中国大陆科学钻探主孔榴辉岩中石榴石和绿辉石原位激光探针分析及其成岩成矿指示意义

本文以中国大陆科学钻探主孔0～2000m岩芯中的榴辉岩为对象,运用EMPA和LA-ICP-MS技术,系统测定了榴辉岩中石榴石和绿辉石的主量与微量元素组成,并据此讨论了它们的成岩成矿意义.研究结果表明,CCSD主孔榴辉岩中石榴石富重稀土和Sc、Y、Co,而绿辉石则富中稀土和Pb、Sr、V,石榴石和绿辉石的高场强元素(特别是Nb、Ta)含量均很低.石榴石存在不同程度的Ce负异常,指示榴辉岩的形成过程中卷入有地表氧化条件下形成的风化沉积物.石榴石具有低的Zr/Y比值,绿辉石普遍具有高的Sr含量,这些特征说明榴辉岩(特别是高钛榴辉岩)的原岩可能为遭受过壳源物质混染与交代的富集地幔部分熔融的产物.高钛与低钛榴辉岩中石榴石和绿辉石在主量及微量元素组成上存在一定差别,总体而言,高钛榴辉岩中石榴石具高的MgO含量和较高的MgO/TFeO比值,以及较高的稀土和Sc含量,而绿辉石则相对富TFeO、MnO,并具有较高的Sr、Zr、Hf含量.高钛榴辉岩中石榴石和绿辉石常出现不同程度的Eu正异常,Cr含量均显著低于低钛榴辉岩.综合分析表明,高钛榴辉岩的原岩最可能为富斜长石的辉长质侵入岩,原岩组成的差异应是导致二类榴辉岩中石榴石和绿辉石矿物化学组成存在差异的主要原因.     

Laboratory modelling of shear behaviour of soft joints under constant normal stiffness conditions

Shear behaviour of regular sawtooth rock joints produced from casting plaster are investigated under constant normal stiffness (CNS) conditions. Test results obtained in this investigation are also compared with the constant normal load (CNL) tests. It is observed that the peak shear stress obtained under CNL conditions always underestimates the peak shear stress corresponding to the CNS condition. Plots of shear stress against normal stress show that a nonlinear (curved) strength envelope is acceptable for soft rock joints subjected to a CNS condition, in comparison with the linear or bilinear envelopes often proposed for a CNL condition. Models proposed by Patton (1966) and Barton (1973) have also been considered for the predictions of peak shear stress of soft joints under CNS conditions. Although Patton's model is appropriate for low asperity angles, it overestimates the shear strength in the low to medium normal stress range at higher asperity angles. In contrast, while Barton's model is realistic for the CNL condition, it seems to be inappropriate for modelling the shear behaviour of soft joints under CNS conditions. The effect of infill material on the shear behaviour of the model joints is also investigated, and it is found that a small thickness of bentonite infill reduces the peak stress significantly. The peak shear stress almost approached that of the shear strength of infill when the infill thickness to asperity height ratio (t/a) reached 1.40. This paper also introduces an original, empirical shear strength envelope to account for the change in normal stress and surface degradation during CNS shearing. © Rapid Science Ltd. 1998     

P–Y Curves for Piles Under Seismic Lateral Loads

This paper describes an experimentally based procedure for building dynamic P–Y curves for clays from the Campeche sound in the Gulf of Mexico and for Mexico City clays. Cyclic triaxial and resonant column tests were used to derive hyperbolic stiffness–strain and damping–strain functions that depend on soil plasticity and on relative consistency. The dynamic P–Y curves incorporate these functions and also include hysteretical and geometrical damping characteristics of the pile–soil system; they can be used directly in dynamic interaction analyses of structure–pile–soil systems in the time or the frequency domains. Usual practice relies on pseudo static formulations and a simplified alternative to include P–Y curves in this kind of analysis is also proposed, which is essentially the same as the dynamic ones but does not include radiation or hysteretical damping.     

Swelling Behaviour of Expansive Shales from the Middle Region of Saudi Arabia

Severe and widespread damage in residential buildings, sidewalks and pavements in various parts of the middle region of Saudi Arabia is caused by the development of heave and swelling pressure in the expansive shales in the region. This paper presents the problems and the geotechnical and physicochemical properties of the tested shales. The swelling potential was determined using various methods. Swell tests were conducted under different loading conditions and following different procedures to quantify the amount of vertical swell and swelling pressure. The conventional one-dimensional oedometer swell tests were performed using three different procedures, namely, free swell, constant volume swell and swell overburden. In addition, swell tests were performed in the stress path triaxial apparatus. Tests under different vertical stresses and confinements were conducted. Vertical swell and swelling pressure obtained from the various methods were compared. The reliability of the different methods for estimation of swelling potential is discussed.     

