mercury and other heavy metal contamination in the sediment of the river. The river bottom sediment was sampled from the river segment between Jilin City to Haerbin City in 2005. Total concentrations of Hg, Cd, Cu, Cr, Pb, Zn, Ni, As, Sc, and major cations (A1, Fe, Mg, Ca, K, Na) in the sediment were measured by atomic fluorescence spectrometer, ICP-MS, and ICP-OES, respectively, following digestion with various acids. We found the concentrations of most elements in the uncontaminated sediment were significantly correlated to those of Sc. 相似文献
14.
Much of southern and eastern Africa is semi-arid and heavily groundwater dependent. Borehole drilling commenced over a hundred years ago with magnetic and electrical resistivity surveys for borehole siting being introduced from 1936. Formalised training of hydrogeologists led in the 1970s to an almost standard approach to hydrogeological investigation and a period of stability followed, during which some major investigations were carried out. A period of decentralisation and fragmentation has since taken place in many parts of southern and eastern Africa, and groundwater monitoring and management are inadequate in many countries. All but six of the 14 SADC (Southern African Development Community) member states reportedly have an adequate monitoring network in place. However, groundwater demand is increasing and hydrogeologists need to promote the use of appropriate methodologies as an essential part of tackling the severe issues now facing the water sector in the region. 相似文献
15.
Karst groundwater protection in the Kupa River catchment area and sustainable development 总被引:1,自引:0,他引:1
One of the most significant water resources in the Republic of Croatia is the catchment area of the Kupa River, located in
the region bordering the Republic of Slovenia. About 88% of the total amount of water in this catchment originates in Croatia
and just 12% from Slovenia; therefore, the largest part of the catchment area (about 1000 km2) is on the Croatian side of the border. It is a typical karst area of the Dinarides with aquifers characterized by a relatively
rapid water exchange, high groundwater flow velocities and aquifers open to human impact from the surface. Consequently, the
aquifers are highly vulnerable and at risk. Due to the availability of large quantities of high-quality spring water (about
6 m3/s), the entire area has a strategic importance within the context of any future development strategy pertaining to the western
part of Croatia. The catchment area on the Croatian side was investigated using a wide range of research methods that included
a classical hydrogeological approach, the detailed hydrologic calculation of water balance to the hydrogeochemical analyses
and modelling. The objective was to determine protection zones and protection measures for the whole area. The difficulties
are increased due to the fact that the karst catchment area is crossed by major traffic corridors, oil pipelines and a railway
and that many settlements and a highly developed wood industry are present. The combination of protecting water resources
with adequate prevention measures and necessary remedial activities that should satisfy the very strict requirements necessary
for the protection of the karst aquifers while still allowing for present and future human activities is difficult – but not
impossible – to achieve. One good example is the present highway with a closed dewatering system and waste water treatment
before the water passes into the karst underground system. 相似文献
16.
Athanasios Maramathas 《Hydrogeology Journal》2006,14(7):1360-1366
A new approach to the method of artificial upraising of the water outlet point, for management and development of brackish karst springs, uses the MODKARST model. Brackish karst springs simulation can be used to estimate the necessary upraising of the spring elevation, so that sea-water intrusion is blocked. The consequent freshwater loss to the sea, due to this upraising, can also be estimated. The method has been applied to the periodically brackish karst Almiros spring at Heraklion of Crete, Greece. The spring simulation showed that the sea-water intrusion could be prevented through an artificial upraising of the water-outlet point, realized by the construction of a dam. The exact upraising has been estimated. Freshwater loss to the sea because of this upraising has also been estimated. The model could also be used as a tool for the management of the spring. For example, it was used to assess management options for the spring during the depletion period of the year 1994. The best scenario for the development of the spring during this period has been estimated. 相似文献
17.
