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101.
相比重力数据,重力张量数据通常包含更多的异常信息。本文根据重力数据与重力张量数据的关系,利用位场转化技术,将重力张量数据应用于传统的Parker-Oldenburg密度界面反演算法中。通过模型试验,证明了在网格间距较大或者数据存在一定噪音时,使用本文算法进行反演能得到更好的效果。实验结果说明利用重力张量数据可以有效地提高密度界面反演的分辨率。 相似文献
102.
蓬莱9-1花岗岩体是渤海海域首次发现的中生代花岗岩,鉴于渤海海域在华北克拉通中的重要构造位置,该花岗岩的形成时代和成因机制的研究对区域构造研究具有重大意义。锆石LA-ICP-MS U-Pb定年结果表明该花岗岩体形成于中侏罗世160~165Ma。花岗岩属于高钾钙碱性系列,为准铝质-过铝质花岗岩;富Al_2O_3(14.84%~17.19%)和Sr(485×10~(-6)~909×10~(-6)),贫Y(0.66×10~(-6)~1.39×10~(-6))和Yb(小于2.0×10~(-6)),无铕的负异常,多数样品表现为铕的弱正异常,表现出C-型埃达克岩特征。表明渤海地区在160~165Ma期间处于挤压地壳增厚环境下,以地壳减薄为标志的克拉通破坏过程彼时尚未发生,其区域动力学环境可能仍处于华北板块-华南板块碰撞拼接的影响范围内。 相似文献
103.
104.
为寻找天然抗污损活性化合物,以抗硅藻附着活性为导向,采用有机溶剂萃取、半制备高压液相色谱对分离自海绵的芽孢杆菌UST050418-715代谢产物进行分离,纯化抗硅藻附着活性物质,并利用气相色谱-质谱联用仪、核磁共振波谱分析活性物质结构。从菌株UST050418-715代谢产物中分离得到7种具有抗硅藻附着活性的环二肽类化合物,分别鉴定为:(1)环(L-亮氨酸-反式-8-羟基-L-脯氨酸-)、(2)环(L-缬氨酸-L-脯氨酸)、(3)环(D-脯氨酸-L-亮氨酸)、(4)环(L-脯氨酸-D-亮氨酸)、(5)环(甘氨酸-L-脯氨酸)、(6)环(L-苯丙氨酸-顺式-8-羟基-D-脯氨酸-)、(7)环(L-苯丙氨酸-反式-8-羟基-L-脯氨酸-)。说明海绵附生芽孢杆菌UST050418-715代谢产物中存在大量环二肽类化合物,可以帮助宿主海绵实现对硅藻附着的化学防御。 相似文献
105.
Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials 下载免费PDF全文
Pei‐Pei Zhao Jie Li Le Zhang Zhi‐Bing Wang De‐Xin Kong Jin‐Long Ma Gang‐Jian Wei Ji‐Feng Xu 《Geostandards and Geoanalytical Research》2016,40(2):217-226
The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions. 相似文献
106.