有机酸对高岭石形成影响的模拟试验研究

利用富里酸、胡敏酸和盐酸与天然矿物－长石、蒙脱石和云母在常温常压下进行反应,探讨矿物溶解及高岭石形成机理。实验表明富里酸对这些矿物具有较大的溶解能力,其原因是由于形成了具有较大溶解度和活动性的有机硅和有机铝复合体。在中性－碱性条件下有利于有机硅复合体的形成,酸性条件下有利于有机铝复合体的形成。在富里酸作用下,蒙脱石和云母分别在４个月和８个月有少量转化成高岭石,说明层状硅酸盐矿物比架状硅酸盐矿物更易     

A comparison of estimated and calculated effective porosity

 Effective porosity in solute-transport analyses is usually estimated rather than calculated from tracer tests in the field or laboratory. Calculated values of effective porosity in the laboratory on three different textured samples were compared to estimates derived from particle-size distributions and soil–water characteristic curves. The agreement was poor and it seems that no clear relationships exist between effective porosity calculated from laboratory tracer tests and effective porosity estimated from particle-size distributions and soil–water characteristic curves. A field tracer test in a sand-and-gravel aquifer produced a calculated effective porosity of approximately 0.17. By comparison, estimates of effective porosity from textural data, moisture retention, and published values were approximately 50–90% greater than the field calibrated value. Thus, estimation of effective porosity for chemical transport is highly dependent on the chosen transport model and is best obtained by laboratory or field tracer tests. Received, March 1997 · Revised, August 1997 · Accepted, August 1997     

Reddening of dune sands—evidence from southeast India

Thin section, SEM, and TEM analyses have indicated that the red ‘teri’ sands of southeast India have formed from weathering in situ of coastal dune sands. The data does not support a detrital origin for the red sands. C¹⁴ dates indicate that dune deposition and weathering, to a maximum depth of 10 m, leading to the formation of a hematite, koalinite and illite rich matrix has taken place rapidly over the past 25,000 years. It is postulated that garnet was a major source of hematite (ferric oxide).     

Spatial distribution and temporal variation of reference evapotranspiration in arid and semi‐arid regions of Iran

Analysis of spatial and temporal variations of reference evapotranspiration (ET_o) is important in arid and semi‐arid regions where water resources are limited. The main aim of this study was to analyse the spatial distribution and the annual, seasonal and monthly trends of the Penman–Monteith ET_o for 21 stations in the arid and semi‐arid regions of Iran. Three statistical tests the Mann‐Kendall, Sen's slope estimator and linear regression were used for the analysis. The analysis revealed that ET_o increased from January to July and deceased from July to December at almost all stations. Additionally, higher annual ET_o values were found in the southeast of the study region and lower values in the northwest of the region. Although the results showed both positive and negative trends in annual ET_o series, ET_o generally increased, significantly so in six (～30%) of the stations. Analysis of the impacts of meteorological variables on the temporal trends of ET_o indicated that the increasing trend of ET_o was most likely due to a significant increase in minimum air temperature, while decreasing trend of ET_o was mainly caused by a significant decrease in wind speed. At the sites where increasing ET_o trends were statistically significant, the rate of increase varied from (+)8·36 mm/year at Mashhad station to (+)31·68 mm/year at Iranshahr station. On average, an increasing trend of (+)4·42 mm/year was obtained for the whole study area during the last four decades. Seasonal and monthly ET_o have also tended to increase at the majority of the stations. The greatest numbers of significant trends were observed in winter on the seasonal time‐scale and in September on the monthly time‐scale. Copyright © 2011 John Wiley & Sons, Ltd.     

The impact of the nitrogen carryover effect on economic activity and the environment

 The economic and environmental consequences of soil nitrogen tests can have significant impacts on agricultural production. Some of these are explored here. The pre-side-dress soil N-test is evaluated for a hypothetical farmer growing corn at the ARS Sustainable Agriculture Demonstration Farm site in southern Maryland. For a farmer not currently using a soil N-test, adoption of this technology can lead to the enhancement of net farm income and the reduction in nitrogen loss to the environment. This will transpire only if the farmer is currently underestimating nitrogen carryover by more than 25% or applying nitrogen fertilizer based solely on an expected plateau-yield goal. Received: 13 February 1997 · Accepted: 13 May 1997