Whereas certain linkages between stream channel morphology and stream ecology are fairly well-understood, how geomorphology influences trophic interactions remains largely unknown. As a first step, a simple, heuristic model is developed that couples reach-scale geomorphic morphology with trophic dynamics between vegetation, detritus, herbivores, and predators. Predation is assumed to increase with depth beyond a threshold depth, and herbivory is assumed to decrease with velocity beyond a threshold velocity. Results show that the modeled food chain is sensitive to channel geometry, particularly around the threshold conditions for predators and herbivores. Importantly, geomorphic influences are not isolated to a particular trophic level, but rather are transferred through the food chain via top-down and bottom-up effects. The modeled system is particularly sensitive to changes in the end-members of the food chain: vegetation and predators. Results illustrate that geomorphic disturbances, known to affect a single trophic level (e.g., fish), likely impact multiple trophic levels in the stream ecosystem via trophic interactions. Such impacts at the multiple trophic level are poorly understood. While limited by the lack of empirical long-term data for testing and calibration, this simple model provides a structure for generating hypotheses, collecting targeted data, and assessing the potential impacts of stream disturbance or restoration on entire stream ecosystems. Further, the model illustrates the potential for future coupled stream models to explore spatial and temporal linkages. 相似文献
18.
Spatial assessment and redesign of a groundwater quality monitoring network using entropy theory, Gaza Strip, Palestine 总被引:3,自引:0,他引:3
Using entropy theory, a methodology was developed for the evaluation and redesign of groundwater quality monitoring wells in the Gaza Strip in Palestine. Essential to the methodology is the development of a Transinformation Model (TM) which yields the amount of information transfer and the dependency between the wells as a function of distance. The TM parameters, such as the minimum transinformation and the range, were employed for evaluating the network which revealed that most of the distances between wells were less than the range. It also indicated that a high percentage of redundant information existed in the network. Therefore, the network was reduced by superimposing a square pattern over the monitored area and selecting one well per square block in a stratified pattern. The methodology was tested using the chloride data collected from 1972–2000 from 417 groundwater quality monitoring wells in the Gaza Strip. The number of the groundwater quality monitoring wells in the Gaza Strip was reduced by 53%, while there was 26% redundant information based on the minimum existing distance between wells. This methodology is meant to help monitor the groundwater quality (salinity) in the Gaza Strip. 相似文献
19.
Specific yield is an essential parameter for any groundwater management plan. Volumetric analysis in the domain of groundwater
budgeting for the non-monsoon months has been undertaken for a typical watershed of the Deccan basalt province. The Torla
Odha watershed covers an area of over 22 km2 on a third-order tributary of the westerly flowing Bhima River. The watershed receives a normal annual rainfall of 643 mm.
The entire water demand is supplied by dug wells, which penetrate a shallow aquifer. The specific yield was estimated by comparing
the monthly net volume of water removed from the aquifer, with the volume of aquifer de-saturated, based on monthly water
level data. The estimated specific yield ranges from 0.0019 in May to 0.0173 in November with an average value of 0.0093.
A correlation of the groundwater levels with the detailed geology suggests that the higher specific yield value (0.017) corresponds
to dewatering of the weathered zone within the shallow aquifer. The specific yield of the massive basalt immediately below
the weathered zone varies from 0.0089 to 0.0103. The underlying vesicular basalt, which is dissected by sheet joints, has
a relatively higher specific yield (0.0121). The massive basalt, which forms the base of the shallow aquifer system, has a
lower specific yield from 0.0019 to 0.0022.
Résumé Le débit spécifique est un paramètre essentiel pour tout plan de gestion des eaux souterraines. Les analyses volumétriques, dans le cadre des bilans hydriques des eaux en dehors des mois de mousson, ont été entreprises pour un bassin-versant typique de la province basaltique du Deccan. Le bassin-versant du Torla Odha couvre une superficie de 22 km2, et alimente l’affluent du troisième ordre de la rivière Bhima, qui coule vers l’Ouest. La pluviométrie annuelle atteint 643 mm. Toute la demande en eau es assurée par des puits foncés pénétrant dans l’aquifère phréatique. Le débit spécifique a été estimé en comparant le volume net mensuel d’eau captée dans l’aquifère, avec le volume de l’aquifère dé-saturé, basé sur les données des niveaux piézométriques mensuels. Le débit spécifique estimé s’étend entre 0,0019 en Mai et 0.173 en Novembre; la moyenne se situe à 0,0093. Une corrélation entre les niveaux des eaux souterraines et la géologie, suggère que les débits spécifiques les plus importants (0,017) correspondent aux zones altérées de l’aquifère phréatique. Le débit spécifique du massif basaltique, immédiatement sous la zone altérée, varie entre 0,0089 et 0,0103. Le basalte vésiculaire, situé juste en dessous et traversé par des diaclases parallèles, possède un débit spécifique sensiblement plus élevé (0,0121). Le basalte massif, qui forme la base de l’aquifère phréatique, possède un débit spécifique moins important, compris entre 0,0019 et 0,0022.