Jason Jweda Louise Bolge Cornelia Class Steven L. Goldstein 《Geostandards and Geoanalytical Research》2016,40(1):101-115
The Lamont‐Doherty Earth Observatory radiogenic isotope group has been systematically measuring Sr‐Nd‐Pb‐Hf isotopes of USGS reference material BCR‐2 (Columbia River Basalt 2), as a chemical processing and instrumental quality control monitor for isotopic measurements. BCR‐2 is now a widely used geochemical inter‐laboratory reference material (RM), with its predecessor BCR‐1 no longer available. Recognising that precise and accurate data on RMs is important for ensuring analytical quality and for comparing data between different laboratories, we present a compilation of multiple digestions and analyses made on BCR‐2 during the first author's dissertation research. The best estimates of Sr, Nd and Hf isotope ratios and measurement reproducibilities, after filtering at the 2s level for outliers, were 87Sr/86Sr = 0.705000 ± 11 (2s, 16 ppm, n = 21, sixteen digestions, one outlier), 143Nd/144Nd = 0.512637 ± 13 (2s, 25 ppm, n = 27, thirteen digestions, one outlier) and 176Hf/177Hf = 0.282866 ± 11 (2s, 39 ppm, n = 25, thirteen digestions, no outliers). Mean Nd and Hf values were within error of those reported by Weis et al. (2006, 2007) in their studies of RMs; mean Sr values were just outside the 2s uncertainty range of both laboratories. Moreover, a survey of published Sr‐Nd‐Hf data shows that our results fall within the range of reported values, but with a smaller variability. Our Pb isotope results on acid leached BCR‐2 aliquots (n = 26, twelve digestions, two outliers) were 206Pb/204Pb = 18.8029 ± 10 (2s, 55 ppm), 207Pb/204Pb = 15.6239 ± 8 (2s, 52 ppm), 208Pb/204Pb = 38.8287 ± 25 (2s, 63 ppm). We confirm that unleached BCR‐2 powder is contaminated with Pb, and that sufficient leaching prior to digestion is required to achieve accurate values for the uncontaminated Pb isotopic compositions. 相似文献
107.
An Alternative Protocol for Single Zircon Dissolution with Application to (U‐Th‐Sm)/He Thermochronometry 下载免费PDF全文
Bouchaïb Tibari Arnaud Vacherat Martin Stab Raphaël Pik Delphine Yeghicheyan Pascal Hild 《Geostandards and Geoanalytical Research》2016,40(3):365-375
Zircon (U‐Th‐Sm)/He (ZHe) thermochronometry is a powerful tool that has been widely used in geology to constrain the exhumation histories of orogens. In this study, we present an alternative protocol for dissolving zircon grains for determination of parent nuclides. This new alkali fusion procedure developed at the SARM (Service d'Analyse des Roches et des Minéraux) in Nancy, France, is fast (requiring only 2 d, including cleaning steps) and offers several advantages over conventional methods by avoiding: (i) use of HF pressure dissolution and (ii) complete removing of grains from the metal microvials. After dissolution, U, Th and Sm were measured using an ICP‐MS. We tested the new procedure on two different ZHe reference materials, the Fish Canyon Tuff and Buluk Tuff; these provided precision values for ZHe‐age estimations of 9 and 6% (1s), respectively. In addition, using this method, zircons from the Buluk Tuff are shown to be chemically more homogenous and more suitable for assessing the uncertainty of the entire integrated procedure. 相似文献
108.
Community‐Derived Standards for LA‐ICP‐MS U‐(Th‐)Pb Geochronology – Uncertainty Propagation,Age Interpretation and Data Reporting 下载免费PDF全文
Matthew S. A. Horstwood George Gehrels Simon E. Jackson Noah M. McLean Chad Paton Norman J. Pearson Keith Sircombe Paul Sylvester Pieter Vermeesch James F. Bowring Daniel J. Condon Blair Schoene 《Geostandards and Geoanalytical Research》2016,40(3):311-332
The LA‐ICP‐MS U‐(Th‐)Pb geochronology international community has defined new standards for the determination of U‐(Th‐)Pb ages. A new workflow defines the appropriate propagation of uncertainties for these data, identifying random and systematic components. Only data with uncertainties relating to random error should be used in weighted mean calculations of population ages; uncertainty components for systematic errors are propagated after this stage, preventing their erroneous reduction. Following this improved uncertainty propagation protocol, data can be compared at different uncertainty levels to better resolve age differences. New reference values for commonly used zircon, monazite and titanite reference materials are defined (based on ID‐TIMS) after removing corrections for common lead and the effects of excess 230Th. These values more accurately reflect the material sampled during the determination of calibration factors by LA‐ICP‐MS analysis. Recommendations are made to graphically represent data only with uncertainty ellipses at 2s and to submit or cite validation data with sample data when submitting data for publication. New data‐reporting standards are defined to help improve the peer‐review process. With these improvements, LA‐ICP‐MS U‐(Th‐)Pb data can be considered more robust, accurate, better documented and quantified, directly contributing to their improved scientific interpretation. 相似文献
109.
