This study investigates the retention of heavy metals in secondary precipitates from a sulfidic mine rock dump and underlying
podzolic soils by means of mineralogical and chemical extraction methods. The rock dump, which is at least 50 years old, consists
of a 5–10-cm-thick leached zone and an underlying 110–115-cm-thick accumulation zone. Optical microscopy and electron microprobe
analyses confirm that pyrrhotite weathering has proceeded much further in the leached horizon relative to the accumulation
horizon. The weathering of sulfides in the leached zone has resulted in the migration of most heavy metals to the accumulation
zone or underlying soils, where they are retained in more stable phases such as secondary ferric minerals, including goethite
and jarosite. Some metals are temporarily retained in hydrated ferrous sulfates (e.g., melanterite, rozenite).
Received: 28 October 1996 · Accepted: 24 February 1997 相似文献
Both sulfate and conductivity are useful indicators of acid mine drainage (AMD) contamination. Unlike pH, they are both extremely sensitive to AMD even where large dilutions have occurred. The advantage of using sulfate to trace AMD is that unlike other ions it is not removed to any great extent by sorption or precipitation processes, being unaffected by fluctuations in pH. These two parameters are also closely associated as would be expected, as conductivity is especially sensitive to sulfate ions. Therefore, as sulfate analysis is difficult in the field, conductivity can be used to predict sulfate concentration in both AMD and contaminated surface waters using regression analysis. Most accurate predictions are achieved by using equations given for specific conductivity ranges or AMD sources. There is also potential to use conductivity to predict approximate concentrations of key metals when the pH of the water is within their respective solubility ranges. 相似文献
A comparative study of sulfide mine tailings from two sites near Silver City in southwest New Mexico has shown the need for environmental monitoring in a geological context. The Cyprus-Piños Altos and Cleveland deposits consist of Cu and Zn skarn mineralization in the Piños Altos Mountains of New Mexico. Primary ore minerals in both deposits include chalcopyrite, sphalerite, and galena. The Cyprus-Piños Altos Mine ceased operation in 1995 and the Cleveland Mill closed in 1950. The deposits have similar mineralogical characteristics; however, the tailings are different in terms of age, degree of oxidation and method of disposal. The Cyprus-Piños Altos tailings (CPAT) are stored in a lined, bermed impoundment. They are dominantly water-saturated and exhibit no secondary-phase formation. The grains are not cemented and show no evidence of primary-mineral dissolution. The geochemical data show a predominantly primary signature. The tailings pond water is neutral to slightly alkaline (pH?from 7 to 8.3), partly as a result of processing methods. The Cleveland mill tailings (CMT) were deposited in a valley at the headwaters of an ephemeral stream. They are highly oxidized and differentially cemented. They have undergone numerous wet/dry cycles resulting in extensive oxidation. Secondary minerals predominate, and consist mainly of jarosite, goethite, hematite, and Fe-oxyhydroxides and -oxyhydroxysulfates. The pH of the stream draining the CMT is as high as 2.15. Maximum metal contents in the stream immediately downstream from the tailings are 5305?ppm Zn, 454?ppm Cu, 1.16?ppm Pb, 17.5?ppm Cd, 1.4?ppm As, and 0.01?ppm Hg. 相似文献
Spinel lherzolite xenoliths from Tertiary basaltic host magmas at Allyn River, eastern Australia reveal two distinct petrographic and geochemical types. One group is distinguished by xenoliths with undeformed, equilibrated microstructures and interstitial melt patches; The second group shows deformation and contains abundant fluid inclusions but no melt patches. Trace-element signatures of clinopyroxene in these xenoliths provide evidence for metasomatism by a silicate agent with hydrous component and by a carbonate-rich agent respectively.
Melt patches in the undeformed xenoliths contain secondary minerals including clinopyroxene, olivine, feldspar, Mg- and Ca-rich carbonate, apatite, ilmenite and spinel. They are interpreted to represent volatile-rich melt captured shortly prior to entrainment in the host basalt. Sulfide globules, now recrystallised to discrete sulfide phases but inferred to be molten at lithospheric mantle T and P, are closely associated with the melt patches. The close association between sulfide and highly mobile, volatile-bearing fluid has important implications for the mobility of Re and Os, the use of their isotopes in dating mantle events, and the possible effect of volatile-bearing metasomatic agents on their composition. 相似文献
During and after the very wet 1991/1992 winter experienced in Jordan, significant slope failures occurred along several sections of the new Irbid-Amman highway in Jordan. The topography over most of the route is hilly, and significant amounts of cut and fill were used to construct the highway. One such slope failure lies at 44+800 km on the highway south of Jerash City at a distance of about 5.0 km from Wadi Zerqa bridge. A landslide occurred downslope of the highway embankment resulting in a collapse of the most of the gabbion wall supporting the embankment. This paper deals with the overall stability of the slope at 44+800 km. It presents the geological and geotechnical studies carried out at this site, identifies the causes and mechanism of instability, and presents appropriate remedial measures. The study concluded that the landslide movement occurred within the colluvium material. It resulted primarily from excess piezometric pressures generated within the slope as a direct consequence of inadequate drainage. It is recommended to reconstruct the entire gabbion wall with its foundation seated on the sandstone that underlies the colluvium and to install a surface drainage system at the site. 相似文献