Free hydrogen-hydrocarbon gases from the Lovozero loparite deposit (Kola Peninsula,NW Russia)

The Lovozero nepheline-syenite massif in the north-eastern Fennoscandian Shield, well-known to mineralogists and petrologists, is also interesting with its high contents of hydrogen-hydrocarbon gases in different forms of presence, which is untypical of magmatic rocks. The article systematizes and generalizes little known and unpublished data on the composition, location, character and scale (intensity) of the free gases (FG) emission within a major loparite deposit confined to the massif. СН₄ and Н₂ are dominant in the FG composition. The molecular weight distribution of hydrocarbon gas components corresponds to the classic Anderson–Schulz–Flory distribution with a steep gradient. Carbon and hydrogen of the gases are characterized by rather heavy isotope compositions, becoming lighter from the transition of methane to ethane. The FG volume has been estimated as 0.2–1.6 m³ of gas per 1 m³ of undisturbed rock. The gas recovery of walls in underground workings has been up to 0.2 ml/min/m² for СН₄ and 0.5 ml/min/m² for Н₂ in several years after their heading. The discharge of some shot holes that characterizes the gas emission intensity (1.8–2 m deep and 40 mm in diameter) is up to 300 ml/min, but its 1–2 orders lesser values dominate. The discharge time in some sections varies from several days to 20 years. The overpressure of gases towards the air mainly does not increase 100 hPa, sometimes reaching 120 kPa. It has been defined, that FG distribute irregularly (at the distance of centimeters to hundreds of meters) and their composition and particularly emission intensity perform different temporal fluctuations. The abiogenic origin of FG has been proposed, with FG appearing as a mixture of gases in various proportions: (a) gases remaining in microfissures at the massif's consolidation after the capture by fluid inclusions and those lost during degassing and (b) gases occurred in mechanic-chemical reactions, partial emission and concentration of occluded and diffusely scattered gases under the unstable stress-strain mode of the rock mass. Combustible and explosive hydrogen-hydrocarbon FG can accumulate in the air of underground workings and cause accidents, disrupting the workflow. The background for using characteristics of spatial-temporal variations of the FG emission as precursors of dangerous geodynamic phenomena has been indicated.     

基于学习曲线的中国未来制氢成本趋势研究

氢能是中国能源系统低碳转型和实现2060年前碳中和目标的重要技术选择之一。根据原料来源可以将氢分为绿氢、蓝氢和灰氢,其制备成本和碳排放强度存在较大差异。文中以中国氢能生产现状为基础,建立基于学习曲线的平准化制氢成本（LCOH）模型,测算不同制氢技术从2020年到2060年的成本变化趋势。结果表明：现阶段灰氢成本最低,绿氢成本最高;到2030年绿氢成本将下降至20~25元/kg;2050年后,绿氢将成为成本最低的制氢方式（含碳排放成本),而且PEM（质子交换膜）电解水制氢的成本将低于AE（碱性）电解水制氢,光伏+PEM电解水制氢成本将下降至12元/kg。电解槽和电力成本下降是未来绿氢成本下降的主要驱动因素。敏感性分析表明,运营维护成本和关键技术学习率是影响绿氢成本下降速度的重要参数。     

Identification of sources and groundwater recharge zones from hydrochemistry and stable isotopes of an agriculture-based paleo-lacustrine basin of drought-prone northeast Mexico

Over exploitation for agricultural activities and consumption has depleted the groundwater resources of drought-prone northeast Mexico. Major ion concentrations along with δ¹⁸O_H2O, δ²H_H2O and d-excess values of shallow groundwater from the Cieneguilla Basin (near Tula) located at a distance of ∼200 km from coast of the Gulf of Mexico helped to contribute new data about drought vulnerability in this region through identification of the moisture source and groundwater recharge zone. Different degrees of rock-water interaction through gypsum, anhydrite and halite dissolutions and minor silicate weathering controlled the hydrochemistry. Stable isotopes yielded a least square regression and slope similar to the local as well as global meteoric water lines, indicating minimal effect of evaporation during the recharge as well as in the subsoil. Isotopic fractionations along with a digital elevation model demarcated the recharge zones at north and east of the basin, with altitudinal difference of ≥1000 m, and indicated that the recharge occurred through warm season moisture sourced from the Gulf of Mexico. Less frequent landfalling of tropical storms caused by warmer sea surface temperature, however, has reduced this rainfall over the last few decades. If the trend of global warming continues unabated, the depleted groundwater resources would trigger reduction in agricultural activities in this drought-prone region and lead to enhanced socio-economic challenges.     