Resumen El rendimiento específico es un parámetro esencial para cualquier plan de manejo de aguas subterráneas. Se ha llevado a cabo el análisis volumétrico, en el entorno de balance de aguas subterráneas, para los meses sin monzón de una cuenca típica de la provincia de basaltos Deccan. La cuenca Rorla Odha cubre un área de 22 km2 en un tributario de tercer orden del Río Bhima que fluye al oeste. La cuenca capta una lluvia anual normal de 643 mm. La totalidad de la demanda de agua es abastecida por pozos manuales que penetran un acuífero somero. Se estimó el rendimiento específico al comparar el volumen neto mensual de agua removido del acuífero con el volumen de agua de-saturado estimado a partir de datos de niveles de agua mensuales. Los valores estimados de rendimiento específico varían de 0.0019 en mayo a 0.0173 en noviembre con un valor promedio de 0.0093. La correlación de niveles de agua subterránea con la geología de detalle sugieren que el valor más alto (0.017) de rendimiento específico corresponden con el desaguado de la zona de intemperismo dentro del acuífero somero. El rendimiento específico del basalto masivo que se encuentra inmediatamente debajo de la zona de intemperismo varía de 0.0089 a 0.0103. El basalto vesicular subyacente, el cual está disectado por fracturas laminares, tiene un rendimiento específico relativamente más alto (0.0121). El basalto masivo, que forma la base del sistema de acuífero somero, tiene un rendimiento específico más bajo el cual varía de 0.0019 a 0.0022. Palabras clave: basalto Deccan. India. Rendimiento específico. Recarga de agua subterránea. Balance hídrico.相似文献
20.
目的:将电阻率层析成像应用于探测潜伏断层的研究中,本文发现了断层和地下水的一些基本电阻率分布特征,这对于工程物探意义重大,一般情况下,断层两侧具有不同的电阻率特征,但是,根据电阻率层析图像中的电阻率分布,通常难以区分断层和地下水层,这是因为两者不仅都具有低电阻率值,而且还具有非常相似的电阻率异常特征。资料和方法:运用电阻率层析图像的数据,电阻率层析图像中的断层会呈现如下特征:1)由于孔隙度的加大和地下水的存在,使得断层表现出高角度的低阻线性结构。它们既可以出现在浅部盖层中,也可以存在于深部基岩中,特别是在深部区域,它们尤为明显;2)它们还呈现出高角度的线性梯度带,在该梯度带两边的电阻率结构出现整体性的差异,通常情况下,正断层的上盘表现出低阻或/和班驳状的高阻和低阻扰动区,而下盘则为完整的高阻区,这与逆冲断层正好相反;3)与断层有关的电阻率异常区常常具有良好的大尺度水平连续性,并且可以追瞎异常区附近的精细电性结构。而地下水的电阻率特征为:1)如果没有裂隙,地表水所引起的低阻区非常浅,即使存在丰富的水源以及高孔隙度的砾岩和中粗砂。一般情况下,其底端深度不超过强风化区;2)地下水的电阻率值非常低,特别在高矿化度的地区。地下水,包括岩溶水和砂岩水,的电阻率总显示出局部水平延伸或/和面团状特征;3)地下水层的深度朝某个固定方向逐渐增加,并且其电阻率图像会随季节而变;4)一般情况下,在水下渗的地区,会出现降水漏斗,其上部为高阻,而下部为低阻,从而便形成了“Y”或“V”字型的典型结构。结果:利用上述的基本特征一般可以区分断层和地下水。结论:仅依靠电阻率层析图像,可能极难准确地区分断层和裂隙水,这是因为裂隙水不但可能具有高角度的低阻线性结构,而且在一定尺度上具有很好的水平连续性,还有,由于电阻率层析成像较差的垂直分辨率,难以精确确定断层的上端点位置,所以结合其它的物探手段如钻探和浅层地震勘探是非常必要的。 相似文献