An Investigation of Digestion Methods for Trace Elements in Bauxite and Their Determination in Ten Bauxite Reference Materials Using Inductively Coupled Plasma‐Mass Spectrometry 下载免费PDF全文
Wen Zhang Liang Qi Zhaochu Hu Cunjiang Zheng Yongsheng Liu Haihong Chen Shan Gao Shenghong Hu 《Geostandards and Geoanalytical Research》2016,40(2):195-216
Trace elements from samples of bauxite deposits can provide useful information relevant to the exploration of the ore‐forming process. Sample digestion is a fundamental and critical stage in the process of geochemical analysis, which enables the acquisition of accurate trace element data by ICP‐MS. However, the conventional bomb digestion method with HF/HNO3 results in a significant loss of rare earth elements (REEs) due to the formation of insoluble AlF3 precipitates during the digestion of bauxite samples. In this study, the digestion capability of the following methods was investigated: (a) ‘Mg‐addition’ bomb digestion, (b) NH4HF2 open vessel digestion and (c) NH4F open vessel digestion. ‘Mg‐addition’ bomb digestion can effectively suppress the formation of AlF3 and simultaneously ensure the complete decomposition of resistant minerals in bauxite samples. The addition of MgO to the bauxite samples resulted in (Mg + Ca)/Al ratios ≥ 1. However, adding a large amount of MgO leads to significant blank contamination for some transition elements (V, Cr, Ni and Zn). The NH4HF2 or NH4F open vessel digestion methods can also completely digest resistant minerals in bauxite samples in a short period of time (5 hr). Unlike conventional bomb digestion with HF/HNO3, the white precipitates and the semi‐transparent gels present in the NH4HF2 and NH4F digestion methods could be efficiently dissolved by evaporation with HClO4. Based on these three optimised digestion methods, thirty‐seven trace elements including REEs in ten bauxite reference materials (RMs) were determined by ICP‐MS. The data obtained showed excellent inter‐method reproducibility (agreement within 5% for REEs). The relative standard deviation (% RSD) for most elements was < 6%. The concentrations of trace elements in the ten bauxite RMs showed agreement with the limited certified (Li, V, Cr, Cu, Zn, Ga, Sr, Zr and Pb) and information values (Co, Ba, Ce and Hf) available. New trace element data for the ten RMs are provided, some of which for the first time. 相似文献
110.
Tongxiang Ren Jun Wang Hai Lu Tao Zhou Yuanjing Zhou 《Geostandards and Geoanalytical Research》2016,40(2):227-238
Due to intensive research into selenium isotopes in recent years, the increasing requirement for reliable and comparable measurement results has created a strong demand for selenium isotopic certified reference materials (iCRM) that were previously not available. To address this, eleven selenium iCRMs were developed, including ten synthetic iCRMs (GBW 04447–GBW 04456) and one natural iCRM (GBW 04457). The synthetic iCRMs were prepared with 76Se, 78Se, 80Se and 82Se solutions and a natural selenium solution; the natural iCRM was prepared with highly pure selenium material. The property values of isotope ratios in these iCRMs were certified by calibrated mass spectrometry with a collision cell multi‐collector ICP‐MS. The mass discrimination effect of the instrument was corrected with corresponding 78Se/76Se isotope mixtures and 82Se/76Se isotope mixtures, which were gravimetrically prepared with purified, isotopically enriched selenium materials. Homogeneity and stability tests were performed, and no significant influences were found. The uncertainty of the property values of the iCRMs was evaluated according to the Guide to the Expression of Uncertainty in Measurement (GUM) of ISO/BIPM and ISO Guide 35. The δ82/76Se value of GBW 04457 relative to NIST SRM 3149 was also calculated. These iCRMs are intended for use in calibration of instruments and evaluation of methods for the determination of selenium isotope ratios. 相似文献