胶东石城金矿床成矿流体特征及成矿作用

石城金矿位于胶东牟平-乳山成矿带南端,为多金属硫化物型金矿床。其成矿流体阶段可分为3个,相应的流体包裹体特征为:(1)成矿早期(第1阶段)富CO2包裹体;(2)主成矿期(第2阶段)H2O包裹体和含CO2包裹体;(3)成矿后期(第3阶段)H2O包裹体。第1阶段均一温度为256～360℃,盐度3.71%～6.88%NaCl,第2阶段均一温度为168～270℃,盐度4.49%～10.24%NaCl,第3阶段均一温度为123～178℃,盐度0.35%～7.59%NaCl。其中主成矿期为中低温、低盐度的CO2-H2O-NaCl流体体系。H、O同位素表明石城金矿成矿流体为岩浆水与大气水形成的混合热液,C、O同位素则反映了地幔富CO2流体参与了成矿作用,而S同位素进一步揭示了金矿的成矿物质来源为壳幔相互作用的结果。石城金矿的出现表明研究区至少存在两期成矿事件,早期成矿时代约120Ma,主要为石英+黄铁矿型矿石,晚期成矿时代小于111Ma,主要为多金属硫化物型矿石,以石城金矿为代表。     

氢钟钟罩及真空机组的改进设计

本文介绍了氢钟钛合金钟罩的设计制作以及机械泵─分子泵前级真空机组的改进设计．由于钛是一种崭新的工程金属，用钛合金制作的真空钟罩由于采用了较正确的工艺手段，具有强度高、重量轻、在真空中放气率低、无磁、外表美观和经济实惠等优点．而前级真空机组，由于采用了不锈钢波纹管及卡箍结构，无粗大的真空橡皮管，也改善了氢钟的真空条件．钛合金钟罩及改进型前级真空机组的应用对氢钟钛离子泵的启动及系统真空度的提高起了一定的作用．     

The R Coronae Borealis stars — A few mere facts

This review presents a selection of recent highlights of observations of R Coronae Borealis variables. Emphasis is placed on an abundance analysis of a complete sample (18 stars) of the warm galactic RCBs. It is shown that 14 of the 18 have very similar compositions: the iron mass fraction ranges about a factor of 3 around the solar value (assuming C/He = 3%) but abundance ratios X/Fe for elements from Na to Ba show little variation. By contrast, the other 4 stars are deficient in iron but not in Na, Si, S and some other elements. With for example, [Si/Fe] ≃ 2, the quartet is indeed ‘peculiar’. One of the quartet, V854 Cen shows depletions of elements (other than CNO) similar to the depletions seen in interstellar medium corresponding to average logn(H _tot) = − 1.5. Scenarios for creating RCB from normal single and double stars are summarised. Invited review talk presented at the Asia-Pacific regional IAU meeting held at Pune from 16–20 August 1993.     

陕西天文台守时用氢原子钟

本文介绍了陕西天文台守时用氢原子钟（Ｈ２）的改进、分项误差、准确度及在国际时间局（ＢＩＰＭ）公报中取权情况．Ｈ２自１９９１年开始连续运转至今已两年多了。１９９１年３月开始每月向ＢＩＰＭ报送数据，１９９１年９月开始取权１．Ｈ２是我国唯一的一台在ＢＩＰＭ公报上取权的氢钟．     

锍试金富集贵金属元素1Ⅰ.等离子体质谱法测定地质样品中痕量铂族元素

纯化了捕集剂，用锍试金结合Ｔｅ共沉淀富集，等离子体质谱法测定了地质样品中的铂族元素。全流程铂族元素回收率大于９４％。一次熔样可同时测定６个铂族元素。按２０ｇ取样计算，方法检出限（ｎｇ／ｇ）分别为：００２４Ｒｕ，００１３Ｒｈ，０２０Ｐｄ，００３３Ｏｓ，０３９Ｉｒ，０１２Ｐｔ；对标准ＧＰｔ６平行测定５次，铂族元素相对标准偏差为１％（Ｏｓ）～８％（Ｐｔ）；对不同类型标样进行测定，测得结果与标准值基本吻合     

汉诺坝幔源单斜辉石巨晶氢同位素组成的离子探针分析:微尺度不均一性

运用离子探针技术测定了河北汉诺坝新生代玄武岩中3个单斜辉石巨晶的氢同位素组成,结果显示同一颗粒内部表现出微尺度的不均一性,2mm范围内δD的变化达到60‰。δD和氢含量之间不存在同步的变化,巨晶内部的化学成分均一,因此我们认为巨晶的氢同位素不均一性继承自母岩浆。母岩浆的氢同位素变化可能是去气过程中气相与熔体之间的分馏引起的。单斜辉石巨晶形成后很短的时间内即被寄主岩浆带至地表并经历了快速淬火。     

新疆香山铜镍硫化物矿床浅富矿体特征

本文通过对香山铜镍硫化物矿床中浅富矿体产出的地质条件和基本特征、矿石组构特征、成矿元素的赋存规律，以及矿石同位素组成特征和意义的研究，为在整个铜镍成矿带中寻找浅富矿体提供了对比和找矿依据，同时对深部矿体的开发和利用有着重要的实际意义。